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The use of tris(bidentate) Ir(III) complexes as light active components in phosphorescent organic light-emitting diodes (PhOLEDs) is currently the state-of-the-art technology to attain long-lasting and highly performing devices. Still,…

化学物理 · 物理学 2019-01-07 Sylvio Arroliga-Rocha , Daniel Escudero

Phosphorescent metal complexes have been under intense investigations as emissive dopants for energy efficient organic light emitting diodes (OLEDs). Among them, cyclometalated Pt(II) complexes are widespread triplet emitters with…

机器学习 · 计算机科学 2023-01-16 Shuai Wang , ChiYung Yam , Shuguang Chen , Lihong Hu , Liping Li , Faan-Fung Hung , Jiaqi Fan , Chi-Ming Che , GuanHua Chen

We present a comprehensive model to analyze, quantitatively, and predict the process of degradation of organic light-emitting diodes (OLEDs) considering all possible degradation mechanisms, i.e., polaron, exciton, exciton-polaron…

Devices based on deep-blue emitting iridium (III) complexes with N-heterocyclic carbene (NHC) ligands have recently been shown to give excellent performance as phosphorescent organic light-emitting diodes (PHOLEDs). To facilitate the design…

化学物理 · 物理学 2018-10-12 Xiuwen Zhou , Benjamin J. Powell

Cyclometalled Ir(III) compounds are the preferred choice as organic emitters in Organic Light Emitting Diodes. In practice, the presence of the transition metals surrounded by carefully designed ligands allows the fine tuning of the…

材料科学 · 物理学 2020-02-25 Marco Cazzaniga , Fausto Cargnoni , Marta Penconi , Alberto Bossi , Davide Ceresoli

The efficiency of an organic light-emitting diode (OLED) depends on the microscopic orientation of transition dipole moments of the molecular emitters. The most effective materials used for light generation have threefold symmetry, which…

化学物理 · 物理学 2015-02-26 Florian Steiner , Sebastian Bange , Jan Vogelsang , John M. Lupton

Lanthanide-based emitters are attracting increasing interest for their potential in high-performance OLEDs due to their narrow emission bands, high photostability, and functional versatility. However, their low radiative rates and poor…

Organic light-emitting diodes (OLEDs) are central to modern display technologies and are promising candidates for low-cost energy-efficient lighting. Their performance is determined by numerous, intricate fabrication parameters, but not…

Concentration quenching is a major impediment to efficient organic light-emitting devices. We herein report on Organic Light-Emitting Diodes (OLEDs) based on a fluorescent amorphous red-emitting starbust triarylamine molecule…

We review theories of phosphorescence in cyclometalated complexes. We focus primarily on pseudooctahedrally coordinated $t_{2g}^6$ metals (e.g., [Os(II)(bpy)$_3$]$^{2+}$, Ir(III)(ppy)$_3$ and Ir(III)(ptz)$_3$) as, for reasons that are…

化学物理 · 物理学 2015-04-02 B. J. Powell

In this work we present a systematic study of three representative iridium dyes, namely, Ir(ppy)3, FIrpic and PQIr, which are commonly used as sensitizers in organic optoelectronic devices. We show that electronic correlations play a…

材料科学 · 物理学 2015-06-11 Burak Himmetoglu , Alex Marchenko , Ismaila Dabo , Matteo Cococcioni

We report a detailed ab-initio study of the of the microscopic degradation mechanism of FIrpic, a popular blue emitter in OLED devices. We simulate the \emph{operando} conditions of FIrpic by adding an electron-hole pair (exciton) to the…

材料科学 · 物理学 2019-12-05 Marco Cazzaniga , Fausto Cargnoni , Marta Penconi , Alberto Bossi , Davide Ceresoli

This work reports our effort on understanding the efficiency roll-off in blue phosphorescent organic light-emitting diodes (OLEDs), based on a blue phosphorescence from bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl)- iridium…

材料科学 · 物理学 2014-10-27 Wenyu Ji , Furong Zhu

We report highly efficient, simultaneous fluorescence and phosphorescence (74% yield) at room temperature from a single molecule ensemble of (BzP)PB dispersed into a polymer host. The slow phosphorescence (208 ms lifetime) is very efficient…

Two chromophores derived from heptazine, HAP-3MF and HAP-3TPA, were synthesized and tested as emitters in light-emitting diodes (OLEDs) by Adachi and coworkers. Both emitters were shown to exhibit quantum efficiencies which exceed the…

化学物理 · 物理学 2021-11-18 Andrzej L. Sobolewski , Wolfgang Domcke

Biluminescent organic emitters show simultaneous fluorescence and phosphorescence at room temperature. So far, the optimization of the room temperature phosphorescence (RTP) in these materials has drawn the attention of research. However,…

We synthesize and study the properties of praseodymium doped fluoroindate glasses. Glass compositions with praseodymium molar concentrations up to 5% were obtained with good optical quality. Thermal, optical, and luminescence properties are…

Organic light-emitting diodes (OLEDs) have redefined lighting with their environment-friendliness and flexibility. However, only 25 % of the electronic states of organic molecules can emit light upon electrical excitation, limiting the…

材料科学 · 物理学 2025-02-17 Olli Siltanen , Kimmo Luoma , Andrew J. Musser , Konstantinos S. Daskalakis

Organic Light Emitting Diodes (OLED) have experienced vast attention in the scientific literature as the leading contender for the next generation of electronic lighting technology. However, while research continues to push the limit for…

应用物理 · 物理学 2019-08-02 Sahadev Somasundaram

Colloidal quantum dots are promising next-generation phosphors to enhance the color rendition of light-emitting devices (LEDs) while minimizing the brightness drop. In order to exploit the beneficial tunability of quantum dots for highly…

光学 · 物理学 2016-06-01 Jiun-Yi Lien , Chih-Jung Chen , Ray-Kuang Chiang , Sue-Lein Wang
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