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Surface Enhanced Infrared Absorption (SEIRA) is an experimental method where trace amount of a compound can be detected with high sensibility. This high detection sensibility is the result of the interaction of the molecules with a…

Waveguide-integrated plasmonics is a growing field with many innovative concepts and demonstrated devices in the visible and near-infrared. Here, we extend this body of work to the mid-infrared for the application of surface-enhanced…

光学 · 物理学 2018-12-05 Daniel A. Mohr , Daehan Yoo , Che Chen , Mo Li , Sang-Hyun Oh

Enhanced light-matter interactions are the basis of surface enhanced infrared absorption (SEIRA) spectroscopy, and conventionally rely on plasmonic materials and their capability to focus light to nanoscale spot sizes. Phonon polariton…

We have combined atomic layer lithography and template stripping to produce a new class of substrates for surface-enhanced infrared absorption (SEIRA) spectroscopy. Our structure consists of a buried and U-shaped metal-insulator-metal…

光学 · 物理学 2022-04-19 Xiaoshu Chen , Cristian Ciracì , David R. Smith , Sang-Hyun Oh

We investigate local heat generation by molecules at the apex of polymer-embedded vertical antennas excited at resonant mid-infrared wavelengths, exploiting the surface enhanced infrared absorption (SEIRA) effect. The embedding of vertical…

We present a multiscale quantum mechanics/classical (QM/MM) approach for modeling surface-enhanced infrared absorption (SEIRA) spectra of molecules adsorbed on plasmonic nanostructures. The molecular subsystem is described at the density…

化学物理 · 物理学 2025-11-05 Sveva Sodomaco , Piero Lafiosca , Tommaso Giovannini , Chiara Cappelli

Mid-infrared spectroscopy offers powerful label-free molecular analysis capabilities but faces significant challenges when analyzing complex biological samples. Here, we present a transformative surface-enhanced infrared absorption…

The temperature increase and temperature gradients induced by mid-infrared laser illumination of vertical gold nanoantenna arrays embedded into polymer layers was measured directly with a photothermal expansion nanoscope. Nanoscale thermal…

Detecting trace molecules remains a significant challenge. Surface-enhanced infrared absorption (SEIRA) based on plasmonic nanostructures, particularly graphene, has emerged as a promising approach to enhance sensing sensitivity. While…

Surface-enhanced infrared absorption (SEIRA) spectroscopy exploits the field enhancement near nanophotonic structures for highly sensitive characterization of (bio)molecules. The vibrational signature observed in SEIRA spectra is typically…

An analytical theory for the surface-enhanced Raman optical activity (SEROA) with the magnetic response of the substrate particle has been presented. We have demonstrated that the SEROA signal is proportional to the magnetic polarizability…

光学 · 物理学 2017-12-27 Tong Wu , Xiuhui Zhang , Rongyao Wang , Xiangdong Zhang

Mid-infrared (mid-IR) spectroscopy offers unparalleled opportunities in sensing through chemically specific detection of molecular absorption fingerprints. Yet, its practical applications are limited by the weak light-matter interaction in…

New type of plasmonic nanoparticles - silver octopods that can be synthesized with a variety of shapes - have been demonstrated to show versatile optical response using the discrete dipole approximation. The octopods show a complex behavior…

介观与纳米尺度物理 · 物理学 2015-05-13 Ivan I. Naumov , Zhiyong Li , Alexander M. Bratkovsky

Surface-enhanced spectroscopy techniques are the method-of-choice to characterize adsorbed intermediates occurring during electrochemical reactions, which are crucial in realizing a green sustainable future. Characterizing species with low…

介观与纳米尺度物理 · 物理学 2023-07-21 Malo Duportal , Luca M. Berger , Stefan A. Maier , Andreas Tittl , Katharina Krischer

The absorption and emission spectrum arising from the vibrational motion of a molecule is mostly in the infrared region. These fingerprint absorptions of polar bonds enable us to acquire bond-specific chemical information from specimens.…

光学 · 物理学 2024-11-15 Govind Dayal , Dheeraj Pratap

Plasmonic detectors have the potential to provide a method of rapid spectroscopy without the need of moving mirrors or gratings. Previous measurements have demonstrated frequency tunable detection based on plasmonic excitations, however…

材料科学 · 物理学 2015-02-04 Che Jin Bae , Gottfried Strasser , Andrea G. Markelz

The short-wave infrared (SWIR) is an underexploited portion of the electromagnetic spectrum in metasurface-based nanophotonics despite its strategic importance in sensing and imaging applications. This is mainly attributed to the lack of…

Spectroscopic analysis of large biomolecules is critical in a number of applications, including medical diagnostics and label-free biosensing. Recently, it has been shown that Raman spectroscopy of proteins can be used to diagnose some…

光学 · 物理学 2017-11-28 S. Hamed Shams Mousavi , Ali A. Eftekhar , Amir H. Atabaki , Ali Adibi

We present the experimental realization of ordered arrays of hyper-doped silicon nanodisks, which exhibit a localized surface plasmon resonance. The plasmon is widely tunable in a spectral window between 2 and 5 $\mu$m by adjusting the free…

Silicon photonics in conjunction with complementary metal-oxide-semiconductor (CMOS) fabrication has greatly enhanced the development of integrated optical phased arrays. This facilitates a dynamic control of light in a compact form factor…

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