相关论文: Magnetic excitations in molecular magnets with com…
We devise a formalism to investigate in a systematic way the spectroscopic magnetic excitations in molecular magnets. This consists in introducing a bilinear spin Hamiltonian that allows for discrete coupling parameters accounting for…
We study the behavior of the magnetization and the magnetic susceptibility of molecular magnets with complex bridging structure. Our computations are based on a post-Hartree-Fock method accounting for the intricate network of interatomic…
Magnetic excitations in a Ni$_4$ magnetic molecule were investigated by inelastic neutron scattering and bulk susceptibility ($\chi_\text{bulk}$) techniques. The magnetic excitation spectrum obtained from the inelastic neutron scattering…
We study the magnetic excitations of the trimeric magnetic compounds A$_3$Cu$_3$(PO$_4$)$_4$ (A = Ca, Sr, Pb). The spectra are analyzed in terms of the Heisenberg model and a generic spin Hamiltonian that accounts for the changes in valence…
We investigate the role of exchange bridges in molecular magnets. We explore their effects on the distribution of the valence electrons and their contribution to the exchange processes. The present study is focused on a spin-half dimer with…
We develop a structured theoretical framework used in our recent articles [Eur. Phys. J. B 92, 93 (2019) and Phys. Rev. B 101, 094427 (2020)] to characterize the unusual behavior of the magnetic spectrum, magnetization and magnetic…
The tetrameric Ni(II) spin cluster Ni4Mo12 has been studied by INS. The data were analyzed extensively in terms of a very general spin Hamiltonian, which includes antiferromagnetic Heisenberg interactions, biquadratic 2-spin and 3-spin…
We have investigated magnetoelectric coupling in the single-molecule magnet $\mathrm{Mn}_{4}\mathrm{Te}_{4}(\mathrm{P}\mathrm{Et}_{3})_{4}$ with tetrahedral spin frustration. Our density functional studies found that an electric dipole…
We present results of inelastic neutron scattering experiments performed for the compound Magnetic and neutron spectroscopic properties of the tetrameric nickel compound $[Mo_{12}O_{28}(\mu_2-OH)_9(\mu_3-OH)_3{Ni(H_2O)_3}_4] $\cdot$…
Magnetic molecules are a class of compounds that is also investigated in view of their magnetocaloric properties. The isothermal entropy change and the adiabatic temperature change are key figures of merit for magnetocaloric performance.…
Inelastic neutron scattering experiments have been carried out on a powder sample of Cu2PO4OH, which consists of diamond-shaped tetramer spin units with S=1/2. We have observed two nearly dispersionless magnetic excitations at E1~12 and…
We performed inelastic neutron scattering experiment to study magnetic excitation of O$_2$ molecules adsorbed in microporous compound. The dispersionless excitation with characteristic intensity modulation is observed at $\hbar \omega =…
We investigate the bulk magnetic, electron paramagnetic resonance, and magneto-optical properties of {Ni4Mo12}, a magnetic molecule with antiferromagnetically coupled tetrahedral {Ni4Mo12} in a diamagnetic molybdenum matrix. The…
We investigate the magnetic properties of three Mn$_6$ single molecule magnets by means of inelastic neutron scattering and frequency domain magnetic resonance spectroscopy. The experimental data reveal that small structural distortions of…
Using detailed first principles calculations, we have found a new class of stable organic molecular magnets based on zwitterionic molecules possessing donor, $\pi$ bridge, and acceptor groups. These molecules are organic molecules…
We employ density functional theory within a non-collinear framework to investigate the magnetic properties of the octanuclear molecular rings Cr$_8$ and V$_8$. Our aim is to generalize the evaluation of the effective magnetic interactions…
The ability to electrically-drive spin excitations in molecules with magnetic anisotropy is key for high-density storage and quantum-information technology. Electrons, however, also tunnel via the vibrational excitations unique to a…
Recent magnetic measurements on tetra-nickel molecular magnets [Ni(hmp)(ROH)Cl]$_4$, where R=CH$_3$, CH$_2$CH$_3$, or (CH$_2$)$_2$C(CH$_3$)$_3$ and hmp$^-$ is the monoanion of 2-hydroxymethylpyridine, revealed a strong exchange bias prior…
Electron spin resonance and magnetization data in magnetic fields up to 55 T of a novel multicenter paramagnetic molecular complex [L_2Ni_4(N_3)(O_2C Ada)_4](Cl O_4) are reported. In this compound, four Ni centers each having a spin S = 1…
Magnetic excitations in a weakly coupled spin dimers and chains compound Cu2Fe2Ge4O13 are measured by inelastic neutron scattering. Both structure factors and dispersion of low energy excitations up to 10 meV energy transfer are well…