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We compute ionic free energy adsorption profiles at aqueous graphene interface by developing a self-consistent approach. To do so, we design a microscopic model for water and put the liquid on an equal footing with the graphene described by…

软凝聚态物质 · 物理学 2023-03-01 Anton Robert , Hélène Berthoumieux , Marie-Laure Bocquet

Graphene is the two-dimensional (2d) building block for carbon allotropes of every other dimensionality. It can be stacked into 3d graphite, rolled into 1d nanotubes, or wrapped into 0d fullerenes. Its recent discovery in free state has…

Two-dimensional (2D) carbon allotropes have received considerable attention due to their unique properties and potential applications in several fields, including electronics, catalysis, energy storage, and sensing. Following the…

Since its discovery in 2004, graphene, a two-dimensional hexagonal carbon allotrope, has generated great interest and spurred research activity from materials science to particle physics and vice versa. In particular, graphene has been…

高能物理 - 格点 · 物理学 2010-11-03 Joaquín E. Drut , Timo A. Lähde , Eero Tölö

Graphene-based laminates, with ultralong and tortuous nanocapillaries formed by simply stacking graphene flakes together, have great promises in filtration and separation. However, the information on liquid water trans-membrane permeation…

化学物理 · 物理学 2015-02-11 Pengzhan Sun , He Liu , Kunlin Wang , Minlin Zhong , Dehai Wu , Hongwei Zhu

Heterostructures prepared from graphene and fluorographene (FG) using the technology of 2D printing on solid and flexible substrates were fabricated and studied. Excellent stability of printed graphene layers and, to a lesser degree,…

Understanding surface forces of two-dimensional (2D) materials is of fundamental importance as they govern molecular dynamics and atomic deposition in nanoscale proximity. Despite recent observations in wetting transparency and remote…

介观与纳米尺度物理 · 物理学 2024-06-12 Gianluca Vagli , Tian Tian , Franzisca Naef , Hiroaki Jinno , Kemal Celebi , Elton J. G. Santos , Chih-Jen Shih

Intercalation is a process of inserting chemical species into the heterointerfaces of two-dimensional (2D) layered materials. While much research has focused on intercalating metals and small gas molecules into graphene, the intercalation…

MXene-based heterostructures have received considerable interest owing to their unique properties. Herein, we examine various heterostructures of a prototypical MXene and graphene using density functional theory. We find that the adhesion…

介观与纳米尺度物理 · 物理学 2019-02-27 Rui Li , Weiwei Sun , Cheng Zhan , Paul R. C. Kent , De-en Jiang

The electronic structure of the zero-gap two-dimensional graphene has a charge neutrality point exactly at the Fermi level that limits the practical application of this material. There are several ways to modify the Fermi-level-region of…

材料科学 · 物理学 2017-09-13 Elena Voloshina , Denis Usvyat , Martin Schuetz , Yuriy Dedkov , Beate Paulus

Ordered distributions of carbon and substitutional dopant (A) atoms over the sites of a graphene lattice and problem of their stability are considered theoretically. The ranges of values of interatomic-interaction parameters providing the…

材料科学 · 物理学 2014-06-03 T. M. Radchenko , V. A. Tatarenko

Ubiquitous graphene is a stricly 2D material representing an ideal adsorbing platform due to its large specific surface area as well as its mechanical strength and resistance to both thermal and chemical stresses. However, graphene as a…

材料科学 · 物理学 2016-10-06 Massimiliano Bartolomei , Giacomo Giorgi

Intercalation of epitaxial graphene on SiC(0001) with Sn results in a well-ordered Sn $(1\times1)$ structure on the SiC surface with quasi-freestanding graphene on top. While the electronic properties of the individual layers have been…

The thermodynamic properties of gases have been understood primarily through phase diagrams of bulk gases. However, observations of gases confined in a nanometer space have posed a challenge to the principles of classical thermodynamics.…

软凝聚态物质 · 物理学 2014-10-31 Ing-Shouh Hwang , Yi-Hsien Lu , Chih-Wen Yang , Chung-Kai Fang , Hsien-Chen Ko

Heterogeneous ice growth exhibits a maximum in freezing rate arising from the competition between kinetics and the thermodynamic driving force between the solid and liquid states. Here, we use molecular dynamics simulations to elucidate the…

软凝聚态物质 · 物理学 2013-12-31 Razvan A. Nistor , Thomas E. Markland , B. J. Berne

Understanding how water wets graphene is critical for predicting and controlling its behaviour in nanofluidic, sensing, and energy applications. A key measure of wetting is the contact angle made by a liquid droplet against the surface, yet…

介观与纳米尺度物理 · 物理学 2026-05-04 Darren Wayne Lim , Xavier R. Advincula , William C. Witt , Angelos Michaelides , Fabian L. Thiemann , Christoph Schran

In this work we consider bubbles that can form spontaneously when a two-dimensional (2D) crystal is transferred to a substrate with gases or liquids trapped at the crystal-substrate interface. The underlying mechanics may be described by a…

软凝聚态物质 · 物理学 2022-07-06 Zhaohe Dai , Yifan Rao , Nanshu Lu

In this work, we conducted molecular dynamics simulations to study the fracture mechanism of ice crystals in a bulk phase and at ice-ice interfaces at the atomistic scale. We show that there exists a narrow disordered interfacial layer…

化学物理 · 物理学 2019-07-23 A. Afshar , J. Zhong , D. S. Thompson , D. Meng

When atomically thin two-dimensional (2D) materials are layered they often form incommensurate non-crystalline structures that exhibit long-period moir{\' e} patterns when examined by scanning probes. In this paper we present an approach…

介观与纳米尺度物理 · 物理学 2015-02-23 Jeil Jung , Arnaud Raoux , Zhenhua Qiao , Allan H. MacDonald

Graphene, a monolayer of carbon atoms packed into a two-dimensional crystal structure, attracted intense attention owing to its unique structure and optical, electronic properties. Recent advances in chemical vapor deposition (CVD) have led…

材料科学 · 物理学 2020-10-23 Yu-Hao Deng
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