相关论文: Voltage matching, \'etendue and ratchet steps in a…
Intermediate Band Solar Cell is an advanced concept for solar energy conversion in which two low-energy photons can promote an electron to the conduction band through a so-called intermediate band. To limit recombination and preserve the…
We investigate in this letter the intrinsic properties that have limited the efficiency of nanostructured intermediate band solar cells. Those devices take advantage of intra-band transitions, which occur on narrow energy width, and present…
The theoretical maximum efficiency of a solar cell is typically characterized by a detailed balance of optical absorption and emission for a semiconductor in the limit of unity radiative efficiency and an ideal step-function response for…
A semiconductor structure consisting of two coupled quantum wells embedded into the intrinsic region of a {\it p-i-n} junction is proposed to be implemented as an intermediate band solar cell with ratchet state. The localized conduction…
The ideal solar cell conversion efficiency limit known as the Shockley-Queisser (SQ) limit, which is based on a detailed balance between absorption and radiation, has long been a target for solar cell researchers. While the theory for this…
The Shockley-Queisser (SQ) limit provides a convenient metric for predicting light-to-electricity conversion efficiency of a solar cell based on the band gap of the light-absorbing layer. In reality, few materials approach this radiative…
The intermediate band solar cell (IBSC) and quantum ratchet solar cell (QRSC) have the potential to surpass the efficiency of standard single-junction solar cells by allowing sub-gap photon absorption through states deep inside the band…
The Shockley-Queisser limit is one of the most fundamental results in the field of photovoltaics. Based on the principle of detailed balance, it defines an upper limit for a single junction solar cell that uses an absorber material with a…
Photovoltaic materials are recognized for their potential as sustainable energy sources that enable the conversion between light and electrical energy. However, solar cells have been unable to surpass the theoretical limit of 32%, known as…
In a recent paper, Guillemoles et al [J.F. Guillemoles, T. Kirchartz, D. Cahen and U Rau, Guide for the perplexed to the Shockley-Queisser model for solar cells, Nat. Photonics, 13, 501 (2019)] attempt to clarify and explain the often cited…
The Shockley-Queisser (SQ) limit, introduced by W. Shockley and H. J. Queisser in 1961, is the most well-established fundamental efficiency limit for single-junction photovoltaic solar cells. For widely-studied semiconductors such as Si,…
Creating a single bandgap solar cell that approaches the Shockley-Queisser limit requires a highly reflective rear mirror. This mirror enhances the voltage of the solar cell by providing photons with multiple opportunities for escaping out…
Tandem solar cells are at the forefront of extending the efficiency limits of solar cell technology. Among two-terminal tandems, current-matched (CM) tandem solar cells are of particular interest, owing to their relative ease of…
The spin-split indirect bandgap in hybrid-halide perovskites provides a momentum-space realisation of a photon-ratchet intermediate band. Excited electrons thermalise to recombination-protected Rashba pockets offset in momentum space,…
Maximum efficiency of ideal single-junction photovoltaic (PV) cells is limited to 33% (for one sun illumination) by intrinsic losses such as band edge thermalization, radiative recombination, and inability to absorb below-bandgap photons.…
The Shockley-Queisser (S-Q) theory defines the thermodynamic upper limits for Jsc, Voc, FF, and efficiency of a solar cell. The classical calculation assumes an abrupt onset of absorption at the band-edge, perfect absorption for all…
We employ a detailed balance approach to model a single-junction solar cell with a realistic narrow-band, non-unity-quantum-yield upconverter. As upconverter bandwidths are increased from 0 to 0.5 eV, maximum cell efficiencies increase from…
The fundamental efficiency limit of a single bandgap solar cell is about 31% at one sun with a bandgap of about Eg = 1.35 eV (1), determined by the trade-off of maximising current with a smaller bandgap and voltage with a larger bandgap.…
We argue that alternating-layer structures of lattice mismatched or misaligned (twisted) atomically-thin layers should be expected to be more efficient absorbers of the broad-spectrum of solar radiation than the bulk material of each…
The Shockley-Queisser limit describes the maximum solar energy conversion efficiency achievable for a particular material and is the standard by which new photovoltaic technologies are compared. This limit is based on the principle of…