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The cyano radical (CN) is a key molecule across many different factions of astronomy and chemistry. Accurate, empirical rovibronic energy levels with uncertainties are determined for 8 doublet states of CN using the \Marvel{} (Measured…

太阳与恒星天体物理 · 物理学 2020-10-13 Anna-Maree Syme , Laura K. McKemmish

Accurate, experimental rovibronic energy levels, with associated labels and uncertainties, are reported for 11 low-lying electronic states of the diatomic \TiO\ molecule, determined using the \Marvel\ (Measured Active Rotational-Vibrational…

The carbon dimer, the $^{12}$C$_2$ molecule, is ubiquitous in astronomical environments. Experimental-quality rovibronic energy levels are reported for $^{12}$C$_2$, based on rovibronic transitions measured for and among its singlet,…

Rotation-vibration energy levels are determined for the electronic ground state of the acetylene molecule, $^{12}$C$_2$H$_2$, using the Measured Active Rotational-Vibrational Energy Levels (MARVEL) technique. 37,813 measured transitions…

The rovibronic structure of A$^2\Sigma^+$, B$^2\Pi$ and C$^2\Pi$ states of nitric oxide (NO)is studied with the aim of producing comprehensive line lists for its near ultraviolet spectrum. Empirical energy levels for the three electronic…

化学物理 · 物理学 2021-08-24 Qianwei Qu , Bridgette Cooper , Sergei N. Yurchenko , Jonathan Tennyson

The calcium monohydroxide radical (CaOH) is an important astrophysical molecule relevant to cool stars and rocky exoplanets, amongst other astronomical environments. Here, we present a consistent set of highly accurate rovibronic…

化学物理 · 物理学 2020-06-01 Y. Wang , A. Owens , J. Tennyson , S. N. Yurchenko

Zirconium oxide(ZrO) is an important astrophysical molecule that defines the S-star classification class for cool giant stars. Accurate, empirical rovibronic energy levels, with associated labels and uncertainties, are reported for 9…

The spectrum of dicarbon (C2) is important in astrophysics and for spectroscopic studies of plasmas and flames. The C2 spectrum is characterized by many band systems with new ones still being actively identified; astronomical observations…

An analysis of the measured rovibrational transitions is carried out for the 12C32S2 isotopologue of carbon disulfide. Data from 21 sources is extracted and validated using a consistent set of standard linear molecule quantum numbers. A…

原子物理 · 物理学 2025-02-28 Tanvi Sattiraju , Jonathan Tennyson

44325 measured and assigned transitions of H$_2^{32}$S, the parent isotopologue of the hydrogen sulfide molecule, are collated from 33 publications into a single database and reviewed critically. Based on this information,…

Silicon mononitride ($^{28}$Si$^{14}$N, $^{29}$Si$^{14}$N, $^{30}$Si$^{14}$N, $^{28}$Si$^{15}$N) line lists covering infrared, visible and ultraviolet regions are presented. The \name\ line lists produced by ExoMol include rovibronic…

地球与行星天体物理 · 物理学 2022-10-25 Mikhail Semenov , Nicholas Clark , Sergei N. Yurchenko , Gap-Sue Kim , Jonathan Tennyson

An optimal set of 1050 rovibronic energy levels for 35 triplet electronic states of $D_2$ has been obtained by means of a statistical analysis of all available wavenumbers of triplet-triplet rovibronic transitions studied in emission,…

光学 · 物理学 2008-02-08 B. P. Lavrov , I. S. Umrikhin

A semi-empirical IR/Vis line list, SOLIS, for the sulphur monoxide molecule $^{32}$S$^{16}$O is presented. SOLIS includes accurate empirical rovibrational energy levels, uncertainties, lifetimes, quantum number assignments, and transition…

地球与行星天体物理 · 物理学 2023-12-18 Ryan P. Brady , Sergei N. Yurchenko , Jonathan Tennyson , Gap-Sue Kim

Optimal set of 1050 rovibronic energy levels for 35 triplet electronic states of $D_2$ has been obtained by means of a statistical analysis of all available wavenumbers of triplet-triplet rovibronic transitions studied in emission,…

光学 · 物理学 2009-11-13 B. P. Lavrov , I. S. Umrikhin

Comprehensive and accurate rovibronic line lists for the X $^{1}\Sigma^{+}$ and A $^{1}\Pi$ states of $^{12}$C$^{1}$H$^{+}$ and $^{13}$C$^{1}$H$^{+}$ which should be applicable up to temperatures of 5000 K are presented. Available empirical…

太阳与恒星天体物理 · 物理学 2023-08-09 Oliver Pearce , Sergei N. Yurchenko , Jonathan Tennyson

Carbon monoxide is thought to be the second most abundant molecule in the Universe. This makes observation of both its parent isotopologue ($^{12}$C$^{16}$O) and its stable isotopologues, $^{13}$C$^{16}$O, $^{12}$C$^{18}$O,…

星系天体物理 · 物理学 2026-01-21 Timur Grigorev , Yuhang Dai , Max Potter , Xiaoyu Xiang , Keyu Zhang , Jonathan Tennyson

Line lists for the ground electronic ground state for six major isotopologues of nitric oxide are presented. The line lists are constructed using empirical energy levels (and line positions) and high-level {\it ab inito} intensities. The…

地球与行星天体物理 · 物理学 2017-06-28 Andy Wong , Sergei N. Yurchenko , Peter Bernath , Holger S. P. Müller , Stephanie McConkey , Jonathan Tennyson

Published high-resolution rotation-vibration transitions of \spec{h212c16o}, the principal isotopologue of methanal, are analyzed using the MARVEL (Measured Active Rotation-Vibration Energy Levels) procedure. The literature results are…

Previously-determined empirical energy levels are used to construct a rovibronic model for the $\mathrm{X}\,^4\Sigma^-$, $\mathrm{A}'\,^4\Phi$, $\mathrm{A}\,^4\Pi$, $\mathrm{B}\,^4\Pi$, $\mathrm{C}\,^4\Sigma^-$, $\mathrm{D}\,^4\Delta$,…

化学物理 · 物理学 2023-01-25 Qianwei Qu , Sergei N. Yurchenko , Jonathan Tennyson

An accurate line list, called XABC, is computed for nitric oxide which covers its pure rotational, vibrational and rovibronic spectra. A mixture of empirical and theoretical electronic transition dipole moments are used for the final…

地球与行星天体物理 · 物理学 2021-08-24 Qianwei Qu , Sergei N. Yurchenko , Jonathan Tennyson
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