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We theoretically investigate light matter interactions for chiral molecules in the presence of non-chiral nanoantennas. Isotropic nanostructures supporting optical-frequency electric or magnetic dipoles are sufficient to locally enhance the…

介观与纳米尺度物理 · 物理学 2013-06-14 Aitzol Garcia-Etxarri , Jennifer A. Dionne

Molecular chirality plays a crucial role in innumerable biological processes. The chirality of a molecule can typically be identified by its characteristic optical response, the circular dichroism (CD). CD signals have thus long been used…

Dark-field illumination is shown to make planar chiral nanoparticle arrangements exhibit circular dichroism in extinction analogous to true chiral scatterers. Circular dichrosim is experimentally observed at the maximum scattering of single…

The circular dichroism (CD) spectra of single-wall carbon nanotubes are calculated using a dipole approximation. The calculated CD spectra show features that allow us to distinguish between nanotubes with different angles of chirality, and…

材料科学 · 物理学 2007-05-23 A. Sanchez-Castillo , C. E. Roman-Velazquez , C. Noguez

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

Strong enhancement of molecular circular dichroism has the potential to enable efficient asymmetric photolysis, a method of chiral separation that has conventionally been impeded by insufficient yield and low enantiomeric excess. Here, we…

We establish a general unified formulation which, using the optical theorem of electromagnetic helicity, shows that dichorism is a phenomenon arising in any scattering -or diffraction- process, elastic or not, of chiral electromagnetic…

光学 · 物理学 2017-04-12 Manuel Nieto-Vesperinas

Molecular Circular dichroism (CD) spectroscopy faces significant limitations due to the inherent weakness of chiroptical light-matter interactions. In this view, resonant optical antennas constitute a promising solution to this problem…

It is very interesting to bring plasmonic circular dichroism spectroscopy to the mid-infrared spectral interval, and there are two reasons for this. This spectral interval is very important for thermal bio-imaging and, simultaneously, this…

材料科学 · 物理学 2017-09-08 Xiang-Tian Kong , Runbo Zhao , Zhiming Wang , Alexander O. Govorov

We introduce a definition of the electromagnetic chirality of an object and show that it has an upper bound. Reciprocal objects attain the upper bound if and only if they are transparent for all the fields of one polarization handedness…

光学 · 物理学 2016-08-03 Ivan Fernandez-Corbaton , Martin Fruhnert , Carten Rockstuhl

Prospects of using metal hole arrays for the enhanced optical detection of molecular chirality in nanosize volumes are investigated. Light transmission through the holes filled with an optically active material is modeled and the activity…

光学 · 物理学 2017-01-17 Maxim V. Gorkunov , Alexander N. Darinskii , Alexey V. Kondratov

Achieving intrinsic optical chirality requires breaking all mirror symmetries of an object, and maximum chirality, which allows interaction with only one helicity of light, is particularly promising for applications such as chiral sensing,…

光学 · 物理学 2025-02-28 Jiaqi Niu , Jingquan Liu , Bin Yang

Polariton states with high levels of chiral dissymmetry offer exciting prospects for quantum information, sensing, and lasing applications. Such dissymmetry must emanate from either the involved optical resonators or the quantum emitters.…

化学物理 · 物理学 2022-09-28 Andrew H. Salij , Randall H. Goldsmith , Roel Tempelaar

The chiral state of a molecule plays a crucial role in molecular recognition and biochemical reactions. Because of this and owing to the fact that most modern drugs are chiral, the sensitive and reliable detection of the chirality of…

介观与纳米尺度物理 · 物理学 2019-04-30 Luisa M. Kneer , Eva-Maria Roller , Lucas V. Besteiro , Robert Schreiber , Alexander O. Govorov , Tim Liedl

Circular Dichroism (CD) can distinguish the handedness of chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest Thermal Circular Dichroism (TCD) for chiral…

光学 · 物理学 2024-07-19 Ershad Mohammadi , Giulia Tagliabue

The ability to differentiate chiral molecules of different handedness is of great importance for chemical and life sciences. Since most of the relevant chiral molecules have their chiral transitions in the UV region, detecting their…

The on-chip measurement of polarization states plays an increasingly crucial role in modern sensing and imaging applications. While high-performance monolithic linearly polarized photodetectors have been extensively studied, integrated…

High-harmonic generation (HHG) provides the only source of attosecond pulses -- currently the shortest accessible time intervals, and it is employed as the only table-top source of light in extreme UV and soft X-ray spectral regions. Chiral…

Chirality in inorganic nanoparticles and nanostructures has gained increasing scientific interest, because of the possibility to tune their ability to interact differently with left- and right-handed circularly polarized light. In some…

In many biological materials with a hierarchical structure there is an intriguing and unique mechanism responsible for the 'propagation' of order from the molecular to the nano- or micro-scale level. Here we present a much simpler molecular…