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KCa was produced in a heatpipe oven and its thermal emission spectrum around 8900 cm$^{-1}$ was recorded by a high resolution Fourier transform spectrometer. In addition, many selected transitions of this spectrum between deeply bound…

We present the first high-resolution spectroscopic study of LiCs. LiCs is formed in a heat pipe oven and studied via laser-induced fluorescence Fourier-transform spectroscopy. By exciting molecules through the X$^1\Sigma^+$-B$^1\Pi$ and…

原子物理 · 物理学 2007-05-23 Peter Staanum , Asen Pashov , Horst Knoeckel , Eberhard Tiemann

An experimental study of the long range behavior of the ground state X^1\Sigma^+_g of Sr_2 is performed by high resolution spectroscopy of asymptotic vibrational levels and the use of available photoassociation data. Ground state levels as…

化学物理 · 物理学 2010-04-19 A. Stein , H. Knöckel , E. Tiemann

The Ti:Saphire laser operated within 13800 - 11800 cm$^{-1}$ range was used to excite the $c^3\Sigma^+$ state of KCs molecule directly from the ground $X^1\Sigma^+$ state. The laser-induced fluorescence (LIF) spectra of the $c^3\Sigma^+…

Precise potentials for the ground state X1Sigma+g and the minimum region of the excited state 2_1Sigma+u of Sr2 are derived by high resolution Fourier-transform spectroscopy of fluorescence progressions from single frequency laser…

化学物理 · 物理学 2009-01-09 A. Stein , H. Knöckel , E. Tiemann

Rotationally-resolved Fourier-transform spectra of laser-induced fluorescence (LIF) $A^1\Sigma^+_u\sim b^3\Pi_u \rightarrow X^1\Sigma^+_g$ of K$_2$ molecules were recorded and analyzed yielding 4053 term values of spin-orbit (SO) coupled $A…

原子物理 · 物理学 2023-12-29 I. Klincare , A. Lapins , M. Tamanis , R. Ferber , A. Zaitsevskii , E. A. Pazyuk , A. V. Stolyarov

A high resolution study of the electronic states 1^1\Sigma^+_u and 1^1\Pi_u which belong to the asymptote 4^1D + 5^1S and of the state 2(A)^1\Sigma^+_u, which correlates to the asymptote 5^1P + 5^1S, is performed by Fourier-transform…

化学物理 · 物理学 2015-03-19 Alexander Stein , Horst Knöckel , Eberhard Tiemann

High-resolution spectroscopy on the $A^2\Pi$ - $X^2\Sigma^+$ electronic system of $^{138}$Ba$^{19}$F is performed using a cold molecular beam produced by a buffer gas source. The hyperfine structure in both $X^2\Sigma^+$ ground and $A^2\Pi$…

We have studied the X 1{\Sigma}+ and B 1{\Pi} states of 7Li85Rb using Laser Induced Fluorescence (LIF) spectroscopy and Fluorescence Excitation Spectroscopy (FES). We extract molecular constants for levels v" = 0-2 of the X 1{\Sigma}+ state…

原子物理 · 物理学 2011-11-04 Sourav Dutta , Adeel Altaf , D. S. Elliott , Yong P. Chen

The laser induced fluorescence (LIF) spectra A1Sigma ~ b3Pi --> X1Sigma+ of KCs dimer were recorded in near infrared region by Fourier Transform Spectrometer with a resolution of 0.03 cm-1. Overall more than 200 LIF spectra were…

原子物理 · 物理学 2015-05-14 A. Kruzins , I. Klincare , O. Nikolayeva , M. Tamanis , R. Ferber , E. A. Pazyuk , A. V. Stolyarov

The 4503 rovibronic term values belonging to the mutually perturbed $A^1\Sigma^+_u$ and $b^3\Pi_u$ states of Cs$_2$ were extracted from laser induced fluorescence (LIF) $A\sim b\rightarrow X^1\Sigma^+_g$ Fourier transform spectra with the…

原子物理 · 物理学 2019-10-23 A. Znotins , A. Kruzins , M. Tamanis , R. Ferber , E. A. Pazyuk , A. V. Stolyarov , A. Zaitsevskii

Transient diode laser absorption spectroscopy has been used to measure three strong vibronic bands in the near infrared spectrum of the C$_2$H, ethynyl, radical not previously observed in the gas phase. The radical was produced by…

化学物理 · 物理学 2016-09-21 Anh T. Le , Gregory E. Hall , Trevor J. Sears

The $A^1\Sigma^+_u$ - $X^1\Sigma^+_g$ UV spectrum of Mg$_2$ has been investigated with high resolution employing Fourier-transform spectroscopy and laser excitation. Computer simulation and fit of line positions to the overlapping…

原子物理 · 物理学 2014-10-20 Horst Knöckel , Steffen Rühmann , Eberhard Tiemann

Despite its apparently simple nature with four valence electrons, the strontium dimer constitutes a challenge for modern electronic structure theory. Here we focus on excited electronic states of Sr$_2$, which we investigate theoretically…

The laser technique of polarisation labelling of levels has been used to study the excited 1$^1\Sigma^{+}_{\mathrm{u}}$ state of $^{88}$Sr$_2$, in most part heavily perturbed by the neighbouring electronic states. By observation of…

原子物理 · 物理学 2023-06-08 Jacek Szczepkowski , Wlodzimierz Jastrzebski , Anna Grochola , Pawel Kowalczyk

We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying (3)1{\Pi} and (5)1{\Sigma}+ states of the RbCs molecule. The…

原子物理 · 物理学 2019-05-22 K. Alps , A. Kruzins , O. Nikolayeva , M. Tamanis , R. Ferber , E. A. Pazyuk , A. V. Stolyarov

We present spectroscopic measurements of seven vibrational levels $v=29-35$ of the $A(1^1\Sigma_u^+)$ excited state of Li$_2$ molecules by the photoassociation of a degenerate Fermi gas of $^6$Li atoms. The absolute uncertainty of our…

原子物理 · 物理学 2013-12-17 Will Gunton , Mariusz Semczuk , Nikesh S. Dattani , Kirk W. Madison

We report on hyperfine-resolved laser spectroscopy of the A$^2\Pi \leftarrow $X$^2\Sigma^+$ transition of MgF, relevant for laser cooling. We recorded 25 rotational transitions with an absolute accuracy of better than 20 MHz, assigned 56…

原子物理 · 物理学 2022-04-13 M. Doppelbauer , S. C. Wright , S. Hofsäss , B. G. Sartakov , G. Meijer , S. Truppe

We present the first direct excitation of the presumably ultra-narrow $1001 \, \textrm{nm}$ ground state transition in atomic dysproium. By using resonance ionization spectroscopy with pulsed Ti:sapphire lasers at a hot cavity laser ion…

原子物理 · 物理学 2018-10-17 Dominik Studer , Lena Maske , Patrick Windpassinger , Klaus Wendt

We report on high resolution Fourier-transform spectroscopy of fluorescence to the a^3\Sigma_u^+ state excited by two-photon or two-step excitation from the X^1\Sigma_g^+ state to the 2^3\Pi_g state in the molecule K_2. These spectroscopic…

原子物理 · 物理学 2009-11-13 A. Pashov , P. Popov , H. Knöckel , E. Tiemann
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