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A novel optical method for distinguishing chiral molecules is proposed and validated within a quantum simulator employing a trapped-ion qudit. This approach correlates the sign disparity of the dipole moment of chiral molecules with…

量子物理 · 物理学 2024-03-11 Teng Liu , Fa Zhao , Pengfei Lu , Qifeng Lao , Min Ding , Ji Bian , Feng Zhu , Le Luo

We propose to discriminate chiral molecules by combining one- and two-photon processes in a closed-loop configuration. The one-photon-coupling intrinsic {\pi}-phase difference between two enantiomers leads to their different superposition…

量子物理 · 物理学 2020-02-20 Jin-Lei Wu , Yan Wang , Jie Song , Yan Xia , Shi-Lei Su , Yong-Yuan Jiang

An interesting method of fast enantio-specific state transfer is proposed for cyclic three-level systems of chiral molecules. We show that the fast population transfer via shortcut to adiabaticity can be accomplished for the cyclic…

量子物理 · 物理学 2023-05-10 Jian-Jian Cheng , Chong Ye , Yong Li

We study quantum systems with broken symmetry that can be modelled as cyclic three-level atoms with coexisting one- and two-photon transitions. They can be selectively optically excited to any state. As an example, we show that left- and…

量子物理 · 物理学 2008-01-28 Yong Li , C. Bruder

Chiral molecules with broken parity symmetries can be modeled as quantum systems with cyclic-transition structures. By using these novel properties, we design two-step laser pulses to distinguish left- and right-handed molecules from the…

量子物理 · 物理学 2015-05-19 W. Z. Jia , L. F. Wei

We propose a method to realize enantiodiscrimination of chiral molecules based on quantum correlation function in a driven cavity-molecule system, where the chiral molecule is coupled with a quantized cavity field and two classical light…

量子物理 · 物理学 2022-08-12 Fen Zou , Yu-Yuan Chen , Bo Liu , Yong Li

Enantiodetection of chiral molecules is important to pharmaceutical drug production, chemical reaction control, and biological function designs. Traditional optical methods of enantiodetection rely on the weak magnetic-dipole or…

化学物理 · 物理学 2022-09-14 Mao-Rui Cai , Chong Ye , Hui Dong , Yong Li

We propose a method for enantio-detection of chiral molecules based on a cavity-molecule system, where the left- and right-handed molecules are coupled with a cavity and two classical light fields to form cyclic three-level models. Via the…

量子物理 · 物理学 2021-10-25 Yu-Yuan Chen , Chong Ye , Yong Li

We propose an accurate and convenient method to achieve 100\% discrimination of chiral molecules with Lewis-Riesenfeld invariant. By reversely designing the pulse scheme of handed resolution, we obtain the parameters of the three-level…

量子物理 · 物理学 2023-05-24 Hang Xu , Xue-Ke Song , Dong Wang , Liu Ye

We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately-designed…

量子物理 · 物理学 2015-05-28 W. Z. Jia , L. F. Wei

Enantio-conversion with the help of electromagnetic fields is an essential issue due to the chirality-dependence of many chemical, biological, and pharmaceutical processes. Here, we propose a method for this issue based on a five-level…

量子物理 · 物理学 2021-03-03 Chong Ye , Bo Liu , Yu-Yuan Chen , Yong Li

Dynamic encircling of exceptional points has attracted significant interest in recent years, as it can facilitate chiral transmission selectivity due to a nontrivial eigenstate evolution. Recently, multi-state systems have been explored,…

光学 · 物理学 2024-06-05 Aodong Li , Jian Wang , Andrea Alù , Lin Chen

We present an optical "enantio-selective switch", that, in two steps, turns a ("racemic") mixture of left-handed and right-handed chiral molecules into the enantiomerically pure state of interest. The optical switch is composed of an…

量子物理 · 物理学 2009-11-07 Petr Král , Ioannis Thanopulos , Moshe Shapiro , Doron Cohen

A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

化学物理 · 物理学 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

Distinguishing between enantiomers is crucial in the study of chiral molecules in chemistry and pharmacology. Many optical approaches rely on enantiospecific cyclic electric-dipole transitions induced by three microwave or laser beams.…

量子物理 · 物理学 2025-12-11 Fen Zou , Yong Li , Peng Zhang

Enantioselective photochemistry provides access to unique molecular structures and functions, with deep implications for fundamental science and industrial applications. Current methods for highly enantioselective photochemistry critically…

化学物理 · 物理学 2025-03-07 Andrés Ordóñez , Patricia Vindel-Zandbergen , David Ayuso

Enantiomers are chiral molecules that exist in right-handed and left-handed conformations. Optical techniques of enantiomers detection are widely employed to discriminate between left- and right-handed molecules. However, identical spectra…

量子物理 · 物理学 2023-05-10 Mohsen Izadyari , M. Tahir Naseem , Özgür E. Müstecaplıouglu

Today we are witnessing the electric-dipole revolution in chiral measurements. Here we reflect on its lessons and outcomes, such as the perspective on chiral measurements using the complementary principles of "chiral reagent" and "chiral…

光学 · 物理学 2022-11-30 David Ayuso , Andres F. Ordonez , Olga Smirnova

Enantiodetection is an important and challenging task across natural science. Nowadays, some chiroptical methods of enantiodetection based on decoherence-free cyclic three-level models of chiral molecules can reach the ultimate limit of the…

量子物理 · 物理学 2022-11-29 Chong Ye , Xiaowei Mu , Yifan Sun , Libin Fu , Xiangdong Zhang

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-handed conformations, allows for enantio-selective population transfer despite random orientation of the molecules. This is based on constructive…

量子物理 · 物理学 2019-07-09 Monika Leibscher , Thomas F. Giesen , Christiane P. Koch
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