相关论文: Magnetization steps in the molecular magnet Ni$_4$…
We investigate the spectroscopic magnetic excitations in molecular magnets with complex intermediate structure among the magnetic ions. Our approach consists in introducing a modified spin Hamiltonian that allows for discrete coupling…
We develop a structured theoretical framework used in our recent articles [Eur. Phys. J. B 92, 93 (2019) and Phys. Rev. B 101, 094427 (2020)] to characterize the unusual behavior of the magnetic spectrum, magnetization and magnetic…
We devise a formalism to investigate in a systematic way the spectroscopic magnetic excitations in molecular magnets. This consists in introducing a bilinear spin Hamiltonian that allows for discrete coupling parameters accounting for…
We investigate the bulk magnetic, electron paramagnetic resonance, and magneto-optical properties of {Ni4Mo12}, a magnetic molecule with antiferromagnetically coupled tetrahedral {Ni4Mo12} in a diamagnetic molybdenum matrix. The…
Magnetic properties of a tetrahedral "Ni_4" molecule are discussed in terms of the Heisenberg model, with magnetic anisotropy terms included, and on the basis of first-principle calculations within the density functional theory. It is shown…
Beginning with a Heisenberg spin Hamiltonian for the manganese ions in the Mn_12 Ac molecule, we find a number of low-energy states of the system. We use these states to solve the time-dependent Schrodinger equation and find the…
Magnetic excitations in a Ni$_4$ magnetic molecule were investigated by inelastic neutron scattering and bulk susceptibility ($\chi_\text{bulk}$) techniques. The magnetic excitation spectrum obtained from the inelastic neutron scattering…
We present a rigorous derivation of the orbital magnetization for interacting electrons within the self-consistent Hartree-Fock approximation. Our method also allows us to derive formulas for the orbital magnetic susceptibility. The results…
The dependence of the magnetic susceptibility on the magnetic field is investigated for the single molecular magnet [Mn(hfac)$_2$NITPh]$_6$. The spikes of the susceptibility detected in a magnetic field ranging from 90 T to 285 T are…
This chapter takes a microscopic view of quantum tunneling of magnetization (QTM) in single-molecule magnets (SMMs), focusing on the interplay between exchange and anisotropy. Careful consideration is given to the relationship between…
Recent magnetic measurements on tetra-nickel molecular magnets [Ni(hmp)(ROH)Cl]$_4$, where R=CH$_3$, CH$_2$CH$_3$, or (CH$_2$)$_2$C(CH$_3$)$_3$ and hmp$^-$ is the monoanion of 2-hydroxymethylpyridine, revealed a strong exchange bias prior…
We use synchrotron x-ray diffraction and electrical transport under pressure to probe both the magnetism and the structure of single crystal NiS2 across its Mott-Hubbard transition. In the insulator, the low-temperature antiferromagnetic…
We investigate the role of exchange bridges in molecular magnets. We explore their effects on the distribution of the valence electrons and their contribution to the exchange processes. The present study is focused on a spin-half dimer with…
The discovery of magnetic bistability in Mn$_{12}$ more than 20 years ago marked the birth of molecular magnetism, an extremely fertile interdisciplinary field and a powerful route to create tailored magnetic nanostructures. However, the…
We calculate the magnetization hysteresis for an ordered array of composite magnetic nanoparticles with a ferromagnetic (FM) core and an antiferromagnetic (AFM) shell, located on a triangular lattice and coupled via magnetostatic forces.…
This study examines the increasing complexity in the magnetic properties of small $n$ = 3, 4, 5, 6 spin-1/2 quantum rings. Using an exact diagonalization of the isotropic Heisenberg Hamiltonian with nearest and next-nearest neighbor…
We study the magnetization dynamics of a molecular magnet driven by static and variable magnetic fields within a semiclassical treatment. The underling analyzes is valid in a regime, when the energy is definitely lower than the anisotropy…
It is demonstrated that the magnetic interactions can be drastically different for nano-sized systems compared to those of bulk or surfaces. Using a real-space formalism we have developed a method to calculate non-collinear magnetization…
A new electronic structure principle, viz. the minimum magnetizability principle (MMP) has been proposed and also has been verified through ab initio calculations, to extend the domain of applicability of the conceptual density functional…
Magnetic structures and spin excitations are studied across the phase diagram of the geometrically frustrated S = 3/2 quantum antiferromagnet Cs2CoBr4 in magnetic fields applied along the magnetic easy axis, using neutron diffraction,…