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We present a pedagogical review of the swelling thermodynamics and phase transitions of polymer gels. In particular, we discuss how features of the volume phase transition of the gel's osmotic equilibrium is analogous to other transitions…

软凝聚态物质 · 物理学 2019-06-13 Michael S. Dimitriyev , Ya-Wen Chang , Paul M. Goldbart , Alberto Fernández-Nieves

We present a study on swelling-induced circumferential buckling of tubular shaped gels. Inhomogeneous stress develops as gel swells under mechanical constraints, which gives rise to spontaneous buckling instability without external force.…

软凝聚态物质 · 物理学 2015-06-04 Howon Lee , Jiaping Zhang , Hanqing Jiang , Nicholas X. Fang

Polymer gels are comprised of a three-dimensional, cross-linked network that can typically withstand the mechanical deformation associated with both swelling and de-swelling. Thus, gels can be designed with smart behaviors that require both…

软凝聚态物质 · 物理学 2024-06-24 Alyssa VanZanten , Shih-Yuan Chen , Michelle M. Driscoll , Caroline R. Szczepanski

We investigate the collective behavior of suspended thermoresponsive microgels, that expel solvent and subsequently decrease in size upon heating. Using a binary mixture of differently thermoresponsive microgels, we demonstrate how…

When a hydrophilic and deformable porous material is immersed in a bath, it may absorb the solvent and expand by several times its volume, thus forming a highly soft and porous hydrogel. A stress applied on the soft hydrogel surface deforms…

软凝聚态物质 · 物理学 2026-04-30 Caroline Kopecz-Muller , Joshua D Mcgraw , Thomas Salez

A roughly constant temperature over a wide range of densities is maintained in molecular clouds through radiative heating and cooling. An isothermal equation of state is therefore frequently employed in molecular cloud simulations. However,…

天体物理学 · 物理学 2009-11-11 G. Pavlovski , M. D. Smith , M. -M. Mac Low

Thermo-responsive hydrogels are a promising material for creating controllable actuators for use in micro-scale devices, since they expand and contract significantly (absorbing or expelling fluid) in response to relatively small temperature…

软凝聚态物质 · 物理学 2022-08-18 Matthew D. Butler , Thomas D. Montenegro-Johnson

Soft membranes are commonly employed in shape-morphing applications, where the material is programmed to achieve a target shape upon activation by an external trigger, and as coating layers that alter the surface characteristics of bulk…

软凝聚态物质 · 物理学 2016-02-05 Alessandro Lucantonio , Luciano Teresi , Antonio DeSimone

In this study we use non-equilibrium thermodynamics to systematically derive a phase-field model of a polyelectrolyte gel coupled to a hydrodynamic model for a salt solution surrounding the gel. The governing equations for the gel account…

软凝聚态物质 · 物理学 2022-03-02 Giulia L. Celora , Matthew G. Hennessy , Andreas Münch , Barbara Wagner , Sarah L. Waters

When a gel absorbs solvent from surrounding, stress field is created in the gel, and this causes complex dynamics of the swelling behavior. Here we study this effect for disk-shaped gel by rigorously solving the diffusio-mechanical coupling…

软凝聚态物质 · 物理学 2021-05-17 Xingkun Man , Masao Doi

A cylindrical hydrogel tube, completely submerged in water, hydrates by swelling and filling its internal cavity. When it comes back into contact with air, it dehydrates: the tube thus expels the solvent through the walls, shrinking. This…

软凝聚态物质 · 物理学 2022-12-05 Michele Curatolo , Federico Lisi , Gaetano Napoli , Paola Nardinocchi

Attractive colloidal particles can form a disordered elastic solid or gel when quenched into a two-phase region, if the volume fraction is sufficiently large. When the interactions are comparable to thermal energies the stress-bearing…

软凝聚态物质 · 物理学 2014-03-13 Lisa J. Teece , James M. Hart , Kerry Yen Ni Hsu , Stephen Gilligan , Malcolm A. Faers , Paul Bartlett

The Euler buckling of rods is a long-studied mechanical instability, and it remains relevant to this day, as the constituent components in many biological and physical systems are linear polymers, such as microtubules or carbon nanotubes.…

统计力学 · 物理学 2026-05-22 Richard Huang , David R. Nelson , Suraj Shankar

We report experimental observations of an undulational instability of myelin figures. Motivated by this, we examine theoretically the deformation and possible instability of concentric, cylindrical, multi-lamellar membrane structures. Under…

软凝聚态物质 · 物理学 2009-11-07 C. -M. Chen , C. F. Schmidt , P. D. Olmsted , F. C. MacKintosh

Thermo-responsive hydrogels are smart materials that rapidly switch between hydrophilic (swollen) and hydrophobic (shrunken) states when heated past a threshold temperature, resulting in order-of-magnitude changes in gel volume. Modelling…

流体动力学 · 物理学 2025-05-14 Joseph J. Webber , Thomas D. Montenegro-Johnson

From microactuators to biological tissues, non-porous materials with the ability to strongly expand when in contact with a solvent are ubiquitous. Consequently, the swelling of polymer systems such as hydrogel has received recently much…

软凝聚态物质 · 物理学 2024-11-04 George T. Fortune , Merlin A. Etzold , Julien R. Landel , Stuart B. Dalziel

We describe the growth of vesicles, due to the accretion of lipid molecules to their surface, in terms of linear irreversible thermodynamics. Our treatment differs from those previously put forward by consistently including the energy of…

统计力学 · 物理学 2009-11-13 Duccio Fanelli , Alan J. McKane

Physically assembled gels have promising applications in many fields because of their tunable mechanical properties. Here, we report the mechanical properties as a function of polymer volume fraction ($\phi$) for a physical gel system…

软凝聚态物质 · 物理学 2020-03-31 Satish Mishra , Rosa Maria Badani Prado , Santanu Kundu

Context: The thermal instability is one of the dynamical agents for turbulence in the diffuse interstellar medium, where both, turbulence and thermal instability interact in a highly non-linear manner. Aims: We study basic properties of…

星系天体物理 · 物理学 2015-05-19 D. Seifried , W. Schmidt , J. C. Niemeyer

Thermally bistable fluid tends to self-organize into clouds of hot and cold material, which are internally uniform and separated by thin conduction fronts. The evolution of these clouds has been studied for isobaric systems, but when…

等离子体物理 · 物理学 2024-07-18 Henry Fetsch , Nathaniel J. Fisch
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