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The electrocaloric effect (ECE) offers a promising alternative to the traditional gas compressing refrigeration due to its high efficiency and environmental friendliness. The unusual negative electrocaloric effect refers to the adiabatic…

材料科学 · 物理学 2023-07-14 Xingyue Ma , Mingxing Chen , Jun-Ming Liu , Di Wu , Yurong Yang

The giant electro- and elasto-caloric effects in spin chain materials are predicted. The theory is based on the exact quantum mechanical solution of the problem. It is shown that the giant jumps in the entropy and the temperature caused by…

量子物理 · 物理学 2024-06-27 A. A. Zvyagin , V. V. Slavin

In acceptor doped ferroelectrics and in ferroelectric films and nanocomposites, defect dipoles, strain gradients, and the electric boundary conditions at interfaces and surfaces often impose internal bias fields. In this work we delicately…

材料科学 · 物理学 2018-09-05 Yang-Bin Ma , Bai-Xiang Xu , Karsten Albe , Anna Grünebohm

We use molecular dynamics with a first-principles-based shell model potential to study the electrocaloric effect (ECE) in lithium niobate, LiNbO$_3$, and find a giant electrocaloric effect along a line passing through the ferroelectric…

材料科学 · 物理学 2012-11-08 Maimon C. Rose , R. E. Cohen

Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…

材料科学 · 物理学 2015-05-18 Yang Bai , Guang-Ping Zheng , San-Qiang Shi

An atomistic effective Hamiltonian is used to investigate electrocaloric (EC) effects of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) relaxor ferroelectrics in its ergodic regime, and subject to electric fields applied along the pseudocubic [111]…

材料科学 · 物理学 2018-04-03 Zhijun Jiang , Y. Nahas , S. Prokhorenko , S. Prosandeev , D. Wang , Jorge Íñiguez , L. Bellaiche

The electrocaloric effect (ECE) in normal and relaxor ferroelectrics is investigated in the framework of a thermodynamic approach based on the Maxwell relation and a Landau-type free energy model. The static dielectric response of relaxors…

无序系统与神经网络 · 物理学 2015-05-20 R. Pirc , Z. Kutnjak , R. Blinc , Q. M. Zhang

A material with reversible temperature change capability under an external electric field, known as the electrocaloric effect (ECE), has long been considered as a promising solid-state cooling solution. However, electrocaloric (EC)…

We show that the electrocaloric (EC) effect -- e.g., the temperature change experienced by an insulator upon application of an electric bias -- lends itself to a straightforward interpretation when expressed as a Taylor series in the…

材料科学 · 物理学 2020-12-09 Mónica Graf , Jorge Íñiguez

There is a surge of interest in developing environmentally friendly cooling technology based on the solid--state electrocaloric effect (ECE). Here, we point out that negative ECE with a fast cooling rate ($\approx$10$^{11}$ K/s) can be…

材料科学 · 物理学 2018-02-07 Yubo Qi , Shi Liu , Aaron M. Lindenberg , Andrew M. Rappe

The electrocaloric (EC) effect is the reversible change in temperature and/or entropy of a material when it is subjected to an adiabatic electric field change. Our tight-binding calculations linked to Fermi statistics, show that the EC…

介观与纳米尺度物理 · 物理学 2021-01-11 Natalia Cortés , Oscar Negrete , Francisco J. Peña , Patricio Vargas

Physical nature of "giant" magnetocaloric and electrocaloric effects, MCE and ECE, is explained in terms of the new fundamentals of phase transitions, ferromagnetism and ferroelectricity. It is the latent heat of structural…

材料科学 · 物理学 2013-06-04 Vitaly J. Vodyanoy , Yuri Mnyukh

Recent progress on caloric effects are reviewed. The application of external stimuli such as magnetic field, hydrostatic pressure, uniaxial stress and electric field give rise respectively to magnetocaloric, barocaloric, elastocaloric and…

材料科学 · 物理学 2013-03-18 Lluis Manosa , Antoni Planes , Mehmet Acet

The electrocaloric effect (ECE) in BaTiO3 is simulated using two different first-principles based effective Hamiltonian molecular dynamics methods. The calculations are performed for a wide range of temperatures (30--900 K) and external…

材料科学 · 物理学 2013-11-12 Takeshi Nishimatsu , Jordan A. Barr , Scott P. Beckman

The magneto-caloric effect (MCE), which is the refrigeration based on the variation of the magnetic entropy, is of great interest in both technological applications and fundamental research. The MCE is quantified by the magnetic Gr\"uneisen…

Anomalous electrocaloric effect (ECE) with decreasing temperature upon application of an electric field is known to occur in antiferroelectrics (AFEs), and previous understanding refers to the field-induced canting of electric dipoles if…

材料科学 · 物理学 2022-12-28 Ningbo Fan , Jorge Íñiguez , L. Bellaiche , Bin Xu

\textit{Ab initio} quantum Monte Carlo (QMC) methods in principle allow for the calculation of exact properties of correlated many-electron systems, but are in general limited to the simulation of a finite number of electrons $N$ in…

统计力学 · 物理学 2021-04-21 Tobias Dornheim , Jan Vorberger

Solid-state cooling applications based on the electrocaloric (EC) effect are particularly promising from a technological point of view due to their downsize scalability and natural implementation in circuitry. However, EC effects typically…

材料科学 · 物理学 2023-07-19 César Menéndez , Claudio Cazorla

We describe magneto-, baro- and elastocaloric effects (MCEs, BCEs and eCEs) in materials which possess both discontinuous (first-order) and continuous (second-order) magnetic phase transitions. Our ab initio theory of the interacting…

材料科学 · 物理学 2020-06-03 Eduardo Mendive-Tapia , Julie B. Staunton

In the framework of solid-state cooling technology, four kinds of caloric effects, magnetocaloric (MC), electrocaloric (EC), barocaloric (BC) and elastocaloric (eC) effects, are compared in view of environment discussion and application…

材料科学 · 物理学 2016-04-21 Zhongjian Xie , Gael Sebald , Daniel Guyomar
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