相关论文: Unveiling the Interstitial Pressure Between Growin…
Ice-templating, also referred to as freeze-casting, is a process exploiting unidirectional crystallization of ice to structure macroporous materials from colloidal solutions. Commonly applied to inorganic and polymeric materials, we employ…
When materials freeze, they often undergo damage due to ice growth. Although this damage is commonly ascribed to the volumetric expansion of water upon freezing, it is usually driven by suction of water towards growing ice crystals. The…
The freezing of concentrated colloidal suspensions is a complex physical process involving a large number of parameters. These parameters provide unique tools to manipulate the architecture of freeze-cast materials at multiple length scales…
Dynamic and thermal processes regulate the structure of the multi-phase interstellar medium (ISM), and ultimately establish how galaxies evolve through star formation. Thus, to constrain ISM models and better understand the interplay of…
Freezing of ice has been largely reported from many aspects, especially its complex pattern formation. Ice grown from liquid phase is usually characteristic of lamellar morphology which plays a significant role in various domains. However,…
We present measurements of the diffusion-limited growth of ice crystals from water vapor at a temperature of -5 C, in air at a pressure of $p_{air}=1$ bar. Starting with thin, c-axis ice needle crystals, the subsequent growth morphologies…
In this work, we perform a systematic computer simulation study of ice premelting, and explore the thickness and structure of quasi-liquid layers formed at the interface of ice with substrates of different hydrophilicity. Our study shows…
In laboratory experiments we observe that ice particles (\leq100 \mu m) entrained in a low pressure atmosphere (~1 mbar) get trapped by temperature gradients between three reservoirs at different tempertature. Confining elements are a…
We investigate the ice-templating behaviour of alumina suspensions by in-situ X-rays radiography and tomography. We focus here on the formation and structure of the transitional zone, which takes place during the initials instants of…
Ice-templating is a simple materials processing and shaping route where the growth of crystals from a solvent template the porosity. Although the principles of ice-templating were established a long time ago, it has lured considerable…
Using statistical field theory supplemented with molecular dynamics simulations, we consider premelting on the surface of ice as a generic consequence of broken hydrogen bonds at the boundary between the condensed and gaseous phases. A…
Ice growth has attracted great attention for its capability of fabricating hierarchically porous microstructure. However, the formation of tilted lamellar microstructure during freezing needs to be reconsidered due to the limited control of…
Ice templating, also known as freeze casting, is a popular shaping route for macroporous materials. Over the past 15 years, it has been widely applied to various classes of materials, and in particular ceramics. Many formulation and process…
Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the freeze-out of molecules onto grains. The processing is caused by…
Ice growth from liquid phase has been extensively investigated in various conditions, especially for ice freely grown in undercooled water and aqueous solutions. Although unidirectional ice growth plays a significant role in sea ice and…
Crystal nucleation studies using hard-sphere and Lennard-Jones models have shown that the pressure within the nucleus is lower than that in the surrounding liquid. Here, we use the mechanical route to obtain it for an ice nucleus in…
It is generally recognized that the interstellar medium has a vast range of densities and temperatures. While these two properties are usually anticorrelated with each other, there are nevertheless variations in their product, i.e., the…
The process of formation for an ice crystal with elaborate, symmetrical patterns from the water vapor is usually complicated and the corresponding mechanism is still not clear. Here, we experimentally constructed the 3D tubular ice crystals…
Crystallization pressure drives deformation and damage in monuments, buildings and the Earth's crust. Even though the phenomenon has been known for 170 years there is no agreement between theoretical calculations of the maximum attainable…
We present neutron powder diffraction results which give unambiguous evidence for the formation of the recently identified new crystalline ice phase[Lobban et al.,Nature, 391, 268, (1998)], labeled ice XII, at completely different…