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Scalar couplings of the form J I_1 \cdot I_2 between nuclei impart valuable information about molecular structure to nuclear magnetic-resonance spectra. Here we demonstrate direct detection of J-spectra due to both heteronuclear and…

原子物理 · 物理学 2015-05-13 M. P. Ledbetter , C. W. Crawford , A. Pines , D. E. Wemmer , S. Knappe , J. Kitching , D. Budker

Nuclear magnetic resonance (NMR) has enormous applications. Two-dimensional NMR is an essential technique to characterize correlations between nuclei and, hence, molecule structures. Towards the ultimate goal of single-molecule NMR,…

量子物理 · 物理学 2016-11-30 Wen-Long Ma , Ren-Bao Liu

Zero- to ultralow-field nuclear magnetic resonance (ZULF NMR) is a powerful version of NMR that allows studying molecules and their transformations in the regime dominated by intrinsic spin-spin interactions. While spin dynamics at zero…

We investigate nuclear magnetic resonance (NMR) in near-zero-field, where the Zeeman interaction can be treated as a perturbation to the electron mediated scalar interaction (J-coupling). This is in stark contrast to the high field case,…

We present experimental data and theoretical interpretation of NMR spectra of remotely magnetized samples, detected in an unshielded environment by means of a differential atomic magnetometer. The measurements are performed in an…

The field of zero- to ultralow-field (ZULF) nuclear magnetic resonance (NMR) is currently experiencing a rapid growth, owing to the progress in optical magnetometry, and also attractive features of ZULF NMR, such as low hardware cost and…

A diamond-based sensor utilizing nitrogen-vacancy (NV) center ensembles permits the analysis of micron-sized samples through NMR techniques at room temperature. Current efforts are directed towards extending the operating range of NV…

量子物理 · 物理学 2024-10-07 P. Alsina-Bolívar , A. Biteri-Uribarren , C. Munuera-Javaloy , J. Casanova

Despite its versatility and high chemical specificity, conventional NMR spectroscopy is limited in measurement throughput due to the need for high-homogeneity magnetic fields, necessitating sequential sample analysis, and bulky devices.…

仪器与探测器 · 物理学 2024-07-02 Blake Andrews , Matthew Lai , Zhen Wang , Norihisa Kato , Michael Tayler , Emanuel Druga , Ashok Ajoy

X-ray four-wave mixing signals generated in the $k_1 + k_2 - k_3$ phase-matching direction are simulated for N1s transitions in para-nitroanline and two-ring hydrocarbons disubstituted with an amine and a nitroso groups. The two-dimensional…

原子物理 · 物理学 2008-11-20 Igor V. Schweigert , Shaul Mukamel

Nuclear magnetic resonance spectroscopy with solid-state spin sensors is a promising pathway for the detection of nuclear spins at the micro- and nanoscale. Although many nanoscale experiments rely on a single sensor spin for the detection…

We propose two dimensional x-ray coherent correlation spectroscopy (2DXCS) for the study of interactions between core-electron and valence transitions. This technique might find experimental applications in the future when very high…

量子物理 · 物理学 2009-11-13 Igor V. Schweigert , Shaul Mukamel

Ensembles of nitrogen-vacancy (NV) centers are used as sensors to detect NMR signals from micron-sized samples at room temperature. In this scenario, the regime of large magnetic fields is especially interesting as it leads to a large…

量子物理 · 物理学 2023-04-04 C. Munuera-Javaloy , A. Tobalina , J. Casanova

Quantum sensors based on nitrogen-vacancy centers in diamond have emerged as a promising detection modality for nuclear magnetic resonance (NMR) spectroscopy owing to their micron-scale detection volume and non-inductive based detection. A…

We propose a scheme to have zero field magnetic resonance spectroscopy based on a nitrogen-vacancy center and investigate the new applications in which magnetic bias field might disturb the system under investigation. Continual driving with…

量子物理 · 物理学 2023-04-06 Linkai Zhao , Q. Chen

Chemical shifts and J-couplings are fundamental parameters in NMR spectroscopy as they provide structural information about molecules. Extracting these quantities from isotopes such as carbon or nitrogen results in reduced sensitivity due…

量子物理 · 物理学 2025-06-23 P. Alsina-Bolívar , J. Casanova

We propose a three-pulse coherent ultrafast optical technique that is particularly sensitive to two-exciton correlations. Two Liouville-space pathways for the density matrix contribute to this signal which reveals double quantum coherences…

介观与纳米尺度物理 · 物理学 2009-11-13 Lijun Yang , Shaul Mukamel

Two dimensional nuclear magnetic resonance (NMR) spectroscopy is one of the major tools for analysing the chemical structure of organic molecules and proteins. Despite its power, this technique requires long measurement times, which,…

Nuclear magnetic resonance (NMR) spectroscopy provides unparalleled access to molecular structure and dynamics but is traditionally limited by weak signal strength, requiring large sample volumes and high magnetic fields. Here, we…

应用物理 · 物理学 2026-04-29 Dileep Singh , Riley W. Hooper , Christoph Findler , Utsab Banerjee , Dominik B. Bucher

We quantify multiparticle quantum entanglement in a system of N two-level atoms interacting with a squeezed vacuum state of the electromagnetic field. We calculate the amount of quantum entanglement present among one hundred such two-level…

量子物理 · 物理学 2016-07-19 Ram Narayan Deb

We present NMR spectra of remote-magnetized deuterated water, detected in an unshielded environment by means of a differential atomic magnetometer. The measurements are performed in a $\mu$T field, while pulsed techniques are applied…

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