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A Copper-Zinc-Tin-Sulphide (CZTS)based solar cell with a modified ce3ll configuration of Mo/SnS/CZTS/SnS2/ZnO is simulated using SCAPS. An SnS2 buffer layer is used in simulation instead of the standard CdS layer. An additional back surface…

材料科学 · 物理学 2015-10-20 Atul Kumar , Ajay D. Thakur

We simulated photovoltaic characteristics of single heterojunction solar cell with Cu2ZnSnS4 and Cu2ZnSnSe4 absorber layer numerically using one dimensional solar cell capacitance simulator (SCAPS-1D). n-CdS/ZnO double buffer layer is used…

应用物理 · 物理学 2018-01-26 Goutam K Gupta , Ambesh Dixit

Cu2ZnSnS(e)4 (CZTS(e)) solar cells have attracted much attention due to the elemental abundance and the non-toxicity. However, the record efficiency of 12.6% for Cu2ZnSn(S,Se)4 (CZTSSe) solar cells is much lower than that of Cu(In,Ga)Se2…

应用物理 · 物理学 2018-03-14 Shoushuai Gao , Zhenwu Jiang , Li Wu , Jianping Ao , Yu Zeng , Yun Sun , Yi Zhang

In this work, first principle calculations of Cu$_2$ZnSnS$_4$ (CZTS), Cu$_2$ZnGeS$_4$ (CZGS) and Cu$_2$ZnSiS$_4$ (CZSS) are performed to highlight the impact of the cationic substitution on the structural, electronic and optical properties…

应用物理 · 物理学 2022-02-22 Thomas Ratz , Jean-Yves Raty , Guy Brammertz , Bart Vermang , Ngoc Duy Nguyen

The efficiencies of solar cells based on kesterite Cu$_2$ZnSnS$_4$ (CZTS) and Cu$_2$ZnSnSe$_4$ (CZTSe) are limited by a low open-circuit voltage due to high rates of non-radiative electron-hole recombination. To probe the origin of this…

材料科学 · 物理学 2018-05-11 Bartomeu Monserrat , Ji-Sang Park , Sunghyun Kim , Aron Walsh

Flexible Cu2ZnSn(S, Se)4 (CZTSSe) solar cells take the advantages of environmental friendliness, low cost, and multi-scenario applications, and have drawn extensive attention in recent years. Compared with rigid devices, the lack of alkali…

Kesterite is a leading candidate among inorganic thin-film photovoltaic technologies, offering sustainable and environmentally friendly solutions without reliance on critical raw materials. This study investigates the performance of…

A coupled optoelectronic model was implemented along with the differential evolution algorithm to assess the efficacy of grading the bandgap of the CZTSSe layer for enhancing the power conversion efficiency of thin-film CZTSSe solar cells.…

应用物理 · 物理学 2020-04-07 Faiz Ahmad , Akhlesh Lakhtakia , Tom H. Anderson , Peter B. Monk

Dual-absorber solar cells represent a promising approach to surpass the efficiency limit of single-junction devices by extending spectral absorption and minimizing thermalization losses. Among earth-abundant thin-film materials, kesterites…

材料科学 · 物理学 2025-11-14 Hasib Md Abid Bin Farid , Md Tashfiq Bin Kashem

CdTe-based thin film solar cell has been modeled and enumerated with a thin CuInTe2 (CIT) current booster layer. CdTe-based n-CdS/p-CdTe/p+-CIT/p++-WSe2 heterojunction device has been evaluated for the highest performance. It is revealed…

Traditional CdS buffer layer in selenium-free Cu(In,Ga)S2 solar cells leads to reduced open-circuit voltage because of a negative conduction band offset at the Cu(In,Ga)S2/CdS interface. Reducing this loss necessitates the substitution of…

We present evidence that band gap narrowing at the heterointerface may be a major cause of the large open circuit voltage deficit of Cu$_2$ZnSnS$_4$/CdS solar cells. Band gap narrowing is caused by surface states that extend the…

介观与纳米尺度物理 · 物理学 2017-04-05 Andrea Crovetto , Mattias Palsgaard , Tue Gunst , Troels Markussen , Kurt Stokbro , Mads Brandbyge , Ole Hansen

A systematic survey and subsequent research have been made on MoTe2-based n-CdS/p-MoTe2/p+-CGS device in solar cell and photodetector field. The optimization has been established by altering the various properties of each constituent layer…

This study investigates the critical role of buffer layers in enhancing the efficiency of thin-film CdTe solar cells. We explore non-toxic buffer materials, specifically ZnSe, ZnMgO, 3C-SiC, and WS2, as potential replacements for the…

Cu2ZnSnS4 (CZTS) is a promising photovoltaic absorber material with earth abundant and nontoxic elements. However, the detrimental native defects and secondary phases of CSTS will largely reduce the energy conversion efficiencies. To…

材料科学 · 物理学 2017-11-15 Yiou Zhang , Kinfai Tse , Xudong Xiao , Junyi Zhu

Sulfide Kesterite Cu2ZnSnS4 (CZTS), a nontoxic and low-cost photovoltaic material, has always being facing severe charge recombination and poor carrier transport, resulting in the cell efficiency record stagnating around 11% for years.…

P-type doped CdTe free surfaces Schottky contacts, and even interfaces with isostructural p-ZnTe frequently exhibit downward band bending and moderate to high recombination velocities. Fermi level pinning by donor-like states can explain…

Sulfide chalcopyrite, Cu(In,Ga)S2, having wide bandgap (larger than 1.5 eV), favorable optoelectronic properties, and high stability, is a promising top-cell absorber for tandem applications. Adapting device structures optimized for 1.0 -…

The influences of work function of transparent conducting oxides (TCO) on the per-formance of organic solar cells, including open circuit voltage, conversion efficiency and fill factor, has been simulated. It is obtained that for non-Ohmic…

仪器与探测器 · 物理学 2016-05-31 Aqing Chen , Kaigui Zhu , Qingyi Shao , Zhenguo Ji

We carried out simulative investigations on a non-toxic, lead-free perovskite solar cell (PSC), where Cs2AgBiBr6, P3HT, ZnO nanorod, and C were utilized as the absorber layer, hole transport layer, electron transport layer, and back…

材料科学 · 物理学 2021-06-25 Intekhab Alam , Rahat Mollick , Md Ali Ashraf
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