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When a particle is placed in a material with a lower bulk melting temperature, intermolecular forces can lead to the existence of a premelted liquid film of the lower melting temperature material. Despite the system being below the melting…

软凝聚态物质 · 物理学 2020-07-06 Navaneeth K. Marath , John S. Wettlaufer

We study multicomponent liquids by increasing the mass of $15\%$ of the particles in a binary Kob-Andersen model. We find that the heavy particles have dual effects on the lighter particles. At higher temperatures, there is a significant…

软凝聚态物质 · 物理学 2024-07-30 Ehtesham Anwar , Palak Patel , Mohit Sharma , Sarika Maitra Bhattacharyya

While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…

材料科学 · 物理学 2022-11-03 Matthias Lerbinger , Armand Barbot , Damien Vandembroucq , Sylvain Patinet

Molecular dynamics simulations are performed for a supercooled simple liquid with changing the system size from N=108 to $10^4$ to examine possible finite-size effects. Although almost no systematic deviation is detected in the static pair…

软凝聚态物质 · 物理学 2007-05-23 Kang Kim , Ryoichi Yamamoto

We review the effect of water anomalies on the properties of low temperature water. When supercooled, liquids dynamical properties change drastically. Supercooled liquids undergo an at least exponential decrease of their diffusion…

软凝聚态物质 · 物理学 2020-01-14 V. Teboul , A. P. Kerasidou

The dynamics of supercooled liquids slow down and become increasingly heterogeneous as they are cooled. Recently, local structural variables identified using machine learning, such as "softness", have emerged as predictors of local…

软凝聚态物质 · 物理学 2024-06-11 Sean A. Ridout , Andrea J. Liu

We use molecular dynamic simulations to investigate the relation between the presence of packing defects in a glass-former and the spontaneous cooperative motions called dynamic heterogeneity. For that purpose we use a simple diatomic…

无序系统与神经网络 · 物理学 2017-05-24 Sonia Taamalli , Hafedh Belmabrouk , Vo Van Hoang , Victor Teboul

The anomalous properties of water in the supercooled state are numerous and well-known. Particularly striking are the strong changes in dynamic properties that appear to display divergences at temperatures close to -- but beyond -- the…

统计力学 · 物理学 2007-05-23 Francis W. Starr , Srikanth Sastry , Francesco Sciortino , H. E. Stanley

The existence of heterogeneity in the dynamics of supercooled liquids is believed to be one of the hallmarks of the glass transition. Intense research has been carried out in the past to understand the origin of this heterogeneity in…

软凝聚态物质 · 物理学 2020-07-01 Indrajit Tah , Smarajit Karmakar

Effect of two-particle correlations between impurities on the temperature of transition of a Fermi liquid in the superfluid or superconducting state is analyzed. It is shown, that correlations with a radius exceeding correlation length of…

超导电性 · 物理学 2015-05-19 I. A. Fomin

Light and heavy water show similar anomalies in thermodynamic and dynamic properties, with a consistent trend of anomalies occurring at higher temperature in heavy water. Viscosity also increases faster upon cooling in heavy water, causing…

化学物理 · 物理学 2024-05-16 Frédéric Caupin , Pierre Ragueneau , Bruno Issenmann

Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and influence nucleation and growth of…

材料科学 · 物理学 2018-05-09 Pei Zhang , Jason J. Maldonis , Ze Liu , Jan Schroers , Paul M. Voyles

When a multicomponent liquid composed of particles with random interactions is slowly cooled below the freezing temperature, the fluid reorganises in order to increase (decrease) the number of strong (weak) attractive interactions and…

软凝聚态物质 · 物理学 2019-07-24 Kulveer Singh , Yitzhak Rabin

We investigate dynamical heterogeneities in the collective relaxation of a concentrated microgel system, for which the packing fraction can be conveniently varied by changing the temperature. The packing fraction dependent mechanical…

软凝聚态物质 · 物理学 2011-05-31 David A. Sessoms , Irmgard Bischofberger , Luca Cipelletti , Véronique Trappe

Diffusivity, a measure for how rapidly a fluid self-mixes, shows an intimate, but seemingly fragmented, connection to thermodynamics. On one hand, the "configurational" contribution to entropy (related to the number of mechanically-stable…

统计力学 · 物理学 2007-05-23 Jeetain Mittal , Jeffrey R. Errington , Thomas M. Truskett

When we lower the temperature of a liquid, at some point we meet a first order phase transition to the crystal. Yet, under certain conditions it is possible to keep the system in its metastable phase and to avoid crystallization. In this…

统计力学 · 物理学 2009-05-12 Andrea Cavagna

We study supercooled dynamics in quantum hard-sphere liquid using quantum mode-coupling formulation. In the moderate quantum regime, classical cage effects lead to slower dynamics compared to strongly quantum regime, where tunneling…

统计力学 · 物理学 2021-02-03 Ankita Das , Eran Rabani , Kunimasa Miyazaki , Upendra Harbola

We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…

软凝聚态物质 · 物理学 2022-12-16 Camille Scalliet , Benjamin Guiselin , Ludovic Berthier

We introduce a new measure of the structure of a liquid which is the softness of the mean-field potential developed by us earlier. We find that this softness is sensitive to small changes in the structure. We then study its correlation with…

软凝聚态物质 · 物理学 2021-05-26 Manoj Kumar Nandi , Sarika Maitra Bhattacharyya

A characteristic property of many soft matter systems is an ultrasoft effective interaction between their structural units. This softness often leads to complex behavior. In particular, ultrasoft systems under pressure demonstrate…

软凝聚态物质 · 物理学 2019-09-19 V. A. Levashov , R. E. Ryltsev , N. M. Chtchelkatchev
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