相关论文: Methanol ice co-desorption as a mechanism to expla…
The formation pathways of sulfur-bearing species in the interstellar medium are crucial to understand astrochemical processes in cold molecular clouds and to gain new insights about the sulfur budget in these regions. We aim to explore the…
We report the detection of methanol in the disk around the young outbursting star V883 Ori with the Atacama Large Millimeter/submillimeter Array (ALMA). Four transitions are observed with upper level energies ranging between 115 and 459 K.…
The recent discovery of methyl formate and dimethyl ether in the gas phase of cold cores with temperatures as cold as 10 K challenges our previous astrochemical models concerning the formation of complex organic molecules. The strong…
Deuterated methanol is one of the most robust windows astrochemists have on the individual chemical reactions forming deuterium-bearing molecules and the physicochemical history of the regions where they reside. The first-time detection of…
The class II masers of methanol are associated with the early stages of formation of high-mass stars. Modelling of these dense, dusty environments has demonstrated that pumping by infrared radiation can account for the observed masers.…
We present the first astrophysical detection of methanol (CH3OH) in the torsional band near 25 um. Using high resolution mid-infrared (MIR) spectroscopy, we identified over seventy gas-phase CH3OH absorption lines between 20 and 28 um…
Dust grains play an important role in the synthesis of molecules in the interstellar medium, from the simplest species to complex organic molecules. How some of these solid-state molecules are converted into gas-phase species is still a…
(Abridged) JWST observations have measured the ice composition toward two highly-extinguished field stars in the Chamaeleon I cloud. The observed extinction excess on the long-wavelength side of the H2O ice band at 3 micron has been…
Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical…
During the evolution of diffuse clouds to molecular clouds, gas-phase molecules freeze out on surfaces of small dust particles to form ices. On dust surfaces, water is the main constituent of the icy mantle in which a complex chemistry is…
We present a multilevel study of the emission of methanol, detected for the first time in this galaxy, and discuss the origin of its emission. The high observed methanol abundance of a few 10^-9 can only be explained if injection of…
We present experimental measurements of photodesorption from ices of astrophysical relevance. Layers of benzene and water ice were irradiated with a laser tuned to an electronic transition in the benzene molecule. The translational energy…
The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption…
Context. The presence of dust in the interstellar medium has profound consequences on the chemical composition of regions where stars are forming. Recent observations show that many species formed onto dust are populating the gas phase,…
We present an extensive review of gas phase reactions producing methylacetylene and propene showing that these relatively abundant unsaturated hydrocarbons cannot be synthesized through gas-phase reactions. We explain the formation of…
Context. The spatial distribution of molecules around starless cores is a powerful tool for studying the physics and chemistry governing the earliest stages of star formation. Aims. Our aim is to study the chemical differentiation in…
The expression of chirality in adsorption phenomena constitutes an important topic, not only relevant to asymmetric transformations involving solid surfaces, but also to the emergence of homochirality in both terrestrial and…
Formamide (NH2CHO) and methylamine (CH3NH2) are known to be the most abundant amine-containing molecules in many astrophysical environments. The presence of these molecules in the gas phase may result from thermal desorption of interstellar…
Nanocrystalline CuO-CuFe2O4 composite thin films were developed from CuFeO2 ceramic target using a radio frequency sputtering method followed by a thermal oxidation process. This fabrication process helps to develop porous sensing layers…
Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…