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Effects of coupling between an molecular exciton and a surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons are investigated using nonequilibrium Green's function method.…

材料科学 · 物理学 2013-11-12 Kuniyuki Miwa , Mamoru Sakaue , Hideaki Kasai

This is a review of exciton dynamics in conjugated polymers. Exciton dynamics encompass multiple time and length scales. Ultrafast femtosecond processes are intrachain and involve a quantum mechanical correlation of the exciton and nuclear…

化学物理 · 物理学 2021-02-15 William Barford

Large exciton diffusion lengths generally improve the performance of organic semiconductor devices, since they enable energy to be transported farther during the exciton lifetime. However, the physics of exciton motion in disordered organic…

化学物理 · 物理学 2023-03-17 Daniel Balzer , Ivan Kassal

The coupling of excitons with atomic vibrations plays a pivotal role on the nonequilibrium optical properties of layered semiconductors. However, addressing the dynamical interaction between excitons and phonons represents a hard task both…

Previous studies have suggested a crossover from superdiffusive to normal heat transport in one-dimensional (1D) anharmonic oscillator systems with a double-well type interatomic interaction like $V(\xi)=-\xi^2/2+\xi^4/4$, when the system…

统计力学 · 物理学 2016-04-22 Daxing Xiong

We present a theoretical analysis of exciton transfer and decoherence effects in a photosynthetic dimer interacting with collective (correlated) and local (uncorrelated) protein-solvent environments. Our approach is based on the framework…

量子物理 · 物理学 2015-12-31 M. Merkli , G. P. Berman , R. T. Sayre , S. Gnanakaran , M. Könenberg , A. I. Nesterov , H. Song

We present a microscopic semi-analytical theory for the description of organic molecules interacting strongly with a cavity mode. Exciton-vibration coupling within the molecule and exciton-cavity interaction are treated on an equal footing…

介观与纳米尺度物理 · 物理学 2016-11-15 Ning Wu , Johannes Feist , Francisco J. Garcia-Vidal

Recent observations of beating signals in the excitation energy transfer dynamics of photosynthetic complexes have been interpreted as evidence for sustained coherences that are sufficiently long-lived for energy transport and coherence to…

量子物理 · 物理学 2013-03-05 A. W. Chin , J. Prior , R. Rosenbach , F. Caycedo-Soler , S. F. Huelga , M. B. Plenio

Motivated by recent advances in the investigation of fluctuation-driven ratchets and flows in excited granular media, we have carried out experimental and simulational studies to explore the horizontal transport of granular particles in a…

统计力学 · 物理学 2009-10-31 Z. Farkas , P. Tegzes , A. Vukics , T. Vicsek

In organic semiconductors working under ambient circumstance, there are remarkable quantum effects lack of comprehensive understanding, and an exotic composite particle named charge transfer (CT) exciton is normally regarded as the key…

介观与纳米尺度物理 · 物理学 2021-12-07 Yao Yao

We consider exciton effects on current in molecular nanojunctions, using a model comprising a two two-level sites bridge connecting free electron reservoirs. Expanding the density operator in the many-electron eigenstates of the uncoupled…

强关联电子 · 物理学 2015-05-14 GuangQi Li , Boris D. Fainberg , Abraham Nitzan , Sigmund Kohler , Peter Hänggi

Two-dimensional optical spectroscopy experiments have shown that exciton transfer pathways in the Fenna-Matthews-Olson (FMO) photosynthetic complex differ drastically under reduced and oxidised conditions, suggesting a functional role for…

Raman spectra obtained by the inelastic scattering of light by crystalline solids contain contributions from first-order vibrational processes (e.g. the emission or absorption of one phonon, a quantum of vibration) as well as higher-order…

材料科学 · 物理学 2017-08-22 Yannick Gillet , Stefan Kontur , Matteo Giantomassi , Claudia Draxl , Xavier Gonze

It is demonstrated that non-equilibrium vibrational effects are enhanced in molecular devices for which the effective potential for vibrations is sensitive to the charge state of the device. We calculate the electron tunneling current…

介观与纳米尺度物理 · 物理学 2007-05-23 Maarten R. Wegewijs , Katja C. Nowack

The rise of organic electronics calls for versatile modeling tools. In this context, we develop a semiclassical Boltzmann theory that describes transport and excitonic processes in crystalline organic semiconductors on equal footing. The…

材料科学 · 物理学 2022-05-03 Charlotte Bäcker , Linus Thummel , Carsten Timm

A chain of cofacial molecules with CN or CNh symmetry supports excitonic states with a screw-like structure. These can be quantified with the combination of an axial wavenumber and an azimuthal winding number. Combinations of these states…

强关联电子 · 物理学 2017-10-11 Xiaoning Zang , Mark T. Lusk

We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

介观与纳米尺度物理 · 物理学 2013-02-18 R. Härtle , M. Butzin , M. Thoss

A time-dependent approach is used to explore inelastic effects during electron transport through few-level systems. We study a tight-binding chain with one and two sites connected to vibrations. This simple but transparent model gives…

介观与纳米尺度物理 · 物理学 2009-11-13 S. Monturet , N. Lorente

We present a novel, counter-intuitive method, based on dark state protection, for significantly improving exciton transport efficiency through `wires' comprising a chain of molecular sites with an intrinsic energy gradient. Specifically, by…

量子物理 · 物理学 2020-10-07 Scott Davidson , Amir Fruchtman , Felix Pollock , Erik Gauger

The spectral properties of one exciton trapped in a self-assembled multi-layered quantum dot is obtained using a high precision variational numerical method. The exciton Hamiltonian includes the effect of the polarization charges, induced…

量子物理 · 物理学 2014-12-24 Mariano Garagiola , Omar Osenda