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The near-field interaction of plasmonic nanostructures and chiral molecules induces circular dichroism in achiral nanostructure. The induced circular dichroism (ICD) strength is several orders greater than the molecular inherent CD (MCD),…

The theory to calculate circular dichroism (CD) of chiral molecules in a finite cluster with arbitrarily disposed objects has been developed by means of T-matrix method. The interactions between chiral molecules and nanostructures have been…

光学 · 物理学 2018-01-01 Tong Wu , Jun Ren , Rongyao Wang , Xiangdong Zhang

Recently, there is a great interest in studying ultrasensitive detection and characterization of biomolecules using plasmonic particles, because they are of considerable importance in biomedical science and pharmaceutics. So far, all the…

光学 · 物理学 2017-12-27 Tong Wu , Weixuan Zhang , Rongyao Wang , Xiangdong Zhang

The chiral state of a molecule plays a crucial role in molecular recognition and biochemical reactions. Because of this and owing to the fact that most modern drugs are chiral, the sensitive and reliable detection of the chirality of…

介观与纳米尺度物理 · 物理学 2019-04-30 Luisa M. Kneer , Eva-Maria Roller , Lucas V. Besteiro , Robert Schreiber , Alexander O. Govorov , Tim Liedl

Circular dichroism (CD) is absorption difference of right-hand and left-hand circularly polarized light by components. CD spectroscopy technique is an important tool for detecting molecular chirality, but the molecular circular dichroism…

The ability to differentiate chiral molecules of different handedness is of great importance for chemical and life sciences. Since most of the relevant chiral molecules have their chiral transitions in the UV region, detecting their…

The plasmonic chirality has drawn a lot of attention because of the tunable circular dichroism (CD) and the enhancement for the signal of chiral molecules. Different mechanisms have been proposed for explaining the plasmonic CD, however, a…

介观与纳米尺度物理 · 物理学 2016-03-23 Li Hu , Xiaorui Tian , Yingzhou Huang , Xinqiang Wang , Yurui Fang

In the close vicinity of a chiral nanostructure, the circular dichroism of a biomolecule could be greatly enhanced, due to the interaction with the local superchiral fields. Modest enhancement of optical activity using a planar…

Molecular chirality plays a crucial role in innumerable biological processes. The chirality of a molecule can typically be identified by its characteristic optical response, the circular dichroism (CD). CD signals have thus long been used…

Chiral crystals show promise for spintronic technologies on account of their high spin selectivity, which has led to significant recent interest in quantitative characterization and first-principles prediction of their spin-optoelectronics…

材料科学 · 物理学 2023-12-05 Christian Multunas , Andrew Grieder , Junqing Xu , Yuan Ping , Ravishankar Sundararaman

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

Increasing the sensitivity of chiral spectroscopic techniques such as circular dichroism (CD) spectroscopy is a current aspiration in the research field of nanophotonics. Enhancing CD spectroscopy depends upon of two complementary…

We report on giant circular dichroism (CD) of a molecule inserted into a plasmonic hot spot. Naturally occurring molecules and biomolecules have typically CD signals in the UV range, whereas plasmonic nanocrystals exhibit strong plasmon…

介观与纳米尺度物理 · 物理学 2015-06-05 Hui Zhang , A. O. Govorov

The circular dichroism (ICD) induced from interaction of chiral molecules with achiral plasmonic metal nanostructures has improved sensitivity of molecular chirality detection. Although experimental results have presented several orders…

Circular dichroism (CD) caused by the response of a chiral object to circularly polarized light has been well established, and the strong CD of plasmonic meta-molecules has also become of interest in recent years; however, their response if…

光学 · 物理学 2020-09-30 Yangzhe Guo , Guodong Zhu , Wanlu Bian , Bin Dong , Yurui Fang

Circular dichroism (CD), i.e. the differential response of a system to left and right circularly polarized light, is one of the only techniques capable of providing morphological information of certain samples. In biology, for instance, CD…

光学 · 物理学 2014-09-16 Xavier Zambrana-Puyalto , Xavier Vidal , Gabriel Molina-Terriza

The interaction between intense light-matter not only promotes emerging applications in quantum and nonlinear optics but also facilitates changes in material properties. Plasmons can significantly enhance not only molecular chirality but…

光学 · 物理学 2025-02-03 Nan Gao , Haoran Liu , Yurui Fang

We theoretically investigate light matter interactions for chiral molecules in the presence of non-chiral nanoantennas. Isotropic nanostructures supporting optical-frequency electric or magnetic dipoles are sufficient to locally enhance the…

介观与纳米尺度物理 · 物理学 2013-06-14 Aitzol Garcia-Etxarri , Jennifer A. Dionne

Plasmonic nanocrystals with hot spots are able to localize optical energy in small spaces. In such physical systems, near-field interactions between molecules and plasmons can become especially strong. This paper considers the case of a…

介观与纳米尺度物理 · 物理学 2017-04-19 Lucas V. Besteiro , Hui Zhang , Jérôme Plain , Gil Markovich , Zhiming Wang , Alexander O. Govorov

Chiral nanophotonic devices are promising candidates for chiral molecules sensing, polarization diverse nanophotonics and display technologies. Active chiral nanophotonic devices, where the optical chirality can be controlled by an external…

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