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Perturbed angular correlation spectroscopy combined with $ab-initio$ electronic structure calculations is used to unravel the structural phase transition path from the low-temperature polar structure to the high-temperature structural phase…

We provide a detailed study of the reflectivity of multiferroic TbMnO_3 for wave numbers from 40 cm^{-1} to 1000 cm^{-1} and temperatures 5 K < T < 300 K. Excitations are studied for polarization directions E || a, the polarization where…

强关联电子 · 物理学 2010-01-22 M. Schmidt , Ch. Kant , T. Rudolf , F. Mayr , A. A. Mukhin , A. M. Balbashov , J. Deisenhofer , A. Loidl

In this work structural refinement, complex impedance spectroscopy, and Raman spectroscopy have been investigated on Na$_{0.5}$(Bi$_{1-x}$Dy$_x$)$_{0.5}$TiO$_3$ (xDyNBT) ceramic systems. The pure NBT, 2DyNBT and 5DyNBT compounds crystallize…

We investigate the high-pressure phase transitions in BiFeO3 by single crystal and powder x-ray diffraction, as well as single crystal Raman spectroscopy. Six phase transitions are reported in the 0-60 GPa range. At low pressures, up to 15…

High-temperature and high-pressure experiments were conducted on columbite-type ZnNb2O6, reaching temperatures up to 873 K at ambient pressure and pressures up to 30 GPa at ambient temperature, respectively. Through systematic analysis…

Infrared reflection and transmission as a function of temperature have been measured on single crystals of Cu$_{3}$Bi(SeO$_{3}$)$_{2}$O$_{2}$Cl. The complex dielectric function and optical properties along all three principal axes of the…

材料科学 · 物理学 2015-06-05 K. H. Miller , P. W. Stephens , C. Martin , E. Constable , R. A. Lewis , H. Berger , G. L. Carr , D. B. Tanner

Powder X-ray diffraction (PXRD) and single-crystal neutron scattering were used to study in detail the structural properties of the Cs2CuCl(4-x)Br(x) series, good realizations of layered triangular antiferromagnets. Detailed…

PbZr0.52Ti0.48O3/La0.67Sr0.33MnO3(PZT/LSMO) bilayer with surface roughness ~ 1.8 nm thin films have been grown by pulsed laser deposition on LaAlO3(LAO) substrates. High remnant polarization (30-54 micro C/cm2), dielectric…

材料科学 · 物理学 2015-05-18 Sandra Dussan , Ashok Kumar , J. F. Scott , Ram S. Katiyar

Dielectric properties of BTZ-BCT ceramics were probed in the frequency range from 10 Hz to 100 THz in a broad temperature range (10-900 K). Polar soft phonon observed in infrared spectra softens with cooling, however below 500 K its…

材料科学 · 物理学 2016-12-13 S. Kamba , E. Simon , V. Skoromets , V. Bovtun , M. Kempa , J. Pokorny , M. Savinov , J. Koruza , B. Malic

Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition…

Recently, the possibility of a low-temperature non-cubic phase in BaZrO$_3$ has generated engaging discussions about its true ground state and the consequences on its physical properties. In this paper, we investigate the microscopic…

材料科学 · 物理学 2023-04-19 M. Sepliarsky , R. Machado , S. Tinte , M. G. Stachiotti

We present a comprehensive investigation into the physical properties of intermetallic ErPd$_2$Si$_2$, a compound renowned for its intriguing magnetic and electronic characteristics. We confirm the tetragonal crystal structure of…

Low temperature properties of BaZrO3 are revealed by combining experimental techniques (X-ray diffraction, neutron scattering and dielectric measurements) with theoretical first-principles-based methods (total energy and linear response…

材料科学 · 物理学 2009-11-11 A. R. Akbarzadeh , I. Kornev , C. Malibert , L. Bellaiche , J. M. Kiat

We report the temperature dependent x-ray powder diffraction of the FeAs-based superconductors in the range between 300 K and 95 K. In the case of NdOFeAs we have detected the structural phase transition from the tetragonal phase, with…

超导电性 · 物理学 2009-01-12 Alessandro Ricci , Michela Fratini , Antonio Bianconi

GdFe3(BO3)4 exhibits a structural phase transition at 156 K, antiferromagnetic order of the Fe3+ moments at 36 K followed by a spin reorientation phase transition at 9 K. The reorientation phase transition is studied through dielectric,…

强关联电子 · 物理学 2009-11-11 F. Yen , B. Lorenz , Y. Y. Sun , C. W. Chu , L. N. Bezmaternykh , A. N. Vasiliev

Effect of an internal chemical pressure on structural, optical, magnetic and electrical properties in Bi0.9RE0.1FeO3 Ceramics (RE =Gd3+,Tb3+,Dy3+)has been studied extensively. Some of the highlights are as follows; 1. Coexistence of…

材料科学 · 物理学 2012-06-26 T. Karthik , T. Durga Rao , A. Srinivas , Saket Asthana

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

Ab initio calculations show an antiferromagnetic-ferromagnetic phase transition around 9-10 GPa and a magnetic anomaly at 12 GPa in BiFeO3. The magnetic phase transition also involves a structural and insulator-metal transition. The G-type…

材料科学 · 物理学 2012-12-20 Hong-Jian Feng

Dielectric measurements on 0.65[Pb(Ni_1/3Nb_2/3)O_3]-0.35PbTiO_3 ceramic in the temperature range 90K to 470K shows a relaxor ferroelectric transition around 350K with a Vogel-Fulcher freezing temperature of 338K and appearance of a…

材料科学 · 物理学 2007-06-08 Satendra Pal Singh , Akhilesh Kumar Singh , Dhananjai Pandey , S. M. Yusuf

X-ray diffraction experiments were performed on polycrystalline and single-crystal specimens of Ce$_{2}$Fe$_{17}$ at temperatures between 10 K and 300 K. Below $T_{\mathrm{t}}$ = 118$\pm$2 K, additional weak superstructure reflections were…