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Polar distortions in solids give rise to the well-known functionality of switchable macroscopic polarisation in ferroelectrics and, when combined with strong spin-orbit coupling, can mediate giant spin splittings of electronic states. While…

By means of first-principles simulations, we unambiguously show that improper ferroelectricity in magnetite in the low-temperature insulating phase is driven by charge-ordering. An accurate comparison between monoclinic ferroelectric Cc and…

材料科学 · 物理学 2015-05-13 Kunihiko Yamauchi , Tetsuya Fukushima , Silvia Picozzi

The structural phase transition in hexagonal BaMnO$_3$ occurring at $T_c$=130 K was studied in ceramic samples using electron and X-ray diffraction, second harmonic generation as well as by dielectric and lattice dynamic spectroscopies. The…

Realization of ferromagnetic ferroelectricity, combining two ferroic orders in a single phase, is the longstanding problem of great practical importance. One of the difficulties is that ferromagnetism alone cannot break inversion symmetry…

材料科学 · 物理学 2026-04-22 I. V. Solovyev

We report ferroelectric ordering in Ni substituted CaBaCo4O7. Magnetization showed ferrimagnetic transition at 60 K and an additional transition is found ~ 82 K, further, enhanced antiferromagnetic interactions and decrease in saturation…

材料科学 · 物理学 2017-10-18 C. Dhanasekhar , A. K Das , Ripandeep Singh , A. Das , G. Giovannetti , D. Khomskii , A. Venimadhav

URu$_2$Si$_2$ is surely one of the most mysterious of the heavy-fermion compounds. Despite more than twenty years of experimental and theoretical works, the order parameter of the transition at $T_0 = 17.5$ K is still unknown. The state…

强关联电子 · 物理学 2012-03-06 G. W. Scheerer , W. Knafo , D. Aoki , G. Ballon , A. Mari , D. Vignolles , J. Flouquet

Magnetoelectric multiferroics are highly sought after for applications in low-power electronics and for advancing fundamental research, including axion insulators and dark matter detection. However, achieving a combination of ferroic spin…

材料科学 · 物理学 2024-12-02 Libor Šmejkal

The layered compound KCu$_3$As$_2$O$_7$(OD)$_3$, comprising distorted kagome planes of $S=1/2$ Cu$^{2+}$ ions, is a recent addition to the family of type-II multiferroics. Previous zero field neutron diffraction work has found two helically…

Investigation of the magnetism of Cu$_3$Mo$_2$O$_9$ single crystal, which has antiferromagnetic (AF) linear chains interacting with AF dimers, reveals an AF second-order phase transition at $T_{\rm N} = 7.9$ K. Although weak…

Cu3Nb2O8 is an unusual multiferroic compound that undergoes a series of magnetic ordering at low temperatures. Concurrent development of electric polarization has been reported at TN1 ~25 K corresponding to a non-collinear helicoidal…

强关联电子 · 物理学 2015-06-22 G. Sharma , J. Saha , S. D. Kaushik , V. Siruguri , S. Patnaik

Type-II multiferroics, where spin interactions induce a ferroelectric polarization, are interesting for new device functionalities due to large magnetoelectric coupling. We report on a new type of multiferroicity in the quadruple-perovskite…

In this paper we examine the role of crystal chemistry factors in creating conditions for formation of magnetoelectric ordering in BiFeO3. It is generally accepted that the main reason of the ferroelectric distortion in BiFeO3 is concerned…

材料科学 · 物理学 2011-06-03 L. M. Volkova , D. V. Marinin

We investigated the series of temperature and field-driven transitions in LuFe$_2$O$_4$ by optical and M\"{o}ssbauer spectroscopies, magnetization, and x-ray scattering in order to understand the interplay between charge, structure, and…

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

材料科学 · 物理学 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

In this letter, we report the structural, electronic and ferroelectric properties of the layered mixed-valent transition-metal compound, Sr$_{4}$Fe$_{6}$O$_{12}$ (SFO). We demonstrate how SFO undergoes a phase transition from a…

强关联电子 · 物理学 2025-02-05 Arindam Sarkar , Hena Das , Prashant Singh , Aftab Alam

We investigate the frustrated magnetic interactions in cubic transition metal oxides with orbital degeneracy. The $e_g$ orbitals order easier and their ordering explains the $A$-type antiferromagnetic phase in KCuF$_3$ and LaMnO$_3$. In…

强关联电子 · 物理学 2016-08-31 Andrzej M. Oles

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…

Ferroelectric control of altermagnetism in momentum space has been studied widely, while the control of magnetism in real space of altermagnets are still rare. We present a design rule to identify multiferroicity in n=2 Ruddlesden-Popper…

There has been tremendous research activity in the field of magneto-electric (ME) multiferroics after Kimura et al. [1] showed that antiferromagnetic and ferroelectric order coexist in orthorhom- bically distorted perovskite TbMnO3 and are…

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