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The atmospheres of small exoplanets likely derive from a combination of geochemical outgassing and primordial gases left over from formation. Secondary atmospheres, such as those of Earth, Mars and Venus, are sourced by outgassing.…
Earth's water, intrinsic oxidation state, and metal core density are fundamental chemical features of our planet. Studies of exoplanets provide a useful context for elucidating the source of these chemical traits. Planet formation and…
Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths…
Terrestrial-like exoplanets may obtain atmospheres from three primary sources: Capture of nebular gases, degassing during accretion, and degassing from subsequent tectonic activity. Here we model degassing during accretion to estimate the…
Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial…
Here we investigate how small amounts of hydrogen (much smaller than the mass of the exoplanet) above a magma ocean on a rocky exoplanet may modify the atmospheric chemistry and atmospheric escape.We use a chemical model of a magma ocean…
Currently, there are about 3 dozen known super-Earth (M < 10 MEarth), of which 8 are transiting planets suitable for atmospheric follow-up observations. Some of the planets are exposed to extreme temperatures as they orbit close to their…
Hydrogen in rocky planet atmospheres has been invoked in arguments for extending the habitable zone via N2-H2 and CO2-H2 greenhouse warming, and providing atmospheric conditions suitable for efficient production of prebiotic molecules. On…
Recent studies have unequivocally proven the existence of clouds in super-Earth atmospheres (Kreidberg et al. 2014). Here we provide a theoretical context for the formation of super-Earth clouds by determining which condensates are likely…
Terrestrial exoplanets likely form initial atmospheres through outgassing during and after accretion, although there is currently no first-principles understanding of how to connect a planet's bulk composition to its early atmospheric…
It is now understood that the accretion of terrestrial planets naturally involves giant collisions, the moon-forming impact being a well known example. In the aftermath of such collisions the surface of the surviving planet is very hot and…
Atmospheric chemistry models have shown molecular oxygen can build up in CO2-dominated atmospheres on potentially habitable exoplanets without an input of life. Existing models typically assume a surface pressure of 1 bar. Here we present…
We consider super-Earth sized planets which have a water mass fraction that is large enough to form an external mantle composed of high pressure water ice polymorphs and that lack a substantial H/He atmosphere. We consider such planets in…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial…
Photochemistry has the potential to substantially impact the atmospheric composition of exoplanets with consequences on the radiative transfer, thermal structure and dynamics of the atmospheres, particularly in UV-rich stellar environments.…
In the last few years astronomical surveys have expanded the reach of planetary science into the realm of small and dense extrasolar worlds. These share a number of characteristics with the terrestrial and icy planetary objects of the Solar…
We propose a classification of exoplanet atmospheres based on their H, C, O, N element abundances below about 600 K. Chemical equilibrium models were run for all combinations of H, C, N, O abundances, and three types of solutions were…
Understanding the evolution of Earth and potentially habitable Earth-like worlds is essential to fathom our origin in the Universe. The search for Earth-like planets in the habitable zone and investigation of their atmospheres with climate…
Little is known about the interaction between atmospheres and crusts of exoplanets so far, but future space missions and ground-based instruments are expected to detect molecular features in the spectra of hot rocky exoplanets. We aim to…
Oxygen is a well-studied biosignature. Studying potential abiotic pathways for O2 build-up in exoplanet atmospheres is essential for evaluating whether the detection of O2 would constitute a biosignature detection on other worlds. Previous…