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We present dynamic density functional theory (DDFT) incorporating general inhomogeneous, incompressible, time dependent background flows and inertia, describing externally driven passive colloidal systems out of equilibrium. We start by…

软凝聚态物质 · 物理学 2024-09-11 Rory D. Mills-Williams , Benjamin D. Goddard , Andrew J. Archer

Odd diffusion breaks time-reversal symmetry in overdamped systems through transverse probability currents while preserving equilibrium steady states. In this work, we develop a dynamical density functional theory (DDFT) for dense…

软凝聚态物质 · 物理学 2026-02-02 Iman Abdoli , René Wittmann , Hartmut Löwen

We show that one may view the self and the distinct part of the van Hove dynamic correlation function of a simple fluid as the one-body density distributions of a binary mixture that evolve in time according to dynamical density functional…

软凝聚态物质 · 物理学 2011-11-09 Andrew J. Archer , Paul Hopkins , Matthias Schmidt

The Dynamic Density Functional (DDF) theory and standard Brownian dynamics simulations (BDS) are used to study the drifting effects of a colloidal particle in a polymer solution, both for ideal and interacting polymers. The structure of the…

软凝聚态物质 · 物理学 2009-11-10 F. Penna , J. Dzubiella , P. Tarazona

Dynamical density functional theory (DDFT) has been successfully derived and applied to describe on the one hand passive colloidal suspensions, including hydrodynamic interactions between individual particles. On the other hand, active…

统计力学 · 物理学 2016-01-18 Andreas M. Menzel , Arnab Saha , Christian Hoell , Hartmut Löwen

Classical density functional theory (cDFT) and dynamical density functional theory (DDFT) are modern statistical mechanical theories for modeling many-body colloidal systems at the one-body density level. The theories hinge on knowing the…

Understanding the nanoscale effects controlling the dynamics of a contact line -- defined as the line formed at the junction of two fluid phases and a solid -- has been a longstanding problem in fluid mechanics pushing experimental and…

流体动力学 · 物理学 2025-01-06 Andreas Nold , Benjamin D. Goddard , David N. Sibley , Serafim Kalliadasis

The Dean-Kawasaki (DK) equation, which is at the basis of stochastic density functional theory (SDFT), was proposed in the mid-nineties to describe the evolution of the density of interacting Brownian particles, which can represent a large…

软凝聚态物质 · 物理学 2025-05-13 Pierre Illien

We apply the macroscopic fluctuation theory (MFT) to study the large-scale dynamical properties of Brownian particles with arbitrary pairwise interaction. By combining it with standard results of equilibrium statistical mechanics for the…

统计力学 · 物理学 2026-05-19 Aurélien Grabsch , Davide Venturelli , Olivier Bénichou

Density-functional theory (DFT) has been widely used to study water and ice for at least 20 years. However, the reliability of different DFT exchange-correlation (xc) functionals for water remains a matter of considerable debate. This is…

Stimuli-responsive macromolecules display large conformational changes during their dynamics, sometimes switching states, and are an integral property for the development of soft functional materials. Here, we introduce a mean-field…

软凝聚态物质 · 物理学 2024-07-02 José López-Molina , Sebastien Groh , Joachim Dzubiella , Arturo Moncho-Jordá

Large biomolecular systems, whose function may involve thousands of atoms, cannot easily be addressed with parameter-free density functional theory (DFT) calculations. Until recently a central problem was that such systems possess an…

材料科学 · 物理学 2026-01-29 Kristian Berland , Elisa Londero , Elsebeth Schroder , Per Hyldgaard

We derive a closed equation for the empirical concentration of colloidal particles in the presence of both hydrodynamic and direct interactions. The ensemble average of our functional Langevin equation reproduces known deterministic Dynamic…

统计力学 · 物理学 2015-06-19 A. Donev , E. Vanden-Eijnden

Dynamical density functional theory (DDFT) is a powerful variational framework to study the nonequilibrium properties of colloids by only considering a time-dependent one-body number density. Despite the large number of recent successes,…

软凝聚态物质 · 物理学 2021-01-13 René Wittmann , Hartmut Löwen , Joseph M. Brader

In recent years, a number of dynamical density functional theories (DDFTs) have been developed for describing the dynamics of the one-body density of both colloidal and atomic fluids. In the colloidal case, the particles are assumed to have…

软凝聚态物质 · 物理学 2009-08-10 A. J. Archer

The van der Waals density functional (vdW-DF) of Dion et al. [Phys. Rev. Lett. 92, 246401 (2004)] is a promising approach for including dispersion in approximate density functional theory exchange-correlation functionals. Indeed, an…

材料科学 · 物理学 2013-01-30 Jiří Klimeš , David R. Bowler , Angelos Michaelides

We perform Brownian dynamics simulations for studying the self-diffusion in two-dimensional (2D) dusty plasma liquids, in terms of both mean-square displacement and velocity autocorrelation function (VAF). Super-diffusion of charged dust…

等离子体物理 · 物理学 2009-02-25 Lu-Jing Hou , Alexander Piel , P. K. Shukla

Motivated by recent studies on the dynamics of colloidal solutions in narrow channels, we consider the steady state properties of an assembly of non interacting particles subject to the action of a traveling potential moving at a constant…

软凝聚态物质 · 物理学 2009-11-13 Pedro Tarazona , Umberto Marini Bettolo Marconi

Two-dimensional mixtures of dipolar colloidal particles with different dipole moments exhibit extremely rich self-assembly behaviour and are relevant to a wide range of experimental systems, including charged and super-paramagnetic colloids…

软凝聚态物质 · 物理学 2019-04-16 W. R. C. Somerville , J. L. Stokes , A. M. Adawi , T. S. Horozov , A. J. Archer , D. M. A. Buzza

We perform extensive MD simulations of two-dimensional systems of hard disks, focusing on the \emph{on}-collision statistical properties. We analyze the distribution functions of velocity, free flight time and free path length for packing…

统计力学 · 物理学 2015-09-02 Alessandro Taloni , Yasmine Meroz , Adrián Huerta