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Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-level structure and dynamics of materials. Nevertheless, the use of this technique is often limited by its lack of sensitivity, which can prevent…

Dynamic nuclear polarization (DNP) is an NMR sensitivity enhancement technique that mediates polarization transfer from unpaired electrons to NMR-active nuclei. Despite its success in elucidating important structural information on…

We compare here the performances of two approaches to achieve such transfer: PRESTO (Phase-shifted Recoupling Effects a Smooth Transfer of Order), which is currently the method of choice to achieve the magnetization transfer from protons to…

Much new solid state technology for single-photon sources, detectors, photovoltaics and quantum computation relies on the fabrication of strained semiconductor nanostructures. Successful development of these devices depends strongly on…

Nuclear magnetic resonance (NMR) spectroscopy is a widely used tool for chemical analysis and molecular structure identification. Because it typically relies on the weak magnetic fields produced by a small thermal nuclear spin polarization,…

Dynamic nuclear polarization (DNP) is an important method to enhance the limited sensitivity of nuclear magnetic resonance (NMR). Using the existing mechanisms such as Overhauser DNP (ODNP) is still difficult to achieve significant…

化学物理 · 物理学 2025-03-31 Maria Grazia Concilio , Yiwen Wang , Linjun Wang , Xueqian Kong

Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…

量子物理 · 物理学 2020-12-24 L. T. Hall , D. A. Broadway , A. Stacey , D. A. Simpson , J-P. Tetienne , L. C. L. Hollenberg

Polarization transfers are crucial building blocks in magnetic resonance experiments, i.e., they can be used to polarize insensitive nuclei and correlate nuclear spins in multidimensional NMR spectroscopy. The polarization can be…

化学物理 · 物理学 2022-08-24 Zhenfeng Pang , Sheetal Jain , Chen Yang , Xueqian Kong , Kong Ooi Tan

Dynamic nuclear polarization (DNP) has revolutionized the field of NMR spectroscopy, expanding its reach and capabilities to investigate diverse materials, biomolecules, and complex dynamic processes. Bringing high-efficiency DNP to the…

介观与纳米尺度物理 · 物理学 2024-02-27 Sahand Tabatabaei , Pritam Priyadarsi , Namanish Singh , Pardis Sahafi , Daniel Tay , Andrew Jordan , Raffi Budakian

Dynamic nuclear polarization (DNP) has become a very important hyperpolarization method because it can dramatically increase the sensitivity of nuclear magnetic resonance (NMR) of various molecules. Liquid-state DNP based on Overhauser…

化学物理 · 物理学 2016-05-10 Yugui He , Zhen Zhang , Jiwen Feng , Chongyang Huang , Fang Chen , Maili Liu , Chaoyang Liu

Nuclear magnetic resonance (NMR) spectroscopy provides unparalleled access to molecular structure and dynamics but is traditionally limited by weak signal strength, requiring large sample volumes and high magnetic fields. Here, we…

应用物理 · 物理学 2026-04-29 Dileep Singh , Riley W. Hooper , Christoph Findler , Utsab Banerjee , Dominik B. Bucher

Dynamic Nuclear Polarization (DNP) has revolutionized the field of solid-state NMR spectroscopy by significantly enhancing the sensitivity of nuclear magnetic resonance experiments. Conventionally, cross effect DNP relies on biradicals to…

化学物理 · 物理学 2023-09-28 Amaria Javed , Asif Equbal

Our recent developments in in-situ nuclear magnetic resonance (NMR) spectroscopy under extreme conditions led to the observation of a wide variety of physical phenomena not accessible with standard high pressure experimental probes.…

Dynamic nuclear polarization (DNP) enhanced nuclear magnetic resonance (NMR) offers a promising route to studying local atomic environments at the surface of both crystalline and amorphous materials. We take advantage of unpaired electrons…

Dynamic nuclear polarization (DNP) using the boron vacancy ($\mathrm{V_B^-}$) in hexagonal boron nitride (hBN) has gained increasing attention. Understanding this DNP requires systematically investigating the optically detected magnetic…

Nuclear spin hyperpolarization provides a promising route to overcome the challenges imposed by the limited sensitivity of nuclear magnetic resonance. Here we demonstrate that dissolution of spin-polarized pentacene-doped naphthalene…

Dynamic nuclear polarization (DNP) is used in nuclear magnetic resonance (NMR) to transfer polarization from electron spins to nuclear spins. The resulting nuclear polarization enhancement can, in theory, be two or three orders of magnitude…

量子物理 · 物理学 2015-10-14 Sarah Sheldon , David G. Cory

Highly sensitive nuclear spin detection is crucial in many scientific areas including nuclear magnetic resonance spectroscopy (NMR), imaging (MRI) and quantum computing. The tiny thermal nuclear spin polarization represents a major obstacle…

Inelastic proton scattering under extreme forward angles including $0^\circ$ and at energies of a few hundred MeV has been established as a new spectroscopic tool for the study of complete dipole strength distributions in nuclei. Such data…

核实验 · 物理学 2020-05-11 Peter von Neumann-Cosel , Atsushi Tamii

Resistively-detected NMR (RDNMR) is a unique characterization method enabling highly-sensitive NMR detection for a single quantum nanostructure, such as a quantum point contact (QPC). In many studies, we use dynamic nuclear polarization and…

介观与纳米尺度物理 · 物理学 2022-03-09 M. H. Fauzi , T. Sobue , A. Noorhidayati , K. Sato , K. Hashimoto , Y. Hirayama
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