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The differential response of chiral molecules to incident left- and right- handed circularly polarized light is used for sensing the handedness of molecules. Currently, significant effort is directed towards enhancing weak differential…

We theoretically study circular dichroism of chiral molecules embedded inside a helicity-preserving Fabry-P\'erot cavity. We find an increase of the intrinsic chiroptical response of the molecules by 2 orders of magnitude and report the…

光学 · 物理学 2023-02-22 L. Mauro , J. Fregoni , J. Feist , R. Avriller

We derive a set of design requirements that lead to structures suitable for molecular circular dichroism (CD) enhancement. Achirality of the structure and two suitably selected sequentially incident beams of opposite helicity ensures that…

The ability to differentiate chiral molecules of different handedness is of great importance for chemical and life sciences. Since most of the relevant chiral molecules have their chiral transitions in the UV region, detecting their…

Circular dichroism (CD) is absorption difference of right-hand and left-hand circularly polarized light by components. CD spectroscopy technique is an important tool for detecting molecular chirality, but the molecular circular dichroism…

Polariton states with high levels of chiral dissymmetry offer exciting prospects for quantum information, sensing, and lasing applications. Such dissymmetry must emanate from either the involved optical resonators or the quantum emitters.…

化学物理 · 物理学 2022-09-28 Andrew H. Salij , Randall H. Goldsmith , Roel Tempelaar

Circular Dichroism (CD) can distinguish the handedness of chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest Thermal Circular Dichroism (TCD) for chiral…

光学 · 物理学 2024-07-19 Ershad Mohammadi , Giulia Tagliabue

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

The chiral state of a molecule plays a crucial role in molecular recognition and biochemical reactions. Because of this and owing to the fact that most modern drugs are chiral, the sensitive and reliable detection of the chirality of…

介观与纳米尺度物理 · 物理学 2019-04-30 Luisa M. Kneer , Eva-Maria Roller , Lucas V. Besteiro , Robert Schreiber , Alexander O. Govorov , Tim Liedl

We design, in a most simple way, Fabry-Perot cavities with longitudinal chiral modes by sandwiching between two smooth metallic silver mirrors a layer of polystyrene made planar chiral by torsional shear stress. We demonstrate that the…

光学 · 物理学 2021-05-19 Jérôme Gautier , Minghao Li , Thomas W. Ebbesen , Cyriaque Genet

Geometrical chirality is a universal property encountered on very different length scales ranging from geometrical shapes of living organisms to protein and DNA molecules. Interaction of chiral matter with chiral light - that is,…

光学 · 物理学 2022-01-25 Kirill Voronin , Alexey Taradin , Maxim V. Gorkunov , Denis G. Baranov

We consider the discriminatory interaction of a chiral molecule with circularly polarised modes inside a cavity. Starting from a generalised Jaynes--Cummings model that includes both electric and magnetic dipole couplings, we derive the…

Quantum metasurfaces, i.e., two-dimensional subwavelength arrays of quantum emitters, can be employed as mirrors towards the design of hybrid cavities, where the optical response is given by the interplay of a cavity-confined field and the…

量子物理 · 物理学 2024-04-26 Nico S. Bassler , Andrea Aiello , Kai P. Schmidt , Claudiu Genes , Michael Reitz

We present a scheme to realize precise discrimination of chiral molecules in a cavity. Assisted by additional laser pulses, cavity fields can evolve to different coherence states with contrary-sign displacements according to the handedness…

量子物理 · 物理学 2023-07-19 Yi-Hao Kang , Zhi-Cheng Shi , Jie Song , Yan Xia

Chiral perovskites owing to their broken mirror symmetry exhibit selective absorption of circularly polarized light manifesting a strong circular dichroism (CD). CD spectroscopy has been a key technique to understand chiral perovskites and…

材料科学 · 物理学 2026-02-10 Reshna Shrestha , Wanyi Nie

We derive here a new highly selective photoelectron-based chirality-sensing technique that utilizes 'locally-chiral' laser pulses. We show that this approach results in strong chiral discrimination, where the standard forwards/backwards…

化学物理 · 物理学 2021-07-14 Ofer Neufeld , Hannes Hübener , Angel Rubio , Umberto De Giovannini

Increasing the sensitivity of chiral spectroscopic techniques such as circular dichroism (CD) spectroscopy is a current aspiration in the research field of nanophotonics. Enhancing CD spectroscopy depends upon of two complementary…

We provide a theoretical framework based on classical electromagnetism, to describe optical properties of Fabry-P\'erot cavities, filled with multilayered and linear chiral materials. We find a formal link between transfer-matrix,…

光学 · 物理学 2024-03-15 L. Mauro , J. Fregoni , J. Feist , R. Avriller

Chiral molecules show differences in their chemical and optical properties due to different spatial arrangements of the atoms in the two enantiomers. A common way to optically differentiate them is to detect the disparity in the absorption…

We investigate how a periodic array composed of achiral isotropic high-refractive index dielectric nanospheres generates nearfield over the array surface reaching helicity density very close to its upper bound. The required condition for an…

应用物理 · 物理学 2020-04-03 Mina Hanifeh , Filippo Capolino
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