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We use accurate ab initio and quantum scattering calculations to explore the prospects for sympathetic cooling of the heavy molecular radical SrOH($^2\Sigma$) by ultracold Li atoms in a magnetic trap. A two-dimensional potential energy…

原子物理 · 物理学 2017-07-05 Masato Morita , Jacek Kłos , Alexei A. Buchachenko , Timur V. Tscherbul

We prepare mixtures of ultracold CaF molecules and Rb atoms in a magnetic trap and study their inelastic collisions. When the atoms are prepared in the spin-stretched state and the molecules in the spin-stretched component of the first…

The prospects of sympathetic cooling of polar molecules with magnetically co-trapped alkali-metal atoms are generally considered poor due to strongly anisotropic atom-molecule interactions leading to large spin relaxation rates. Using…

原子物理 · 物理学 2012-02-06 T. V. Tscherbul , J. Klos , A. A. Buchachenko

We report numerically exact quantum scattering calculations on magnetic Feshbach resonances in ultracold, strongly anisotropic atom-molecule [Rb($^2$S) + SrF($^2\Sigma^+$)] collisions based on state-of-the-art ab initio potential energy…

We model sympathetic cooling of ground-state CaF molecules by ultracold Li and Rb atoms. The molecules are moving in a microwave trap, while the atoms are trapped magnetically. We calculate the differential elastic cross sections for CaF-Li…

原子物理 · 物理学 2015-11-18 Jongseok Lim , Matthew D. Frye , Jeremy M. Hutson , M. R. Tarbutt

We present an accurate quantum mechanical study of molecule-molecule collisions in the presence of a magnetic field. The work focusses on the analysis of elastic scattering and spin relaxation in collisions of O2(3Sigma_g) molecules at cold…

原子物理 · 物理学 2012-02-06 T. V. Tscherbul , Yu. V. Suleimanov , V. Aquilanti , R. V. Krems

We report on measurements of the collisional properties of a mixture of $^{133}$Cs and $^{87}$Rb atoms in a magnetic trap at $\mu\mathrm{K}$ temperatures. By selectively evaporating the Rb atoms using a radio-frequency field, we achieved…

软凝聚态物质 · 物理学 2009-11-10 M. Anderlini , E. Courtade , M. Cristiani , D. Cossart , D. Ciampini , C. Sias , O. Morsch , E. Arimondo

We investigate the energetics of the atom exchange reaction in the SrF+alkali-metal atom and CaF+alkali-metal atom systems. Such reactions are possible only for collisions of SrF and CaF with the lithium atoms, while they are energetically…

化学物理 · 物理学 2017-07-05 Maciej Kosicki , Dariusz Kedziera , Piotr Zuchowski

We present a rigorous theoretical study of low-temperature collisions of polyatomic molecular radicals with ^1S_0 atoms in the presence of an external magnetic field. Accurate quantum scattering calculations based on ab initio and scaled…

原子物理 · 物理学 2011-03-07 T. V. Tscherbul , H-G. Yu , A. Dalgarno

State-of-the-art {\em ab initio} techniques have been applied to compute the potential energy curves of the (BaRb)$^+$ molecular ion in the Born-Oppenheimer approximation. The long-range coefficients describing the electrostatic, induction,…

We present accurate ab initio and quantum scattering calculations on a prototypical hybrid ion-atom system Yb$^+$-Rb, recently suggested as a promising candidate for the experimental study of open quantum systems, quantum information…

原子物理 · 物理学 2016-09-29 Timur V. Tscherbul , Paul Brumer , Alexei A. Buchachenko

We have computed ab inito cross sections for cold collisions of Rb atoms with OH radicals. We predict collision rate constants of order 10^{-11} cm^3/s at temperatures in the range 10-100 mK at which molecules have already been produced…

原子物理 · 物理学 2009-11-13 M. Lara , J. L. Bohn , D. Potter , P. Soldan , J. Hutson

We explore the quantum dynamics of nuclear spin relaxation in cold collisions of $^1\Sigma^+$ molecules with structureless atoms in an external magnetic field. To this end, we develop a rigorous coupled-channel methodology, which accounts…

化学物理 · 物理学 2023-06-29 Rebekah Hermsmeier , Xiaodong Xing , Timur V. Tscherbul

We develop a rigorous quantum mechanical theory for collisions of polyatomic molecular radicals with S-state atoms in the presence of an external magnetic field. The theory is based on a fully uncoupled space-fixed basis set representation…

We have calculated elastic and state-resolved inelastic cross sections for cold and ultracold collisions in the Rb($^1 S$) + OH($^2 \Pi_{3/2}$) system, including fine-structure and hyperfine effects. We have developed a new set of five…

原子物理 · 物理学 2015-06-26 Manuel Lara , John L. Bohn , Daniel E. Potter , Pavel Soldán , Jeremy M. Hutson

We report a combined experimental and theoretical study of collision-induced dipolar relaxation in a cold spin-polarized gas of atomic nitrogen (N). We use buffer gas cooling to create trapped samples of 14N and 15N atoms with densities…

原子物理 · 物理学 2011-03-07 T. V. Tscherbul , J. Klos , A. Dalgarno , B. Zygelman , Z. Pavlovic , M. T. Hummon , H-I Lu , E. Tsikata , J. M. Doyle

We carry out quantum inelastic scattering calculations of collisions of Rb atoms with inverting NH3 and ND3 molecules in the energy range between 0 and 100 cm-1, which are important for experiments using velocity-controlled molecular beams…

化学物理 · 物理学 2013-05-29 Piotr S. Żuchowski , Jeremy M. Hutson

Spin relaxation due to atom-atom collisions is measured for magnetically trapped erbium and thulium atoms at a temperature near 500 mK. The rate constants for Er-Er and Tm-Tm collisions are 3.0 times 10^-10 cm^3 s^-1 and 1.1 times 10^-10…

原子物理 · 物理学 2015-05-14 Colin B. Connolly , Yat Shan Au , S. Charles Doret , Wolfgang Ketterle , John M. Doyle

We present a multichannel scattering calculation of elastic and inelastic cold collisions between two low-field seeking, metastable ^{88}Sr [(5s5p) ^3P_2] atoms in the presence of an external magnetic field. The scattering physics is…

原子物理 · 物理学 2009-11-10 Viatcheslav Kokoouline , Robin Santra , Chris H. Greene

We describe a new implementation of magnetic collider for investigating cold collisions between ultracold atomic clouds in different spin states, and we use this to investigate scattering involving both even and odd order partial waves. Our…

其他凝聚态物理 · 物理学 2007-05-23 Angela S. Mellish , Niels Kjaergaard , Paul S. Julienne , Andrew C. Wilson
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