相关论文: The Jahn-Teller active fluoroperovskites $A\mathrm…
The Jahn-Teller distortion and the resulting orbital order usually cause some fascinating correlated electronic behaviors, and generally lead to antiferromagnetism in perovskite bulks. Here we demonstrate that the Jahn-Teller distortion…
We report on the magnetic and Mossbauer properties of polycrystalline HoFe1-xCrxO3 compounds. Magnetization data reveals the continuous tailoring of magnetic transition due to weakening of Ho3+ Fe3+ and Fe3+ Fe3+ interactions in the entire…
There is great interest in hybrid organic-inorganic materials such as metal-organic frameworks (MOFs). The compounds [C(NH$_{2}$)$_{3}$]M(HCOO)$_{3}$, where M=Cu$^{2+}$ or Cr$^{2+}$ are Jahn-Teller (JT) active ions, are MOF with perovskite…
We report on THz absorption spectroscopy combined with high magnetic fields of polycrystalline RCrO3 (R= Pr, Sm, Er) aiming understanding spin wave resonances at their low temperature magnetic phases. Our measurements show that the…
We report on the temperature dependent Raman spectroscopic studies of orthorombic distorted perovskite YCrO3 in the temperature range of 20-300K. Temperature dependence of DC-magnetization measurement under field cooled and zero field…
The Jahn-Teller effect in the charge-ordered (CO) state for La1-xCaxMnO3 (0.5<x<0.87) was studied by measuring the low-temperature powder x-ray diffraction, internal friction, and shear modulus. We find that the electron-lattice interaction…
The magnetic phase diagram of the perovskite-type Ti oxides as a function of the GdFeO3-type distortion is examined by using the Hartree-Fock analysis of a multiband d-p Hamiltonian from a viewpoint of competitions of the spin-orbit…
We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…
A detailed high-resolution, variable temperature powder diffraction study of the fluoro-perovskites NaFeF$_3$ and NaCoF$_3$ is performed to probe their orbital ordering transitions. Through analysis of the symmetry adapted macrostrains and…
The magnetic properties of polycrystaline La0.5Ba0.5CoO2.5+d (d = 0.44 and 0.485) where investigated using muon spin relaxation and bulk magnetization experiments. Below a Curie temperature of T_C = 160 K and 180 K, respectively, a magnetic…
We investigate the evolution of spin and orbital order in undoped LaMnO$_3$ under increasing temperature with a model including both superexchange and Jahn-Teller interactions. We used several cluster mean field calculation schemes and find…
Neutron and X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magnetic and structural phase transitions of the spinel system Fe1+xCr2-xO4(0.0<=x<=1.0). The temperature versus Fe…
We have studied a nearly stoichiometric insulating Y$_{0.97(2)}$Cr$_{0.98(2)}$O$_{3.00(2)}$ single crystal by performing measurements of magnetization, heat capacity, and neutron diffraction. Albeit that the YCrO$_3$ compound behaviors like…
We explore orbital dynamics in the spin liquid candidate Ba3CuSb2O9 using multi-frequency electron spin resonance. We prepared two high quality single crystals. The crystal with a slight copper deficiency shows a structural phase transition…
First- and second-harmonic dielectric susceptibilities are maidenly studied on Samarium Orthoferrite of mesoscopic/500 nm and nanoscopic/55 nm grainsizes. Magneto-electrically coupled to the antiferromagnetic and spin-reorientation…
$^{31}$P nuclear magnetic resonance (NMR) measurements have been carried out to investigate the magnetic properties and spin dynamics of Fe$^{3+}$ ($S$ = 5/2) spins in the two-dimensional triangular lattice (TL) compound…
Ca3CoMnO6 is composed of CoMnO6 chains made up of face-sharing CoO6 trigonal prisms and MnO6 octahedra. The structural, magnetic, and ferroelectric properties of this compound were investigated on the basis of density functional theory…
We have synthesized the novel material Na_2IrO_3 and studied its structure, transport, magnetic, and thermal properties using powder x-ray diffraction (PXRD), electrical resistivity, isothermal magnetization M versus magnetic field H,…
A-site ordered perovskites, CaCu$_3$B$_4$O$_{12}$, which are derivatives of conventional ABO$_3$ perovskites, exhibit varying electronic and magnetic properties. With the objective of examining the role of Cu in this work, we have studied…
In $A_{3}$Cr$_{2}$O$_{8}$, where $A$ = Sr or Ba, the Cr$^{5+}$ ions surrounded by oxygen ions in a tetrahedral coordination are Jahn-Teller active. The Jahn-Teller distortion leads to a structural transition and a related emergence of three…