相关论文: Chlorine-bearing molecules in molecular absorbers …

We report the first extragalactic detection of chloronium (H2Cl+), in the z=0.89 absorber in front of the lensed blazar PKS1830-211. The ion is detected through its 1_11-0_00 line along two independent lines of sight toward the North-East…

We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight towards the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H35Cl and H37Cl, are observed using…

Using the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared (HIFI), we have observed para-chloronium (H2Cl+) toward six sources in the Galaxy. We detected interstellar chloronium absorption in foreground molecular…

We report additional detections of the chloronium molecular ion, H$_2$Cl$^+$, toward four bright submillimeter continuum sources: G29.96, W49N, W51, and W3(OH). With the use of the HIFI instrument on the Herschel Space Observatory, we…

Despite being only the 19th most abundant element in the interstellar medium, chlorine's reactivity and volatility give rise to a unique interstellar chemistry, favouring the formation of several chlorine-bearing hydrides. Further, the…

We report the first detection of chloronium, H$_2$Cl$^+$, in the interstellar medium, using the HIFI instrument aboard the \emph{Herschel} Space Observatory. The $2_{12}-1_{01}$ lines of ortho-H$_2^{35}$Cl$^+$ and ortho-H$_2^{37}$Cl$^+$ are…

Chlorine and molecular hydrogen are known to be tightly linked together in the cold phase of the local interstellar medium through rapid chemical reactions. We present here the first systematic study of this relation at high redshifts using…

We have revisited the chemistry of chlorine-bearing species in the diffuse interstellar medium with new observations of the HCl$^+$ molecular ion and new astrochemical models. Using the GREAT instrument on board SOFIA, we observed the…

The z=0.89 molecular absorber toward PKS1830-211 provides us with the opportunity to probe the chemical and physical properties of the interstellar medium in the disk of a galaxy at a look-back time of half the present age of the Universe.…

We present a comprehensive examination of interstellar P and Cl abundances based on an analysis of archival spectra acquired with the Space Telescope Imaging Spectrograph of the Hubble Space Telescope and the Far Ultraviolet Spectroscopic…

We report the detection of OH+ and H2O+ in the z=0.89 absorber toward the lensed quasar PKS1830-211. The abundance ratio of OH+ and H2O+ is used to quantify the molecular hydrogen fraction (fH2) and the cosmic-ray ionization rate of atomic…

We present the first detections of CH3SH, C3H+, C3N, HCOOH, CH2CHCN, and H2CN in an extragalactic source. Namely the spiral arm of a galaxy located at z=0.89 on the line of sight to the radio-loud quasar PKS 1830-211. OCS, SO2, and NH2CN…

Cl I is the atomic species most directly coupled to molecular hydrogen due to its chemistry. Its weakest lines are thereby probably the best tracer of optically thick H2 components in diffuse clouds. We report on the empirical determination…

Absorption lines at high redshift in front of quasars are rare in the mm domain. Only five associated and five intervening systems have been reported in the literature. These bring very useful information complementary to emission lines,…

Based on measurements with the Effelsberg 100-m telescope, a multi-line study of molecular species is presented toward the south-western source of the gravitational lens system PKS 1830-211, which is by far the best known target to study…

We present the first results of an ALMA spectral survey of strong absorption lines for common interstellar species in the z=0.89 molecular absorber toward the lensed blazar PKS1830-211. The dataset brings essential information on the…

With close pairs of quasars at different redshifts, a background quasar sightline can be used to study a foreground quasar's environment in absorption. We used a sample of 17 Lyman limit systems with column density N_HI > 10^19 cm^-2…

Context. Radio frequency molecular absorption lines appear along sight lines with AV well below 1 mag, revealing the presence of H2 in diffuse gas even when 2.6mm CO emission is absent. Aims. We discuss absorption lines of HCO+, C2H, HCN,…

The specific mass shift in the electron affinity between ^{35}Cl and ^{37}Cl has been determined by tunable laser photodetachment spectroscopy to be -0.51(14) GHz. The isotope shift was observed as a difference in the onset of the…

Chlorine (Cl) is a chemical element of the group of the halogens and is between the 17th and the 20th most abundant elements in the Solar System. It is thought to be produced from the capture of a proton or neutron by specific alpha-element…