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PbTe is a leading thermoelectric material at intermediate temperatures, largely thanks to its low lattice thermal conductivity. However, its efficiency is too low to compete with other forms of power generation. This efficiency can be…

介观与纳米尺度物理 · 物理学 2021-01-27 Javier F. Troncoso , Piotr Chudzinski , Tchavdar N. Todorov , Pablo Aguado-Puente , Myrta Grüning , Jorge J. Kohanoff

Understanding the impact of lattice imperfections on nanoscale thermal transport is crucial for diverse applications ranging from thermal management to energy conversion. Grain boundaries (GBs) are ubiquitous defects in polycrystalline…

While the effect of intrinsic defects on the electronic properties of half-Heusler compounds has been extensively discussed in literature, their effect on the lattice vibrations has received much less attention, due to the prohibitive…

材料科学 · 物理学 2024-12-17 M. Yazdani-Kachoei , B. Rabihavi , I. E. Brumboiu , S. Mehdi Vaez Allaei , I. Di Marco

Prior experimental studies showed that nanowires are promising structures for improving the thermoelectric performance of practical thermoelectric materials due to the strongly induced phonon-boundary scattering. However, few studies…

介观与纳米尺度物理 · 物理学 2017-09-13 Lei Ma , Riguo Mei , Mengmeng Liu , Xuxin Zhao , Qixing Wu , Hongyuan Sun

Lead chalcogenides such as PbS, PbSe, and PbTe are of interest for their exceptional thermoelectric properties and strongly anharmonic lattice dynamics. Although PbTe has received the most attention, PbSe has a lower thermal conductivity…

材料科学 · 物理学 2017-01-11 Nina Shulumba , Olle Hellman , Austin J. Minnich

As the energy problem becomes more prominent, researches on thermoelectric (TE) materials have deepened over the past few decades. Low thermal conductivity enables thermoelectric materials better thermal conversion performance. In this…

材料科学 · 物理学 2021-09-20 Yingtao Wang , Xian Zhang

Understanding the microscopic processes affecting the bulk thermal conductivity is crucial to develop more efficient thermoelectric materials. PbTe is currently one of the leading thermoelectric materials, largely thanks to its low thermal…

The microscopic physics behind low lattice thermal conductivity of single crystal rocksalt lead telluride (PbTe) is investigated. Mode-dependent phonon (normal and umklapp) scattering rates and their impact on thermal conductivity were…

The predictive modeling of lattice thermal conductivity is of fundamental importance for the understanding and design of materials for a wide range of applications. Two major approaches, namely molecular dynamics (MD) simulations and…

材料科学 · 物理学 2019-08-14 Marcello Puligheddu , Yi Xia , Maria K. Y. Chan , Giulia Galli

The lattice thermal conductivity of thermoelectric material CuInTe2 is predicted using classical molecular dynamics simulations, where a simple but effective Morse-type interatomic potential is constructed by fitting first-principles total…

材料科学 · 物理学 2017-04-26 J. Wei , H. J. Liu , L. Cheng , J. Zhang , P. H. Jiang , J. H. Liang , D. D. Fan , J. Shi

Transition metal dichalcogenides are investigated for various applications at the nanoscale thanks to their unique combination of properties and dimensionality. For many of the anticipated applications, heat conduction plays an important…

In silicon, lattice thermal conductivity plays an important role in a wide range of applications such as thermoelectric and microelectronic devices. Grain boundaries (GBs) in polycrystalline silicon can significantly reduce lattice thermal…

计算物理 · 物理学 2021-05-26 Susumu Fujii , Atsuto Seko

Achieving high valley degeneracy (i.e. "band convergence") in a material usually results in considerably enhanced thermoelectric properties. However, it is still unclear why this strategy of designing efficient thermoelectric materials is…

材料科学 · 物理学 2022-05-30 Ransell D'Souza , José D. Querales-Flores , Jiang Cao , Stephen Fahy , Ivana Savić

High entropy carbides ceramics with randomly-distributed multiple principal cations have shown high temperature stability, low thermal conductivity, and possible radiation tolerance. While chemical disorder has been shown to suppress…

材料科学 · 物理学 2022-05-23 Cody A. Dennett , Zilong Hua , Eric Lang , Fei Wang , Bai Cui

The lead chalcogenides represent an important family of functional materials, in particular due to the benchmark high-temperature thermoelectric performance of PbTe. A number of recent investigations, experimental and theoretical, have…

材料科学 · 物理学 2014-05-27 Jonathan Michael Skelton , Stephen C. Parker , Atsushi Togo , Isao Tanaka , Aron Walsh

The lattice thermal conductivity plays a key role in the performance of thermoelectric materials, where the lower values lead to a higher figure of merit values. Two-dimensional group III-VI monolayers such as InTe are promising materials…

计算物理 · 物理学 2022-02-24 Hind Alqurashi , Abhiyan Pandit , Bothina Hamad

We investigate the thermal conductivity of plumbene using molecular dynamics simulations, overcoming existing limitations by optimizing the parameters of Tersoff and Stillinger-Weber potentials via artificial neural networks. Our findings…

材料科学 · 物理学 2023-11-20 Rafat Mohammadi , Behrad Karimi , John Kieffer , Daniel Hashemi

The lattice thermal conductivity of the candidate thermoelectric material Mg$_3$Sb$_2$ is studied from first principles, with the inclusion of anharmonic, isotope, and boundary scattering processes, and via an accurate solution of the…

材料科学 · 物理学 2018-12-11 Maria Barbara Maccioni , Roberta Farris , Vincenzo Fiorentini

The major obstacle in the design of materials with low lattice thermal conductivity is the difficulty in efficiently scattering phonons across the entire frequency spectrum. Using first principles calculations, we show that driving PbTe…

材料科学 · 物理学 2019-03-26 Ronan M. Murphy , Éamonn D. Murray , Stephen Fahy , Ivana Savić

Nanostructured materials enable high thermal transport tunability, holding promises for thermal management and heat harvesting applications. Predicting the effect that nanostructuring has on thermal conductivity requires models, such as the…

材料科学 · 物理学 2021-10-19 S. Aria Hosseini , Sarah Khanniche , P. Alex Greaney , Giuseppe Romano
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