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Hybrid halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them, MAPbI$_3$ where MA stands for the methylammonium cation, exhibits ideal properties for…

材料科学 · 物理学 2017-07-10 A. Koliogiorgos , S. Baskoutas , I. Galanakis

Hybrid organic-inorganic perovskites, MAPbX3 (X= halogen), containing methylammonium (MA: CH3-NH3+) in the large voids conformed by the PbX6 octahedral network, are the active absorption materials in the new generation of solar cells.…

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

材料科学 · 物理学 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

Organic-inorganic coupling in the hybrid lead-halide perovskite is a central issue in rationalizing the outstanding photovoltaic performance of these emerging materials. Here we compare and contrast the evolution of structure and dynamics…

Organic-inorganic hybrid halide perovskites, in which the A cations of an ABX$_3$ perovskite are replaced by organic cations, may be used for photovoltaic and solar thermoelectric applications. In this contribution, we systematically study…

材料科学 · 物理学 2016-03-15 Tran Doan Huan , Vu Ngoc Tuoc , Nguyen Viet Minh

The performance of perovskite solar cells recently exceeded 15% solar-to-electricity conversion efficiency for small-area devices. The fundamental properties of the active absorber layers, hybrid organic-inorganic perovskites formed from…

材料科学 · 物理学 2013-10-11 Federico Brivio , Alison B. Walker , Aron Walsh

Third-generation photovoltaic (PV) materials combine many advantageous properties, including a high optical absorption together with a large charge carrier mobility, facilitated by small effective masses. Halide perovskites (ABX3, where X…

The alkali-trihalogeno-germanates AGeX$_3$ with A a large single positive ion such as Rb, Cs, or organic radicals such as methyl ammonium (MA), and X a halogen (I, Br, Cl, F) along with the corresponding stannates (ASnX$_3$) and plumbates…

材料科学 · 物理学 2020-06-05 Santosh Kumar Radha , Walter R. L. Lambrecht

The toxicity and stability issues of lead-based perovskites motivate the search for non-toxic, durable alternatives. This work examines lead-free $\mathrm{Mg_3ZBr_3}$ ($Z=\mathrm{As,Sb,Bi}$) halide perovskites as optoelectronic materials,…

材料科学 · 物理学 2026-02-03 Md Mohiuddin , Mohammed Mehedi Hasan , Alamgir Kabir

Inorganic-organic perovskites semiconductors are becoming increasingly interesting due to their remarkable optical properties, such as a high photoluminescence quantum yield and the possibility to show optical gain in a broad range of…

光学 · 物理学 2021-03-30 Michele Bellingeri , Francesco Scotognella

Organic-inorganic hybrid halide perovskites have ignited tremendous interests for photovoltaic applications. However, their nonlinear optical response has not been studied although many of these structures lack the centrosymmetry and…

材料科学 · 物理学 2020-02-14 Wenshen Song , Guang-Yu Guo , Su Huang , Lan Yang , Li Yang

The low ionization energy of an $A$ site molecule is a very important factor, which determines the thermodynamical stability of $A$PbI$_3$ hybrid halide perovskites, while the size of the molecule governs the stable phase at room…

材料科学 · 物理学 2018-02-13 Chao Zheng , Oleg Rubel

Organic-inorganic hybrid perovskites are considered to be most promising photovoltaic materials. Highest efficiencies of perovskite solar cells have been achieved by using appropriate cation and anion mixtures. Mixed perovskite solar cells…

化学物理 · 物理学 2019-12-23 Gee Yeong Kim , Alessandro Senocrate , Yaru Wang , Davide Moia , Joachim Maier

Hybrid AMX3 perovskites (A=Cs, CH3NH3; M=Sn, Pb; X=halide) have revolutionized the scenario of emerging photovoltaic technologies. Introduced in 2009 by Kojima et al., a rapid evolution very recently led to 15% efficient solar cells.…

材料科学 · 物理学 2014-10-08 Paolo Umari , Edoardo Mosconi , Filippo De Angelis

Halide perovskites consist a class of materials under intense investigation due to their potential technological applications like solar cells, optoelectronic devices and catalysis. Recently we have studied using electronic band structure…

材料科学 · 物理学 2018-10-17 G. Moschou , A. Koliogiorgos , I. Galanakis

Organometallic lead halide perovskites are highly efficient materials for solar cells and other optoelectronic applications due to their high quantum efficiency and exceptional semiconducting properties. A peculiarity of these perovskites…

Organic-inorganic hybrid double perovskites have attracted increasing interest in the commercialization of lead-free and nontoxic perovskites due to their unique optoelectronic properties compared with inorganic perovskites. In this study,…

应用物理 · 物理学 2023-06-14 A. Johnson , B. A. Ikyo , T. J. Ikyumbur , F. Gbaorun , A. A. Nathan

Halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them several crystallize in low symmetry lattice structures like trigonal, hexagonal, orthorhombic…

材料科学 · 物理学 2017-11-15 A. Koliogiorgos , S. Baskoutas , I. Galanakis

Hybrid organic-inorganic halide perovskites with the prototype material of CH$_{3}$NH$_{3}$PbI$_{3}$ have recently attracted intense interest as low-cost and high-performance photovoltaic absorbers. Despite the high power conversion…

材料科学 · 物理学 2017-05-30 Xin-Gang Zhao , Ji-Hui Yang , Yuhao Fu , Dongwen Yang , Qiaoling Xu , Liping Yu , Su-Huai Wei , Lijun Zhang

Previous theoretical calculations show azetidinium has the right radial size to form a 3D perovskite with lead halides [1], and has been shown to impart, as the A-site cation of ABX3 unit, beneficial properties to ferroelectric perovskites…

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