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We present measurements of the thermal expansion coefficient $\alpha$ of polycrystalline RFeAsO (R = La,Ce,Pr,Sm,Gd). Anomalies at the magnetic ordering transitions indicate a significant magneto-elastic coupling and a negative pressure…

超导电性 · 物理学 2015-05-14 R. Klingeler , L. Wang , U. Kohler , G. Behr , C. Hess , B. Buchner

A neptunium analogue of the LaFeAsO tetragonal layered compound has been synthesized and characterized by a variety of experimental techniques. The occurrence of long-range magnetic order below a critical temperature T_N = 57 K is suggested…

We present measurements of the thermal expansion coefficient alpha of polycrystalline LaFeAsO1-xFx (x <= 0.1). The magnetic and structural transitions of the samples with x <= 0.04 give rise to large anomalies in alpha(T), while the onset…

超导电性 · 物理学 2015-05-13 L. Wang , U. Kohler , N. Leps , A. Kondrat , M. Nale , A. Gasparini , A. de Visser , G. Behr , C. Hess , R. Klingeler , B. Buchner

The fluorine-doped rare-earth iron oxyarsenides, REFeAsO1-xFx (RE =rare earth) have recently emerged as a new family of high-temperature superconductors with transition temperatures (Tc) as high as 55 K (refs 1-4). Early work has provided…

Neutron powder diffraction has been used to investigate the structural and magnetic behavior of the isoelectronically doped Fe pnictide material PrFe1-xRuxAsO. Substitution of Ru for Fe suppresses the structural and magnetic phase…

Correlation between structural/microstructural and magneto-thermal transport properties of FeAs-based SmFeAsO and SmFeAsO0.85F0.15 has been studied in detail. The Rietveld analysis of room temperature powder X-ray diffraction (XRD) data…

Establishing a complete electronic phase diagram for REFeAsO (RE = rare earth, RE1111) ironbased superconductors has remained experimentally challenging. Here, we report a systematic investigation of PrFeAsO1-xFx over the full nominal…

A comparative study of thermal properties of SmFeAsO, SmFeAs(O0.93F0.07) and SmFeAs(O0.85F0.15) samples is presented. Specific heat and thermal conductivity show clear evidences of the spin density wave (SDW) ordering below TSDW 135 K in…

The magnetic ordering and crystal structure of iron pnictide SrFeAsF was investigated by using neutron powder diffraction method. With decreasing temperature, the tetragonal to orthorhombic phase transition is found at 180 K, while the…

Superconducting poly- and single-crystalline samples of Sm1-xThxFeAsO with partial substitution of Sm3+ by Th4+ were synthesized and grown under high pressure and their structural, magnetic and transport properties are studied. The…

超导电性 · 物理学 2011-05-25 N. D. Zhigadlo , S. Katrych , S. Weyeneth , R. Puzniak , P. Moll , Z. Bukowski , J. Karpinski , H. Keller , B. Batlogg

EXAFS studies at the As K edge as a function of temperature have been carried out in SmFeAsO$_{1-x}$F$_x$ ($x$ = 0 and 0.2) compounds to understand the role of local structural distortions superconductivity observed in F doped compound. A…

超导电性 · 物理学 2015-06-19 Kapil Ingle , K. R. Priolkar , Anand Pal , V. P. S. Awana , S. Emura

We present results from a detailed experimental investigation of LaFeAsO, the parent material in the series of "FeAs" based oxypnictide superconductors. Upon cooling this material undergoes a tetragonal-orthorhombic crystallographic phase…

The new quaternary iron arsenide-fluoride SrFeAsF with the tetragonal ZrCuSiAs-type structure was synthesized and the crystal structure was determined by X-ray powder diffraction (P4/nmm, a = 399.30(1), c = 895.46(1) pm). SrFeAsF undergoes…

超导电性 · 物理学 2009-01-06 M. Tegel , S. Johansson , V. Weiss , I. Schellenberg , W. Hermes , R. Poettgen , Dirk Johrendt

The electronic phase diagram of PrFeAsO$_{1-x}$F$_{x}$ (0$\leq$x$\leq$0.225) has been determined using synchrotron X-ray powder diffraction, magnetization and resistivity measurements. The structural transition temperature is suppressed…

We report measurements of resistivity, magnetoresistivity, Hall effect, Seebeck coefficient, infrared reflectivity of undoped SmFeAsO and lightly doped SmFeAs(O0.93F0.07) oxypnictides. All the properties measured on SmFeAsO are…

High-resolution thermal-expansion and specific-heat measurements were performed on single crystalline BaFe2(As1-xPx)2 (0 < x < 0.33, x = 1). The observation of clear anomalies allows to establish the thermodynamic phase diagram which…

We report plane-polarized Raman scattering spectra of iron oxypnictide superconductor NdFeAsO$_{1-x}$F$_x$ single crystals with varying fluorine $x$ content. The spectra exhibit sharp and symmetrical phonon lines with a weak dependence on…

超导电性 · 物理学 2009-11-13 Y. Gallais , A. Sacuto , M. Cazayous , P. Cheng , L. Fang , H. H. Wen

High resolution synchrotron X-ray powder diffraction (SXRPD) was used to study the temperature dependence of the oxygen deficient NdFeAsO$_{0.85}$ superconducting compound. By employing a dense temperature sampling we have managed to reveal…

超导电性 · 物理学 2010-12-08 M. Calamiotou , I. Margiolaki , A. Gantis , E. Siranidi , Z. A. Ren , Z. X. Zhao , E. Liarokapis

The low-temperature antiferromagnetic state of the Sm-ions in both nonsuperconducting SmFeAsO and superconducting SmFeAsO$_{0.9}$F$_{0.1}$ single crystals was studied by magnetic torque, magnetization, and magnetoresistance measurements in…

The phase diagram of NdFe1-xCoxAsO for low cobalt substitution consists of a superconducting dome (0.05 < x < 0.20) with a maximum critical temperature of 16.5(2) K for x = 0.12. The x = 1 end member, NdCoAsO, is an itinerant ferromagnet…

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