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A laboratory study on the band profiles and band strengths of H2O in CO ice, and vice versa, is presented and interpreted in terms of two models. The results show that a mutual interaction takes place between the two species in the solid,…

H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent…

Context: HCOOH is one of the more common species in interstellar ices with abundances of 1-5% with respect to solid H2O. Aims: This study aims at characterizing the HCOOH spectral features in astrophysically relevant ice mixtures in order…

天体物理学 · 物理学 2009-11-13 S. E. Bisschop , G. W. Fuchs , A. C. A. Boogert , E. F. van Dishoeck , H. Linnartz

We measure the band strengths in the far-infrared region of interstellar ice analogs of astrophysically relevant species, such as H$_2$O, CO$_2$, CH$_3$OH, and NH$_3$, deposited at low temperature (8-10 $\mathrm{K}$), followed by warm-up,…

天体物理仪器与方法 · 物理学 2014-07-01 B. M. Giuliano , R. M. Escribano , R. Martín-Doménech , E. Dartois , G. M. Muñoz Caro

Context. The molecular composition of interstellar ice mantles is defined by gas-grain processes in molecular clouds, with the main components being $H_2O$, $CO$, and $CO_2$. $CH_3OH$ ice is detected towards the denser regions, where large…

星系天体物理 · 物理学 2021-08-25 B. Müller , B. M. Giuliano , M. Goto , P. Caselli

Infrared spectroscopic observations toward objects obscured by dense cloud material show that H$_2$O, CO and, likely, CO$_2$ are important constituents of interstellar ice mantles. In order to accurately calculate the column densities of…

天体物理学 · 物理学 2008-02-03 P. A. Gerakines , W. A. Schutte , J. M. Greenberg , Ewine F. van Dishoeck

Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…

天体物理学 · 物理学 2007-05-23 A. C. A. Boogert , P. Ehrenfreund

The abundances of ices in planetary environments have historically been obtained through measurements of near-infrared absorption features (lambda = 1.0-2.5 microns), and near-IR transmission measurements of materials present in the…

天体物理学 · 物理学 2009-11-10 P. A. Gerakines , J. J. Bray , A. Davis , C. R. Richey

Interstellar ices are largely composed of frozen water. It is important to derive fundamental parameters for H$_2$O ice such as absorption and scattering opacities for which accurate complex refractive indexes are needed. The primary goal…

天体物理仪器与方法 · 物理学 2023-12-20 W. R. M. Rocha , M. G. Rachid , M. K. McClure , J. He , H. Linnartz

NH3 and CH3OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH3CN and HCOOCH3. Despite a number of recent studies, little is known about their abundances in the…

The James Webb Space Telescope now enables the spectral study of ices with unprecedented sensitivity and angular resolution. Water ice plays a crucial role in the growth of grains and in planetary formation but its spatial distribution in…

地球与行星天体物理 · 物理学 2025-04-09 Laurine Martinien , Gaspard Duchêne , François Ménard , Ryo Tazaki , Karl. R. Stapelfeldt

N-bearing molecules (like N2H+ or NH3) are excellent tracers of high-density, low-temperature regions like dense cloud cores and could shed light into snowlines in protoplanetary disks and the chemical evolution of comets. However,…

星系天体物理 · 物理学 2023-12-01 S. Kakkenpara Suresh , F. Dulieu , J. Vitorino , P. Caselli

Solid-phase photo-processes involving icy dust grains greatly affect the chemical evolution of the interstellar medium by leading to the formation of complex organic molecules and by inducing photodesorption. So far, the focus of laboratory…

CO is one of the most abundant ice components on interstellar dust grains. When it is mixed with amorphous solid water (ASW) or located on its surface, an absorption band of CO at 2152 cm$^{-1}$ is always present in laboratory measurements.…

天体物理仪器与方法 · 物理学 2022-12-14 Jiao He , Giulia Perotti , Shahnewaz M. Emtiaz , Francis E. Toriello , Adwin Boogert , Thomas Henning , Gianfranco Vidali

The VUV absorption cross sections of most molecular solids present in interstellar ice mantles with the exception of H2O, NH3, and CO2 have not been reported yet. Models of ice photoprocessing depend on the VUV absorption cross section of…

太阳与恒星天体物理 · 物理学 2014-06-02 G. A. Cruz-Diaz , G. M. Munoz Caro , Y. -J. Chen , T. -S. Yih

We present observations of the stretching mode of 13CO2 ice along 13 lines of sight in the Galaxy, using the Short Wavelength Spectrometer on board of the Infrared Space Observatory. Remarkable variations are seen in the absorption band…

Infrared (IR) spectra of vapor-deposited amorphous water at low temperatures show two weak peaks at around 3720 and 3696 cm-1 assigned to free-OH stretching modes of two- and three-coordinated water molecules (so-called dangling OH bonds),…

星系天体物理 · 物理学 2024-07-11 Takeshi Hasegawa , Hiroto Yanagisawa , Takumi Nagasawa , Reo Sato , Naoki Numadate , Tetsuya Hama

Aims. This article aims to provide an alternative method of measuring the porosity of multi-phase composite ices from their refractive indices and of characterising how the abundance of a premixed contaminant (e.g., CO2) affects the…

UV irradiation of simple ices is proposed to efficiently produce complex organic species during star- and planet-formation. Through a series of laboratory experiments, we investigate the effects of the H2O concentration, the dominant ice…

星系天体物理 · 物理学 2015-05-19 Karin I. Oberg , Ewine F. van Dishoeck , Harold Linnartz , Stefan Andersson

Broad infrared emission features (e.g., at 3.3, 6.2, 7.7, 8.6, and 11.3 microns) from the gas phase interstellar medium have long been attributed to polycyclic aromatic hydrocarbons (PAHs). A significant portion (10%-20%) of the Milky Way's…

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