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We predict a large in-plane polarization response to bending in a broad class of trigonal two-dimensional crystals. We define and compute the relevant flexoelectric coefficients from first principles as linear-response properties of the…

材料科学 · 物理学 2023-08-01 Matteo Springolo , Miquel Royo , Massimiliano Stengel

Understanding the nature of brittle failure in ferroelectric materials is essential, but difficult due to the complex interaction between mechanical and electrical concentrated fields near the crack tip. In this work, an extended…

材料科学 · 物理学 2024-05-22 Chang Liu , Yu Tan , Yong Zhang , Zhaoyi Liu , Takahiro Shimada , Xiangyu Li , Jie Wang

The large variety of complex electronic structure materials and their alloys, offer highly promising directions for improvements in thermoelectric (TE) power factors (PF). Their electronic structure contains rich features, referred to as…

材料科学 · 物理学 2023-11-08 Patrizio Graziosi , Neophytos Neophytou

We report a systematic and accurate approach for deriving the bulk free energy surface (FES), a function of temperature, polarization, and strain, from the first-principles density functional theory (DFT) of proper ferroelectrics. The core…

材料科学 · 物理学 2026-02-10 Pinchen Xie , Yixiao Chen , Xinyu Xu , Zhi Yao , Weinan E , Roberto Car

We study the effects of the uniaxial tensile strain and shear deformation as well as their combinations on the electronic properties of single-layer black phosphorene. The evolutions of the strain-dependent band gap are obtained using the…

Using the Landau-Ginzburg-Devonshire theory, an influence of the misfit strain and surface screening charges, as well as the role of the flexoelectric effect, have been studied by numerical modelling in the case of a rhombohedral lead…

材料科学 · 物理学 2021-04-13 I. S. Vorotiahin , A. N. Morozovska , E. A. Eliseev , Y. A. Genenko

Ferroelectric materials are established candidates for beyond complementary metal-oxide-semiconductor technology, owing to their non-volatile spontaneous electrical polarization. The recent boom in electric dipole texture engineering and…

材料科学 · 物理学 2026-01-29 Bixin Yan , Valentine Gillioz , Ipek Efe , Morgan Trassin

Changes in strain can be used to modify electronic and magnetic properties in crystal structures, to manipulate nanoparticles and cells, or to control chemical reactions. The magneto-elastic (ME) effect--the change of magnetic properties…

In the present thesis, a computational framework for the analysis of the deformation and damage phenomena occurring at the micro-scale of polycrystalline materials is presented. Micro-mechanics studies are commonly performed using the…

计算工程、金融与科学 · 计算机科学 2018-02-08 Vincenzo Gulizzi

Flexoelectricity is universal in all dielectrics, effective at high temperatures, and a promising transduction technique for nanoelectromechanical systems (NEMS). However, as flexoelectricity is still in its early stages, many aspects…

材料科学 · 物理学 2024-10-03 Daniel Moreno-Garcia , Luis Guillermo Villanueva

Relating microstructure to properties, electromagnetic, mechanical, thermal and their couplings has been a major focus of mechanics, physics and materials science. The majority of the literature focuses on deriving homogenized constitutive…

介观与纳米尺度物理 · 物理学 2011-12-30 P. Mohammadi , L. Liu , P. Sharma , R. V. Kukta

We have measured the bending-induced polarization of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals with compositions at the relaxor-ferroelectric phase boundary. The crystals display very large flexoelectricity, with flexocoupling coefficients an…

材料科学 · 物理学 2015-06-18 Jackeline Narvaez , Gustau Catalan

The effect of smooth shape changes of metallic nanoparticles on localized surface plasmon resonances is assessed with a boundary integral equation method. The boundary integral equation method allows compact expressions of nanoparticle…

介观与纳米尺度物理 · 物理学 2013-02-19 Titus Sandu

We have constructed the surface phase diagram of the BaTiO$_{3}$(001) surface by employing an evolutionary algorithm for surface structure prediction, where the ferroelectric polarization is included as a degree of freedom. Among over 1000…

材料科学 · 物理学 2015-12-09 Pengcheng Chen , Yong Xu , Na Wang , Artem R. Oganov , Wenhui Duan

In many cases the correct theoretical description of flexoelectricity requires the consideration of the finite size of a body and is reduced to the solution of boundary problems for partial differential equations. Generally speaking, in…

材料科学 · 物理学 2015-01-20 A. S. Yurkov

In this work we analyze the finite-size effects on the structural properties and on the polarization of the rhombohedral phase of HfO$_2$ subjected to a biaxial compressive strain. We show how the presence of surface charges affects the…

材料科学 · 物理学 2022-10-12 Francesco Delodovici , Paolo Barone , Silvia Picozzi

We reveal that strong flexoelectric effect of solids can be induced due to the signfi?cant charge migration along the strain gradient direction, which represents a new understanding of the origin of flexoelectricity. Beyond the linear…

材料科学 · 物理学 2020-08-27 Dong-Bo Zhang , Kai Chang

The recently discovered ferroelectric nematic liquids incorporate to the functional combination of fluidity, processability and anisotropic optical properties of nematic liquids, an astonishing range of physical properties derived from the…

Proximity ferroelectricity is a novel paradigm for inducing ferroelectricity in a non-ferroelectric polar material such as AlN or ZnO that are typically unswitchable with an external field below their dielectric breakdown field. When placed…

Relaxor-ferroelectrics display exceptional dielectric properties resulting from the underlying random dipolar fields induced by strong chemical inhomogeneity. An unusual structural aspect of relaxors is a skin-effect where the near-surface…