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We study the segmental dynamics of poly(ethylene oxide) (PEO) from microscopic simulations in the neat polymer and a polymer electrolyte (PEO/LiBF$_4$) by analyzing the normal modes. We verify the applicability of the Rouse theory,…

软凝聚态物质 · 物理学 2008-04-15 Arijit Maitra , Andreas Heuer

The nanoscale fluctuation dynamics of semi dilute high molecular weight polymer solutions of Polyethylenoxide (PEO) in D2O under non-equilibrium flow conditions were studied by the neutron spin-echo technique. The sample cell was in…

流体动力学 · 物理学 2011-06-16 Maikel C. Rheinstadter , Rainer Sattler , Wolfgang Haeussler , Christian Wagner

Polymer solutions subject to pressure driven flow and in nanoscale slit pores are systematically investigated using the dissipative particle dynamics approach. We investigated the effect of molecular weight, polymer concentration and flow…

软凝聚态物质 · 物理学 2015-06-25 J. A. Millan , W. Jiang , M. Laradji , Y. Wang

The emergence of spatially variable local dynamics, or dynamic heterogeneity, is common in multicomponent polymer systems. Although often attributed to differences in the intrinsic dynamics of each component, the molecular origin of their…

软凝聚态物质 · 物理学 2025-10-23 Shannon Zhang , Michael A. Webb

We present results from a systematic numerical study of decaying turbulence in a dilute polymer solution by using a shell-model version of the FENE-P equations. Our study leads to an appealing definition of drag reduction for the case of…

统计力学 · 物理学 2009-11-10 Chirag Kalelkar , Rama Govindarajan , Rahul Pandit

We report results of a detailed experimental investigation into the drying of sessile droplets of aqueous poly(ethylene oxide) (PEO) polymer solutions under various experimental conditions. Samples are prepared with a range of initial…

软凝聚态物质 · 物理学 2011-05-11 Kyle Anthony Baldwin , Manon Granjard , David Willmer , Khellil Sefiane , David John Fairhurst

The effect of viscoelasticity on sprays produced from agricultural flat fan nozzles is investigated experimentally using dilute aqueous solutions of polyethylene oxide (PEO). Measurements of the droplet size distribution using laser…

流体动力学 · 物理学 2021-08-26 A. Gaillard , R. Sijs , D. Bonn

We present a new general model for the prediction of the drag coefficient of non-spherical solid particles of regular and irregular shapes falling in gas or liquid valid for sub-critical particle Reynolds numbers (i.e. $Re < 3 \times…

流体动力学 · 物理学 2018-10-23 Gholamhossein Bagheri , Costanza Bonadonna

We show that simulations of polymer rheology at a fluctuating mesoscopic scale and at the macroscopic scale where flow instabilities occur can be achieved at the same time with dissipative particle dynamics (DPD) technique.} We model the…

Molecular dynamics (MD) simulations of crystalline poly(ethylene oxide) (PEO) have been carried out in order to study its vibrational properties. The vibrational density of states has been calculated using a normal mode analysis (NMA) and…

材料科学 · 物理学 2009-11-10 M. Krishnan , S. Balasubramanian

The objective of this study is to understand the dynamics of freely evolving particle suspensions over a wide range of particle-to-fluid density ratios. The dynamics of particle suspensions are characterized by the average momentum…

流体动力学 · 物理学 2021-10-29 Vahid Tavanashad , Alberto Passalacqua , Shankar Subramaniam

Drag reduction by polymers in turbulent flows raises an apparent contradiction: the stretching of the polymers must increase the viscosity, so why is the drag reduced? A recent theory proposed that drag reduction in agreement with…

The phenomenon of drag reduction by polymer additives had been studied in simulations on the basis of non-Newtonian fluid mechanical models that take into account the field of polymer extension (conformation tensor) and its interaction with…

流体动力学 · 物理学 2009-11-10 Roberto Benzi , Emily S. C. Ching , Itamar Procaccia

We study the dynamics of a dilute solution of rigid rodlike polymers in a viscous fluid at low Reynolds number by means of numerical simulations of a simple rheological model. We show that the rotational dynamics of polymers destabilizes…

流体动力学 · 物理学 2022-11-11 Leonardo Puggioni , Guido Boffetta , Stefano Musacchio

We investigate the mechanisms by which inertial particles dispersed at semi-dilute conditions cause significant drag-reduction in a turbulent channel flow at $\mathrm{Re}_\tau = 180$. We consider a series of four-way coupled Euler-Lagrange…

流体动力学 · 物理学 2023-03-30 Himanshu Dave , M. Houssem Kasbaoui

Recent direct numerical simulations of the FENE-P model of non-Newtonian hydrodynamics revealed that the phenomenon of drag reduction by polymer additives exists (albeit in reduced form) also in homogeneous turbulence. We introduce here a…

流体动力学 · 物理学 2009-11-10 Roberto Benzi , Elisabetta De Angelis , Rama Govindarajan , Itamar Procaccia

Sessile droplets of aqueous poly(ethylene oxide) solution, with average molecular weight of 100 kDa, are monitored during evaporative drying at ambient conditions over a range of initial concentrations $c_0$. For all droplets with $c_0 \geq…

软凝聚态物质 · 物理学 2011-05-11 David Willmer , Kyle Anthony Baldwin , Charles Kwartnik , David John Fairhurst

The sliding of non-Newtonian drops down planar surfaces results in a complex, entangled balance between interfacial forces and non linear viscous dissipation, which has been scarcely inspected. In particular, a detailed understanding of the…

软凝聚态物质 · 物理学 2017-03-31 Silvia Varagnolo , Daniele Filippi , Giampaolo Mistura , Matteo Pierno , Mauro Sbragaglia

The Rouse model can be regarded as the standard model to describe the dynamics of a short polymer chain under melt conditions. In this contribution, we explicitly check one of the fundamental assumptions of this model, namely that of a…

软凝聚态物质 · 物理学 2014-10-14 Diddo Diddens , Andreas Heuer

We address the phenomenon of drag reduction by dilute polymeric additive to turbulent flows, using Direct Numerical Simulations (DNS) of the FENE-P model of viscoelastic flows. It had been amply demonstrated that these model equations…

混沌动力学 · 物理学 2007-05-23 Elisabetta De Angelis , Carlo M. Casciola , Victor S. L'vov , Renzo Piva , Itamar Procaccia
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