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Using the apical oxygen doping mechanism, i.e. a partial substitution of divalence O for the monovalence Cl, a p-type oxychloride cuprate superconductor, Sr2CuO2+xCl2-y, was synthesized at high pressure high temperature. The x-ray…

超导电性 · 物理学 2009-11-11 Q. Q. Liu , X. M. Qin , Y. Yu , F. Y. Li , C. Dong , C. Q. Jin

The CO2 emissions from major industries cause serious global environment problems and their mitigation is urgently needed. The use of zeolite membranes is a very efficient way in order to capture CO2 from some flue gases. The dominant…

In this paper, we demonstrate a proof-of-concept oxygen sensor based on the thermoelectric principle using polycrystalline $GdBaCo_2O_{5+\delta}$ where 0.45<${\delta}$<0.55 (GDCO). The lattice oxygen in layered double perovskite oxides is…

材料科学 · 物理学 2022-09-07 Soumya Biswas , Madhujith M K , Vinayak Kamble

We investigate the dynamics of water confined in soft ionic nano-assemblies, an issue critical for a general understanding of the multi-scale structure-function interplay in advanced materials. We focus in particular on hydrated…

材料科学 · 物理学 2017-08-23 Quentin Berrod , Samuel Hanot , Armel Guillermo , Stefano Mossa , Sandrine Lyonnard

This study investigates the prospect of using reduced graphene oxide encapsulated between thin wood membranes as a composite filter for water filtration. Graphene oxide (GO) with a volume range of 0.2 to 0.5 mL was deposited on a 95 mm2…

Although 2D materials hold great potential for next-generation pressure sensors, recent studies revealed that gases permeate along the membrane-surface interface that is only weakly bound by van der Waals interactions, necessitating…

In this study, we use the density functional theory (DFT) calculations and the molecular dynamics (MD) simulations to investigate the performance of graphenylene--1 membrane for hydrogen ($H_2$) purification and helium ($He$) separation.…

材料科学 · 物理学 2020-03-18 Parham Rezaee , Hamid Reza Naeij

Although they were first synthesized in chemistry laboratories nearly fifty years ago, the physical properties of the metals PdCoO2, PtCoO2 and PdCrO2 have only more recently been studied in detail. The delafossite structure contains…

强关联电子 · 物理学 2017-01-25 Andrew P Mackenzie

The dimpling in the CuO_2 planes of overdoped Y_{1-y}Ca_yBa_2Cu_3 O_{6.96-6.98} (y=0.02-0.2) has been measured by x-ray absorption-fine- structure spectroscopy (Y-K EXAFS). A step-like decrease around 12% Ca indicates a percolation…

超导电性 · 物理学 2009-10-31 J. Röhler , C. Friedrich , T. Granzow , E. Kaldis , G. Böttger

Single phase cobalt ferrite (CoFe2O4, CFO) nanoparticles of a controlled size (~ 6 nm) exhibiting superparamagnetic properties have been synthesized by hydrothermal technique using oleic acid (OA) as surfactant. The oleic acid coated CFO…

材料科学 · 物理学 2017-01-06 Sandeep Munjal , Neeraj Khare , Chetan Nehate , Veena Koul

Perovskite-type iron oxides with Fe4+ ions have attracted much attention for their versatile helimagnetic phases. While the introduction of a layered A-site ordered structure to AFeO3 with Fe4+ ions potentially lead to novel helimagnetic…

Transition-metal perovskite oxides constitute a series of functional material systems for electronics, catalysis and energy-conversion processes, in which oxygen migration and evolution play a key role. However, the stable metal-oxygen…

材料科学 · 物理学 2021-11-02 Qian Wang , Youdi Gu , Wenxuan Zhu , Lei Han , Feng Pan , Cheng Song

We design an all-carbon membrane for the filtration and desalination of water. A unique layered assembly of carbon nanostructures including graphite oxide (GO), buckypaper consisting of carbon nanotubes, and a strong carbon fabric provides…

材料科学 · 物理学 2019-09-04 David Tománek , Andrii Kyrylchuk

Three Mo-based transition metal dichalcogenides MoS$_2$, MoSe$_2$ and MoTe$_2$ share at ambient conditions the same structure 2H$_c$, consisting of layers where Mo atoms are surrounded by six chalcogen atoms in trigonal prism coordination.…

材料科学 · 物理学 2017-02-15 Oto Kohulák , Roman Martoňák

We demonstrated the lattice structures and the superconducting phases of metallic double-chain based cuprate Pr2Ba4Cu7O15-delta exhibiting higher Tc. After the oxygen heat treatment on citrate pyrolysis precursors, their reduction treatment…

Metal-organic frameworks (MOFs) have emerged as promising materials for carbon capture applications due to their high CO2 capacities and tunable properties. Amongst the many possible MOFs, metal-substituted compounds based on M-DOBDC and…

材料科学 · 物理学 2016-03-11 Hyun Seung Koh , Malay Kumar Rana , Jinhyung Hwang , Donald J. Siegel

We report on the preparation and characterization of single crystal gamma phase NaxCoO2 with 0.25 < x < 0.84 using a non-aqueous electrochemical chronoamperemetry technique. By carefully mapping the overpotential versus x (for x < 0.84), we…

强关联电子 · 物理学 2009-11-13 G. J. Shu , Andrea Prodi , S. Y. Chu , Y. S. Lee , H. S. Sheu , F. C. Chou

Experimental evidences have shown that graphene oxide (GO) can be impermeable to liquids, vapors and gases, while it allows a fast permeation of water molecules. The understanding of filtration mechanisms came mostly from studies dedicated…

介观与纳米尺度物理 · 物理学 2017-06-21 Daiane Damasceno Borges , Cristiano F. Woellner , Pedro A. S. Autreto , Douglas S. Galvao

La0.6Sr0.4Fe0.8Mn0.2O3 (LSFM) compound is synthesized by Sol-gel method and evaluated as a cathode material for the intermediate temperature solid oxide fuel cell (IT-SOFC). X-ray diffraction (XRD) indicates that the LSFM has a Rhombohedral…

应用物理 · 物理学 2019-10-22 F. Yadollahi Farsani , M. Jafari , E. Shahsavari , H. Salamati

The 5d pyrochlore oxide superconductor Cd2Re2O7 (CRO) has attracted significant interest as a spin-orbit-coupled metal (SOCM) that spontaneously undergoes a phase transition to an odd-parity multipole phase by breaking the spatial inversion…

强关联电子 · 物理学 2023-09-18 Daigorou Hirai , Atsuhito Fukui , Hajime Sagayama , Takumi Hasegawa , Zenji Hiroi