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We present results of $^{23}$Na and $^{19}$F nuclear magnetic resonance (NMR) measurements on NaCaCo$_2$F$_7$, a frustrated pyrochlore magnet with a Curie-Weiss temperature, $T_{cw}$ ~-140 K, and intrinsic bond disorder. Below 3.6 K both…

强关联电子 · 物理学 2017-12-20 R. Sarkar , J. W. Krizan , F. Brückner , E. C. Andrade , S. Rachel , M. Vojta , R. J. Cava , H. -H. Klauss

We report the crystal growth, crystal structure and basic magnetic properties of a new cobalt-based pyrochlore, NaSrCo$_2$F$_7$. Na and Sr are completely disordered on the non-magnetic large atom A sites, while magnetic S=3/2 Co$^{2+}$…

材料科学 · 物理学 2015-03-13 J. W. Krizan , R. J. Cava

In this study, I have investigated the magnetic and critical properties of manganese pyrochlore fluoride NaSrMn$_{2}$F$_{7}$, which exhibits a glass transition at T$_\text{f}$$=$2.5 (K) due to charge disorder. A DFT+$U$+SOC framework is…

强关联电子 · 物理学 2023-05-09 Mohammad Amirabbasi

Cobalt pyrochlore fluoride NaCaCo$_2$F$_7$ is a disordered frustrated magnet composed of Co$^{2+}$ ions with an effective spin-$\frac{1}{2}$ magnetic moment and exhibits spin freezing below $T_f \sim$2.4 K. We perform ultrasound velocity…

强关联电子 · 物理学 2020-06-17 T. Watanabe , H. Kato , Y. Hara , J. W. Krizan , R. J. Cava

Weak bond disorder disrupts the expected spin-liquid ground-state of the ideal $S$ = 1/2 Heisenberg pyrochlore antiferromagnet. Here we introduce a single crystal study of the structural and magnetic properties of the bond-disordered…

强关联电子 · 物理学 2023-07-12 Andrej Kancko , Gerald Giester , Ross H. Colman

Electron spin resonance study of frustrated pyrochlore Gd2Ti2O7 is performed in a wide frequency band for a temperature range 0.4-30 K, which covers paramagnetic and magnetically ordered phases. The paramagnetic resonance reveals the…

强关联电子 · 物理学 2012-02-02 S. S. Sosin , A. I. Smirnov , L. A. Prozorova , G. Balakrishnan , M. E. Zhitomirsky

We report the magnetic characterization of the frustrated transition metal pyrochlore NaCaCo$_2$F$_7$. This material has high spin Co$^{2+}$ in CoF$_6$ octahedra in a pyrochlore lattice, and disordered non-magnetic Na and Ca on the…

材料科学 · 物理学 2015-06-19 J. W. Krizan , R. J. Cava

The antiferromagnetic pyrochlore material NaCaCo$_2$F$_7$ is a thermal spin liquid over a broad temperature range (~ 140 K down to $T_F = 2.4 $K), in which magnetic correlations between Co$^{2+}$ dipole moments explore a continuous manifold…

强关联电子 · 物理学 2017-04-26 K. A. Ross , J. M. Brown , R. J. Cava , J. W. Krizan , S. E. Nagler , J. A. Rodriguez-Rivera , M. B. Stone

The spin dynamics in the geometrically frustrated pyrochlore antiferromagnet $\rm Gd_2Sn_2O_7$ is studied by means of the electron spin resonance. In the ordered phase ($T_N = 1$ K), we have detected three gapped resonance modes. Their…

强关联电子 · 物理学 2013-05-29 S. S. Sosin , L. A. Prozorova , P. Bonville , M. E. Zhitomirsky

We report detailed measurements of the low temperature magnetic phase diagram of Er$_2$Ti$_2$O$_7$. Heat capacity and time-of-flight neutron scattering studies of single crystals, subject to magnetic fields applied along the…

The spin-1 anisotropic antiferromagnet NiCl_2-4SC(NH2)_2 exhibits a field-induced quantum phase transition that is formally analogous to Bose-Einstein condensation. Here we present results of systematic high-field electron spin resonance…

强关联电子 · 物理学 2012-02-27 C. Psaroudaki , S. A. Zvyagin , J. Krzystek , A. Paduan-Filho , X. Zotos , N. Papanicolaou

The crystal structures and magnetic properties of three previously unreported A2B2F7 pyrochlore materials, NaSrMn2F7, NaCaFe2F7, and NaSrFe2F7 are presented. In these compounds, either S=2 Fe2+ or S=5/2 Mn2+ is on the B site, while…

强关联电子 · 物理学 2016-12-21 M. B. Sanders , J. W. Krizan , K. W. Plumb , T. M. McQueen , R. J. Cava

NaCaNi$_2$F$_7$ is an insulating, frustrated A$_2$B$_2$F$_7$ pyrochlore with magnetic S = 1 Ni$^{2+}$ on the pyrochlore B site. Non-magnetic Na and Ca are disordered on the A-site. Magnetic susceptibility measurements made on an oriented…

材料科学 · 物理学 2015-04-30 J. W. Krizan , R. J. Cava

We report the observation of spin glass state in the double perovskite oxide Sr$_{2}$FeCoO$_{6}$ prepared through sol-gel technique. Initial structural studies using x rays reveal that the compound crystallizes in tetragonal $I 4/m$…

We present a parametric study of the diffuse magnetic scattering at (1/2,1/2,1/2) positions in reciprocal space, ascribed to a frozen antiferromagnetic spin ice state in single crystalline Tb2Ti2O7. Our high-resolution neutron scattering…

A single crystal of the Co2+ based pyrochlore NaCaCo2F7 was studied by inelastic neutron scattering. This frustrated magnet with quenched exchange disorder remains in a strongly correlated paramagnetic state down to one 60th of the…

We report a random singlet ground state in the $S=\frac{1}{2}$ Heisenberg pyrochlore antiferromagnet NaCdCu$_2$F$_7$. Cationic Na$^+$/Cd$^{2+}$ disorder on the pyrochlore $A$ site generates a broad distribution of…

We report an experimental study of the static magnetization $M(H,T)$ and high-field electron spin resonance (ESR) of polycrystalline \MgGd, a representative member of the newly discovered class of the so-called tripod-kagome…

The $T$-dependence (2- 400 K) of the electron paramagnetic resonance (EPR), magnetic susceptibility, $\chi (T)$, and specific heat, $C_{v}(T)$, of the $normal$ antiferromagnetic (AFM) spinel ZnCr$_{2}$O$_{4}$ and the spin-glass (SG)…

We report the experimental and the analytical results of electron spin resonance (ESR) and magnetization in high magnetic fields up to about 68 T of the quasi two-dimensional triangular lattice antiferromagnet NiGa$_2$S$_4$. From the…

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