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In this article, a pioneering study is presented where the intermittent current interruption method is used to characterize the aging behavior of commercial lithium ion batteries. With a very resource-efficient implementation, this method…

化学物理 · 物理学 2021-11-09 Zeyang Geng , Torbjörn Thiringer , Matthew J. Lacey

Water-in-Salt-Electrolytes (WiSEs) are a promising class of next-generation electrolytes. Unlike classical dilute electrolytes or more conventional battery electrolytes, WiSEs are characterised by their super-concentrated salt concentration…

Lithium-ion batteries are recognised as a key technology to power electric vehicles and integrate grid-connected renewable energy resources. The economic viability of these applications is affected by the battery degradation during its…

应用物理 · 物理学 2020-07-07 Ahmed Gailani , Rehab Mokidm , Moaath El-Dalahmeh , Maad El-Dalahmeh , Maher Al-Greer

Some rate of oxidation and reduction side-reactions will inevitably coexist in most rechargeable batteries, contributing to reversible and irreversible self-discharge. While parasitic reduction traps electrons, parasitic oxidation donates…

化学物理 · 物理学 2026-02-17 Marco-Tulio F. Rodrigues

This paper proposes a hierarchical Bayesian model for probabilistic estimation of the electric vehicle battery capacity fade. Since the battery aging factors such as temperature, current, and state of charge are not fixed, and they change…

系统与控制 · 电气工程与系统科学 2019-11-05 Mehdi Jafari , Laura E. Brown , Lucia Gauchia

Currently, the characterization of electric energy storage units used for power system operation and planning models relies on two major assumptions: charge and discharge efficiencies, and power limits are constant and independent of the…

系统与控制 · 电气工程与系统科学 2024-12-20 Alvaro Gonzalez-Castellanos , David Pozo , Aldo Bischi

Accurately measuring the cycle lifetime of commercial lithium-ion batteries is crucial for performance and technology development. We introduce a novel hybrid approach combining a physics-based equation with a self-attention model to…

机器学习 · 计算机科学 2025-05-07 Constantin-Daniel Nicolae , Sara Sameer , Nathan Sun , Karena Yan

In this paper, a core-shell enhanced single particle model for iron-phosphate battery cells is formulated, implemented, and verified. Starting from the description of the positive and negative electrodes charge and mass transport dynamics,…

系统与控制 · 电气工程与系统科学 2022-09-26 Gabriele Pozzato , Aki Takahashi , Xueyan Li , Donghoon Lee , Johan Ko , Simona Onori

The electrical potential in a battery jumps at each electrode-electrolyte interface. We present a model for computing three-dimensional current and potential distributions, which accounts for such internal voltage jumps. Within the…

As a significant ingredient regarding health status, data-driven state-of-health (SOH) estimation has become dominant for lithium-ion batteries (LiBs). To handle data discrepancy across batteries, current SOH estimation models engage in…

机器学习 · 计算机科学 2022-09-02 Yan Qin , Chau Yuen , Xunyuan Yin , Biao Huang

Battery interfaces critically influence lithium-metal battery performance through their role in ion diffusion and dendrite formation. However, structural characterization of these interfaces has remained challenging due to limitations in…

材料科学 · 物理学 2025-05-08 Hyeongjun Koh , Eric Detsi , Eric A. Stach

Batteries are dynamic systems with complicated nonlinear aging, highly dependent on cell design, chemistry, manufacturing, and operational conditions. Prediction of battery cycle life and estimation of aging states is important to…

系统与控制 · 电气工程与系统科学 2024-10-11 Joachim Schaeffer , Giacomo Galuppini , Jinwook Rhyu , Patrick A. Asinger , Robin Droop , Rolf Findeisen , Richard D. Braatz

Rechargeable lithium metal batteries have been widely investigated recently, driven by the global trend for the electrification of transportation. Understanding the dynamics of lithium metal electrodeposition is crucial to design safe and…

材料科学 · 物理学 2022-07-15 Shoutong Jin , Linming Zhou , Yongjun Wu , Shang Zhu , Qilong Zhang , Hui Yang , Yuhui Huang , Zijian Hong

Amorphous silicon is a highly promising anode material for next-generation lithium-ion batteries. Large volume changes of the silicon particle have a critical effect on the surrounding solid-electrolyte interphase (SEI) due to repeated…

数值分析 · 数学 2024-09-12 Raphael Schoof , Giuseppe Fabian Castelli , Willy Dörfler

Dendrite growth is a long-standing challenge that has limited the applications of rechargeable lithium metal electrodes. Here, we developed a grand potential based nonlinear phase-field model to study the electrodeposition of lithium as…

材料科学 · 物理学 2018-09-12 Zijian Hong , Venkatasubramanian Viswanathan

A general framework to study the mechanical behaviour of a cylindrical silicon anode particle in a lithium ion battery as it undergoes lithiation is presented. The two-way coupling between stress and concentration of lithium in silicon,…

软凝聚态物质 · 物理学 2019-08-13 Jeevanjyoti Chakraborty , Colin P. Please , Alain Goriely , S. Jonathan Chapman

The solid-state diffusion coefficient of the electrode active material is one of the key parameters in lithium-ion battery modelling. Conventionally, this diffusion coefficient is estimated through the galvanostatic intermittent titration…

化学物理 · 物理学 2021-10-18 Zeyang Geng , Yu-Chuan Chien , Matthew J. Lacey , Torbjörn Thiringer , Daniel Brandell

In this work, we derive analytical expressions governing state-of-charge and current imbalance dynamics for two parallel-connected batteries. The model, based on equivalent circuits and an affine open circuit voltage relation, describes the…

系统与控制 · 电气工程与系统科学 2022-11-10 Andrew Weng , Sravan Pannala , Jason B. Siegel , Anna G. Stefanopoulou

To elucidate the role of fluoroethylene carbonate (FEC) as an additive in the standard carbonate-based electrolyte for Li-ion batteries, the solid electrolyte interphase (SEI) formed during electrochemical cycling on silicon anodes was…

Metal anodes provide the highest energy density in batteries. However, they still suffer from electrode/electrolyte interface side reactions and dendrite growth, especially under fast-charging conditions. In this paper, we consider a…

材料科学 · 物理学 2025-07-29 Hamed Taghavian , Viktor Vanoppen , Erik Berg , Peter Broqvist , Jens Sjölund