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Black phosphorus has recently attracted significant attention for its highly anisotropic properties. A variety of ultrafast optical spectroscopies has been applied to probe the carrier response to photoexcitation, but the complementary…

Black phosphorus (BP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted,…

介观与纳米尺度物理 · 物理学 2022-07-27 Mazhar Chebl , Xing He , Ding-Shyue Yang

Ultrafast spectroscopies can access the dynamics of electrons and nuclei at short timescales, shedding light on nonequilibrium phenomena in materials. However, development of accurate calculations to interpret these experiments has lagged…

材料科学 · 物理学 2021-05-05 Xiao Tong , Marco Bernardi

Femtosecond laser excitation of solid-state systems creates non-equilibrium hot electrons that cool down by transferring their energy to other degrees of freedom and ultimately to lattice vibrations of the solid. By combining ab initio…

We experimentally determine the lattice dynamics of black phosphorus layered crystals through a combination of x-ray diffuse scattering and inelastic x-ray scattering, and we rationalize our experimental findings using $\textit{ab initio}$…

Electron-electron thermalization and electron-phonon relaxation processes in laser-excited solids are often assumed to occur on different timescales. This is true for the majority of the conduction band electrons in a metal. However,…

介观与纳米尺度物理 · 物理学 2019-06-05 Sebastian T. Weber , Baerbel Rethfeld

Due to its corrugated hexagonal lattice structure, Black phosphorus (BP) has unique anisotropic physical properties, which provides an additional freedom for designing devices. Many body interactions, including interactions with phonon, is…

化学物理 · 物理学 2019-07-23 Shengjie Meng , Hongyan Shi , Hu Jiang , Xiudong Sun , Bo Gao

The monolayer of black phosphorous, or phosphorene, has recently emerged as a new 2D semiconductor with intriguing highly anisotropic transport properties. Existing calculations of its intrinsic phonon-limited electronic transport…

材料科学 · 物理学 2015-06-24 Bolin Liao , Jiawei Zhou , Bo Qiu , Mildred S. Dresselhaus , Gang Chen

Ultrafast laser irradiation of solids leads to a thermodynamic nonequilibrium within and between the electron and phonon subsystems of the material. Due to electron-electron and phonon-phonon collisions, both subsystems relax into…

材料科学 · 物理学 2018-10-24 Isabel Klett , Baerbel Rethfeld

For over a century, x-ray scattering has been the most powerful tool for determining the equilibrium structure of crystalline materials. Deviations from perfect periodicity, for example due to thermal motion of the atoms, reduces the…

材料科学 · 物理学 2013-05-29 M. Trigo , Y. M Sheu , J. Chen , V. H. Vishwanath , T. Graber , R. Henning , D. A. Reis

Black phosphorus is emerging as a promising semiconductor for electronic and optoelectronic applications. To study fundamental carrier properties, we performed ultrafast femtosecond pump-probe spectroscopy on thin film black phosphorus…

介观与纳米尺度物理 · 物理学 2017-03-13 Vasudevan Iyer , Peide Ye , Xianfan Xu

While the vibrational thermodynamics of materials with small anharmonicity at low temperatures has been understood well based on the harmonic phonons approximation; at high temperatures, this understanding must accommodate how phonons…

材料科学 · 物理学 2015-10-20 Tian Lan

We investigate the ultrafast dynamics of photo-induced non-thermal lattice disorder in a polycrystalline aluminium thin film to elucidate transient short- and long-range lattice distortions, their thermalization and electron-phonon coupling…

材料科学 · 物理学 2026-01-06 Fernando Rodriguez Diaz , Kasra Amini

The electrons and phonons in metal films after ultra-short pulse laser heating are in highly non-equilibrium states not only between the electron sub-system and the phonon sub-system but also within the electron sub-system. An…

材料科学 · 物理学 2014-08-05 Jun Zhou , Nianbei Li , Ronggui Yang

We investigate from first-principles theory and experiment the generation of phonons on picosecond timescales and the relaxation of carriers in multiple conduction band valleys of photo-excited Ge by inter-valley electron-phonon scattering.…

介观与纳米尺度物理 · 物理学 2025-02-03 F. Murphy-Armando , É. D. Murray , I. Savić , M. Trigo , D. Reis , S. Fahy

The coupled nonequilibrium dynamics of electrons and phonons in monolayer MoS2 is investigated by combining first-principles calculations of the electron-phonon and phonon-phonon interaction with the time-dependent Boltzmann equation.…

材料科学 · 物理学 2021-02-12 Fabio Caruso

The femtosecond optical pump-probe technique was used to study dynamics of photoexcited electrons and coherent optical phonons in transition metals Zn and Cd as a function of temperature and excitation level. The optical response in time…

强关联电子 · 物理学 2009-11-11 Muneaki Hase , Kunie Ishioka , Jure Demsar , Kiminori Ushida , Masahiro Kitajima

Revived attention in black phosphorus (bP) has been tremendous in the past decade. While many photoinitiated experiments have been conducted, a cross-examination of bP's photocarrier and structural dynamics is still lacking. In this report,…

材料科学 · 物理学 2023-05-24 Mazhar Chebl , Xing He , Ding-Shyue Yang

Coupling between electrons and phonons (lattice vibrations) drives the formation of the electron pairs responsible for conventional superconductivity. The lack of direct evidence for electron-phonon coupling in the electron dynamics of the…

In recent years, phonon electron carrier dragging has emerged as an innovative approach for modulating energy transfer in low dimensional systems. In this Letter, we explore the fundamental mechanisms of electron-phonon coupling and the…

介观与纳米尺度物理 · 物理学 2025-06-10 Houssem Rezgui
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