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A multi-phase field model is employed to study the microstructural evolution of an alloy undergoing liquid dealloying. The model proposed extends upon the original approach of Geslin et al. to consider dealloying in the presence of grain…

材料科学 · 物理学 2023-08-07 Nathan Bieberdorf , Mark D. Asta , Laurent Capolungo

We present a novel phase-field approach for investigating solute segregation in a moving grain boundary. In our model, the correct choice of various parameters can control the solute-grain boundary interaction potential, resulting in…

材料科学 · 物理学 2023-08-17 Sandip Guin , Miral Verma , Soumya Bandyopadhyay , Yu-Chieh Lo , Rajdip Mukherjee

Phase transformations in metallic grain boundaries (GBs) present significant fundamental interest in the context of thermodynamics of low-dimensional physical systems. We report on atomistic computer simulations of the Cu-Ag system that…

材料科学 · 物理学 2015-07-01 Timofey Frolov , Mark Asta , Yuri Mishin

This paper studies how solute segregation and its relationship to grain boundary energy in binary alloys is captured in the phase field crystal (PFC) formalism, a continuum method that incorporates atomic scale elasto-plastic effects on…

材料科学 · 物理学 2013-04-10 Jonathan Stolle , Nikolas Provatas

Grain boundary (GB) segregation in magnesium (Mg) substantially influences its mechanical properties and performance. Atomic-scale modelling, typically using ab-initio or semi-empirical approaches, has mainly focused on GB segregation at…

Systematic microstructure design requires reliable thermodynamic descriptions of each and all microstructure elements. While such descriptions are well established for most bulk phases, thermodynamic assessment of crystal defects is…

材料科学 · 物理学 2021-07-02 Reza Darvishi Kamachali

Understanding the composition evolution of grain boundaries and grain boundary precipitation at near-atomic scale in aluminum alloys is crucial to tailor mechanical properties and to increase resistance to corrosion and stress corrosion…

Segregation-induced structural transitions in metallic grain boundaries are studied with hybrid atomistic Monte Carlo/molecular dynamics simulations using Cu-Zr as a model system, with a specific emphasis on understanding the effect of…

材料科学 · 物理学 2016-04-27 Zhiliang Pan , Timothy J. Rupert

Mg alloys are promising lightweight structural materials due to their low density and excellent mechanical properties. However, their limited formability and ductility necessitate improvements in these properties, specifically through…

While it is known that alloy components can segregate to grain boundaries (GBs), and that the atomic mobility in GBs greatly exceeds the atomic mobility in the lattice, little is known about the effect of GB segregation on GB diffusion.…

材料科学 · 物理学 2020-08-17 R. K. Koju , Y. Mishin

In magnesium alloys with multiple substitutional elements, solute segregation at grain boundaries (GBs) has a strong impact on many important material characteristics, such as GB energy and mobility, and therefore, texture. Although it is…

Segregation to defects, in particular to grain boundaries (GBs), is an unavoidable phenomenon leading to changed material behavior over time. With the increase of available computational power, unbiased quantum-mechanical predictions of…

材料科学 · 物理学 2025-05-22 Dominik Gehringer , Lorenz Romaner , David Holec

Grain boundary embrittlement occurs when a solute enriches at a grain boundary and lowers its cohesive energy. While grain boundary enrichment is often attributed to equilibrium segregation effects, most models of embrittlement consider…

材料科学 · 物理学 2015-08-18 Michael A. Gibson , Christopher A. Schuh

Structural transformations at interfaces are of profound fundamental interest as complex examples of phase transitions in low-dimensional systems. Despite decades of extensive research, no compelling evidence exists for structural…

材料科学 · 物理学 2013-05-28 Timofey Frolov , David L. Olmsted , Mark Asta , Yuri Mishin

Grain boundaries (GBs) can be treated as two-dimensional (2-D) interfacial phases (also called 'complexions') that can undergo interfacial phase-like transitions. As bulk phase diagrams and calculation of phase diagram (CALPHAD) methods are…

材料科学 · 物理学 2022-09-05 Jian Luo

Microalloying elements tend to segregate to the matrix-precipitate phase boundaries to reduce the interfacial energy. The segregation mechanism is emerging as a novel design strategy for developing precipitation-hardened alloys with…

材料科学 · 物理学 2022-01-11 Sourabh Bhagwan Kadambi , Srikanth Patala

We present a multiscale modelling framework that integrates density functional theory (DFT) with a phase-field model (PFM) to explore the intricate dynamics of grain growth in nanocrystalline {\alpha}-Fe single-phase alloy in the presence…

材料科学 · 物理学 2024-06-13 Sandip Guin , Albert Linda , Yu-Chieh Lo , Somanth Bhowmick , Rajdip Mukherjee

Segregation of impurities to grain boundaries plays an important role in both the stability and macroscopic behavior of polycrystalline materials. The research objective in this work is to better characterize the energetics and length…

材料科学 · 物理学 2013-09-02 N. R. Rhodes , M. A. Tschopp , K. N. Solanki

Interfacial segregation can stabilize grain structures and even lead to grain boundary complexion transitions. However, understanding of the complexity of such phenomena in polycrystalline materials is limited, as most studies focus on…

材料科学 · 物理学 2021-07-02 P Garg , Z Pan , V Turlo , TJ Rupert

Tailoring the nanoscale distribution of chemical species at grain boundaries is a powerful method to dramatically influence the properties of polycrystalline materials. However, classical approaches to the problem have tacitly assumed that…

材料科学 · 物理学 2024-11-11 Malik Wagih , Yannick Naunheim , Tianjiao Lei , Christopher A. Schuh
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