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Photoelectron circular dichroism results from one-photon ionization of chiral molecules by circularly polarized light and manifests itself in forward-backward asymmetry of electron emission in the direction orthogonal to the light…

原子物理 · 物理学 2019-04-24 Andres F. Ordonez , Olga Smirnova

Photoelectron circular dichroism refers to the forward/backward asymmetry in the photoelectron angular distribution with respect to the propagation axis of circularly polarized light. It has recently been demonstrated in femtosecond…

量子物理 · 物理学 2017-01-16 R. E. Goetz , T. A. Isaev , B. Nikoobakht , R. Berger , C. P. Koch

Photoelectron circular dichroism results from one-photon ionization of chiral molecules by circularly polarized light and manifests itself in forward-backward asymmetry of electron emission in the direction orthogonal to the light…

原子物理 · 物理学 2019-04-24 Andres F. Ordonez , Olga Smirnova

Chiral molecules ionized by circularly polarized fields produce a photoelectron current orthogonal to the polarization plane. This current has opposite directions for opposite enantiomers and provides an extremely sensitive probe of…

原子物理 · 物理学 2022-06-28 Andres F. Ordonez , Olga Smirnova

Using a model methane-like chiral system, we theoretically demonstrate a possibility to access photoelectron circular dichroism (PECD) by a single experiment with two overlapping laser pulses of carrier frequencies $\omega$ and $2\omega$,…

原子与分子团簇 · 物理学 2018-12-20 Philipp V. Demekhin , Anton N. Artemyev , Alexander Kastner , Thomas Baumert

Measuring and controlling the ionization dynamics by intense laser fields has recently led to important breakthroughs, from the investigation of tunneling time delays to attosecond molecular imaging by electron holography. In these…

The angular distribution of the emitted electrons, following the two--photon ionization of the hydrogen--like ions, is studied within the framework of second order perturbation theory \textit{and} the Dirac equation. Using a density matrix…

原子物理 · 物理学 2007-05-23 Peter Koval , Stephan Fritzsche , Andrey Surzhykov

We show that the combination of two achiral components - atomic or molecular target plus a circularly polarized photon - can yield chirally structured photoelectron angular distributions. For photoionization of CO, the angular distribution…

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

We study the origin of dichroic effects in elastic scattering of high energy electrons by hydrogen atoms in the presence of a two-color bicircular laser field of commensurate frequencies, in the domain of moderate intensities below 10…

原子物理 · 物理学 2023-09-27 Gabriela Buica

The angular distribution of the emitted electrons, following the two-photon ionization of the hydrogen-like ions, is studied within the framework of second order perturbation theory and the Dirac equation. Using a density matrix approach,…

原子物理 · 物理学 2007-05-23 Peter Koval , Stephan Fritzsche , Andrey Surzhykov

Photoelectron angular distributions following the non-resonant two-photon K-shell ionization of neutral atoms are studied theoretically. Using the independent particle approximation and relativistic second-order perturbation theory, the…

原子物理 · 物理学 2017-07-14 J. Hofbrucker , A. V. Volotka , S. Fritzsche

We show that a nonchiral atom can act as an antenna to induce a photoelectron circular dichroism in a nearby chiral molecule in a three-step process: The donor atom (antenna) is initially resonantly excited by circularly polarized…

原子与分子团簇 · 物理学 2025-05-14 Stefan Yoshi Buhmann , Andreas Hans , Janine C. Franz , Philipp V. Demekhin

Strong-field ionization by counter-rotating two-color laser fields produces quantum interference between photoelectrons emitted on the leading and trailing edges of the laser field oscillations. We show that in chiral molecules, this…

Chiral light-matter interactions have been investigated for two centuries, leading to the discovery of many chiroptical processes used for discrimination of enantiomers. Whereas most chiroptical effects result from a response of bound…

We consider few-photon ionization of atomic lithium by linearly polarized femtosecond laser pulses, and demonstrate that asymmetries of the electron angular distribution can occur for initially polarized (2p, m=+1) target atoms. The…

Elliptical dichroism is known in atomic photoionization as the difference in the photoelectron angular distributions produced in nonlinear ionization of atoms by left- and right-handed elliptically polarized light. We theoretically…

原子物理 · 物理学 2018-08-07 J. Hofbrucker , A. V. Volotka , S. Fritzsche

Photoelectron angular distributions of the two-photon ionization of neutral atoms are theoretically investigated. Numerical calculations of two-photon ionization cross sections and asymmetry parameters are carried out within the…

原子物理 · 物理学 2020-10-22 J. Hofbrucker , L. Eiri , A. V. Volotka , S. Fritzsche

We consider high energy electron scattering by hydrogen atoms in the presence of a laser field of moderate power and higher frequencies. If the field is a superposition of a linearly and a circularly polarized laser beam in a particular…

原子物理 · 物理学 2013-03-07 Aurelia Cionga , Fritz Ehlotzky , Gabriela Zloh

Photoionization of randomly oriented chiral molecules with circularly polarized light leads to a strong forward/backward asymmetry in the photoelectron angular distribution. This chiroptical effect, referred to as Photoelectron Circular…

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