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We demonstrate scaffolding of plasmonic nanoparticles by topological defects induced by colloidal microspheres to match their surface boundary conditions with a uniform far-field alignment in a liquid crystal host. Displacing energetically…

Cholesteric liquid crystals can exhibit spatial patterns in molecular alignment at interfaces that can be exploited for particle assembly. These patterns emerge from the competition between bulk and surface energies, tunable with the system…

软凝聚态物质 · 物理学 2023-11-30 Lisa Tran , Kyle J. M. Bishop

Elastic sheets with macroscopic dimensions are easy to deform by bending and stretching. Yet shaping nanometric sheets by mechanical manipulation is hard. Here we show that nanoparticle self-assembly could be used to this end. We…

软凝聚态物质 · 物理学 2015-05-20 Josep C. Pàmies , Angelo Cacciuto

Capillary forces guide the motion of biomolecular condensates, water-borne insects, and breakfast cereal. These surface-mediated interactions can be harnessed to build units into materials with exotic properties deriving from mesoscale…

软凝聚态物质 · 物理学 2025-07-22 Anshu Thapa , Robert Malinowski , Matthew O. Blunt , Giorgio Volpe , Joe Forth

Self-assembly of nanoparticles at fluid-fluid interfaces is a promising route to fabricate functional materials from the bottom-up. However, directing and controlling particles into highly tunable and predictable structures -- while…

软凝聚态物质 · 物理学 2019-09-25 Qingguang Xie , Gary B. Davies , Jens Harting

Periodic assemblies of nanoparticles are central to surface patterning, with applications in biosensing, energy conversion, and nanofabrication. Evaporation of colloidal droplets on substrates provides a simple yet effective route to…

软凝聚态物质 · 物理学 2026-01-29 Suman Bhattacharjee , Sanjoy Khawas , Sunita Srivastava

The directed self-assembly of colloidal nanoparticles (NPs) using external fields guides the formation of sophisticated hierarchical materials but becomes less effective with decreasing particle size. As an alternative, electron-beam-driven…

软凝聚态物质 · 物理学 2024-09-13 Jonathan G. Raybin , Ethan J. Dunsworth , Veronica Guo , Naomi S. Ginsberg

Experimental investigations of hydrophobic/water interfaces often return controversial results, possibly due to the unknown role of gas accumulation at the interfaces. Here, during advanced atomic force microscopy of the initial evolution…

介观与纳米尺度物理 · 物理学 2015-12-29 Ing-Shouh Hwang , Chung-Kai Fang , Hsien-Chen Ko , Chih-Wen Yang , Yi-Hsien Lu

Colloidal systems find important applications ranging from fabrication of photonic crystals to direct probing of phenomena typically encountered in atomic crystals and glasses. New applications - such as nanoantennas, plasmonic sensors, and…

软凝聚态物质 · 物理学 2016-12-30 Rahul P. Trivedi , Ivan I. Klevets , Bohdan Senyuk , Taewoo Lee , Ivan I. Smalyukh

Self-assembly of nanoparticles can enable composites with pre-designed properties but remains challenged by reproducing structural diversity of atomic and molecular crystals. We combine anisotropic elastic and weakly screened electrostatic…

软凝聚态物质 · 物理学 2016-12-09 Haridas Mundoor , Bohdan Senyuk , Ivan I. Smalyukh

Control of physical behaviors of nematic colloids and colloidal crystals has been demonstrated by tuning particle shape, topology, chirality and surface charging. However, the capability of altering physical behaviors of such soft matter…

软凝聚态物质 · 物理学 2021-01-12 Ye Yuan , Patrick Keller , Ivan I. Smalyukh

Targeting specific technological applications requires the control of nanoparticle properties, especially the crystalline polymorph. Freezing a nanodroplet deposited on a solid substrate leads to the formation of crystalline structures. We…

软凝聚态物质 · 物理学 2018-03-02 Julien Lam , James F. Lutsko

Studies of nanoparticle-based optical matter have only considered spherical constituents. Yet nanoparticles with other shapes are expected to have different local electromagnetic field distributions and therefore interactions with neighbors…

介观与纳米尺度物理 · 物理学 2018-08-01 Delphine Coursault , Nishant Sule , John Parker , Ying Bao , Norbert F. Scherer

Ordering nanoparticles into a desired super-structure is often crucial for their technological applications. We use molecular dynamics simulations to study the assembly of nanoparticles in a polymer brush randomly grafted to a planar…

软凝聚态物质 · 物理学 2017-12-11 Shengfeng Cheng , Mark J. Stevens , Gary S. Grest

Droplet-based microfluidics has emerged as a powerful technology for the miniaturization and automation of biochemical assays. The replacement of surfactants by nanoparticles as interfacial stabilizers has gained increasing interest.…

软凝聚态物质 · 物理学 2019-06-21 Laura Andreina Chacon Orellana , Jean-Christophe Baret

Hypothesis: Sample-spanning particle networks are used to induce structure and a yield stress, necessary for 3D printing of porous ceramics and paints. In capillary suspensions, a small quantity of immiscible secondary fluid is incorporated…

软凝聚态物质 · 物理学 2024-04-17 Lingyue Liu , Jens Allard , Erin Koos

We study the self-assembly of colloidal microgel particles at a quasi-two-dimensional air-water interface of a drying droplet. Using bright-field microscopy, we demonstrate that increasing particle elasticity drives interfacial organization…

软凝聚态物质 · 物理学 2026-03-10 Vaibhav Raj Singh Parmar , Sayantan Chanda , Rituparno Mandal , Ranjini Bandyopadhyay

We demonstrate a variety of ordered patterns, including hexagonal structures and chains, formed by colloidal particles (droplets) at the free surface of a nematic liquid crystal (LC). The surface placement introduces a new type of particle…

软凝聚态物质 · 物理学 2009-11-10 I. I. Smalyukh , S. Chernyshuk , B. I. Lev , A. B. Nych , U. Ognysta , V. G. Nazarenko , O. D. Lavrentovich

Block copolymers often create droplets when placed on a substrate. Such nanostructured droplets can be arranged into regular microstructured arrays, thereby forming hierarchically organized materials that can be used in microelectronics,…

软凝聚态物质 · 物理学 2026-05-04 Artem Petrov , Guillermo A. Hernández-Mendoza , Alfredo Alexander-Katz

We present three-dimensional numerical simulations, employing the well-established lattice Boltzmann method, and investigate similarities and differences between surfactants and nanoparticles as additives at a fluid-fluid interface. We…

软凝聚态物质 · 物理学 2012-07-26 Stefan Frijters , Florian Günther , Jens Harting
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