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Despite intense research, methods for controlling soft matter's spontaneous self-assembly in-to well-defined layers remain a significant challenge. We observed ion-induced structural disconti-nuities of phospholipid vesicles that can be…

软凝聚态物质 · 物理学 2024-04-01 Judith U. De Mel , Sudipta Gupta , Gerald J. Schneider

Polypeptide-based diblock copolymers forming either well-defined self-assembled micelles or vesicles after direct dissolution in water or in dichloromethane, have been studied combining light and neutron scattering with electron microscopy…

We investigate the influence of a non-ionic surfactant like polymer on phospholipid vesicles. Our results from cryogenic transmission electron microscopy (cryo-TEM), dynamic light scattering (DLS), small angle neutron and X-ray scattering…

We present a coarse-grained model for ionic surfactants in explicit aqueous solutions, and study by computer simulation both the impact of water content on the morphology of the system, and the consequent effect of the formed interfaces on…

软凝聚态物质 · 物理学 2015-03-16 Samuel Hanot , Sandrine Lyonnard , Stefano Mossa

Nanoparticles with hydrophobic capping ligands and amphiphilic phospholipids are both found to self-assemble into monolayer films when deposited on the air water interface. By separately measuring the anisotropic stress response of these…

We have established the detailed phase diagram of the prototypical deep eutectic solvent ethaline (ethylene glycol / choline chloride 2:1) as a function of the hydration level, in the bulk state and confined in the nanochannels of…

软凝聚态物质 · 物理学 2022-01-05 Benjamin Malfait , Aicha Jani , Denis Morineau

The self-assembly of photonic nanostructures in insects involves chitin, proteins, and lipids. While synthetic photonic systems have been extensively studied, current lipid-based self-assembly systems are limited in periodicity to…

软凝聚态物质 · 物理学 2026-05-29 Rushna Quddus , Meron Debas , Stefan Salentinig , Ullrich Steiner , Viola Vogler-Neuling

We consider a lattice model for amphiphiles in a solvent with molecules chemically similar to one part of the amphiphilic molecule. The dependence of the interaction potential on orientation of the amphiphilic molecules is taken into…

软凝聚态物质 · 物理学 2014-11-14 Jakub Pękalski , Paweł Rogowski , Alina Ciach

A mesoscale model with molecular resolutions is presented for the dipalmitoyl-phosphatidylcholine (DPPC) and 1-palmitoyl-2-oleyl-sn-glycero-3-phosphocholine (POPC) monolayer simulations at the air-water interface using many-body dissipative…

生物物理 · 物理学 2025-08-06 Yongzheng Zhu , Xuan Bai , Guoqing Hu

We present a model for the joint self-assembly of amphiphilic polymers and small amphiphilic molecules (surfactants) in a dilute aqueous solution. The polymer is assumed to consist of a hydrophilic backbone and a large number of hydrophobic…

软凝聚态物质 · 物理学 2007-05-23 H. Diamant , D. Andelman

Phospholipid monolayers at the air-water interface serve as model systems for various biological interfaces, e.g. lung surfactant layers and outer leaflets of cell membranes. Although the dynamical (viscoelastic) properties of these…

流体动力学 · 物理学 2009-11-19 Siyoung Q. Choi , Todd M. Squires

A new class of deep eutectic solvents are presented where one component of the system is inherently volatile, enabling a premeditated, auto-destructive capability which leads inexorably to a series of novel crystal structures. These…

化学物理 · 物理学 2020-03-17 Jason Potticary , Charlie Hall , Victoria Hamilton , James F. McCabe , Simon R. Hall

Self-assembled topological structures of post-processed two-dimensional materials exhibit novel physical properties distinct from those of their parent materials. Herein, the critical role of desulphurization on self-assembled topological…

材料科学 · 物理学 2021-01-08 Pinqiang Cao , Jianyang Wu

The possibility of laboratory X-ray reflectometry study of the structure of dimyristoyl phosphatidylserine (DMPS) phospholipid monolayers on the water surface in various phase states has been demonstrated.

Self-assembled monolayers of microparticles encoding Archimedean and non-regular tessellations promise unprecedented structure-property relationships for a wide spectrum of applications in fields ranging from optoelectronics to surface…

Monolayers of soft colloidal particles confined at fluid interfaces have been attracting increasing interest for fundamental studies and applications alike. However, establishing the relation between their internal architecture, which is…

软凝聚态物质 · 物理学 2021-03-30 Jacopo Vialetto , Fabrizio Camerin , Fabio Grillo , Lorenzo Rovigatti , Emanuela Zaccarelli , Lucio Isa

Interfaces are a most common motif in complex systems. To understand how the presence of interfaces affect hydrophobic phenomena, we use molecular simulations and theory to study hydration of solutes at interfaces. The solutes range in size…

软凝聚态物质 · 物理学 2014-09-05 Amish J. Patel , Patrick Varilly , Sumanth N. Jamadagni , Hari Acharya , Shekhar Garde , David Chandler

We investigated the molecular dynamics of the prototypical deep eutectic solvent (DES) ethaline. We disentangled the different motions of its two constituents, namely choline chloride and ethylene glycol on a spatio-temporal range that…

The adsorption of polymer and surfactant molecules onto colloidal particles or droplets in solution can be characterized non-destructively by scattering techniques. In a first part, the general framework of Dynamic Light Scattering, Small…

软凝聚态物质 · 物理学 2007-05-24 Julian Oberdisse

When polyelectrolyte-neutral block copolymers are mixed in solutions to oppositely charged species (e.g. surfactant micelles, macromolecules, proteins etc), there is the formation of stable supermicellar aggregates combining both…

软凝聚态物质 · 物理学 2007-05-23 J. -F. Berret , K. Yokota , M. Morvan
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