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The bulk photovoltaic effect (BPVE) leads to directed photo-currents and photo-voltages in bulk materials. Unlike photo-voltages in p-n junction solar cells that are limited by carrier recombination to values below the bandgap energy of the…

应用物理 · 物理学 2023-03-17 Andreas Pusch , Udo Römer , Dimitrie Culcer , Nicholas J. Ekins-Daukes

The bulk photovoltaic effect (BPVE) offers a promising avenue to surpass the efficiency limitations of current solar cell technology. However, disentangling intrinsic and extrinsic contributions to photocurrent remains a significant…

The bulk photovoltaic effect (BPVE) is a phenomenon which creates a net electrical current from sunlight in a polar noncentrosymmetric material possessing a moderate band gap. This effect is being explored as an alternative to traditional…

材料科学 · 物理学 2018-02-14 John A. Brehm

The bulk photovoltaic effect (BPVE) occurs in solids with broken inversion symmetry and refers to DC current generation due to uniform illumination, without the need of heterostructures or interfaces, a feature that is distinct from the…

材料科学 · 物理学 2022-06-02 Zhenbang Dai , Andrew M. Rappe

Photodetection is an indispensable function of optoelectronic devices in modern communication and sensing systems. Contrary to the near-infrared/visible regions, the fast and sensitive photodetectors operated at room temperature for the…

We employ first-principles calculations to investigate the ferroelectric properties and the bulk photovoltaic effect (BPVE) of antimony sulfur iodide (SbSI). The BPVE enables direct sunlight-to-electricity conversion in homogeneous…

材料科学 · 物理学 2025-06-13 Giuseppe Cuono , Subhadeep Bandyopadhyay , Andrea Droghetti , Silvia Picozzi

Bulk photovoltaic effect, which arises from crystal symmetry-driven charge carrier separation, is an intriguing physical phenomenon that has attracted extensive interest in photovoltaic application due to its junction-free photovoltaic and…

材料科学 · 物理学 2023-08-22 Xiaojuan Chen , Kang Xu , Tingxiao Qin , Yubin Wang , Yuzhong Chen , Haiyun Liu , Qihua Xiong

The bulk photovoltaic effect (BPVE) generates a direct current photocurrent under uniform irradiation and is a nonlinear optical effect traditionally studied in non-centrosymmetric materials. The two main origins of BPVE are the shift and…

介观与纳米尺度物理 · 物理学 2025-03-03 Ying-Ming Xie , Naoto Nagaosa

The correlation between the shift current mechanism for the bulk photovoltaic effect (BPVE) and the structural and electronic properties of ferroelectric perovskite oxides is not well understood. Here, we study and engineer the shift…

材料科学 · 物理学 2015-03-03 Fenggong Wang , Steve M. Young , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

Materials that rectify light into current in their bulk are desired for optoelectronic applications. In inversion-breaking Weyl semimetals, bulk photocurrents may arise due to nonlinear optical processes that are enhanced near the Weyl…

We study the bulk photovoltaic effect (BPVE) in Dirac and Weyl semimetals under two-frequency light irradiation. We show that the BPVE emerges for centrosymmetric Dirac and Weyl semimetals in the presence of light fields with frequencies…

介观与纳米尺度物理 · 物理学 2025-01-15 Yuya Ikeda , Sota Kitamura , Takahiro Morimoto

In future solar cell technologies, the thermodynamic Shockley-Queisser limit for solar-to-current conversion in traditional p-n junctions could potentially be overcome with a bulk photovoltaic effect by creating an inversion broken symmetry…

The bulk photovoltaic effect (BPVE) refers to the direct current generation in a noncentrosymmetric material under illumination and can be applied to solar energy technology. BPVE includes injection and shift currents, led by the change of…

介观与纳米尺度物理 · 物理学 2025-11-04 Bo-Xin Lin , Hsiu-Chuan Hsu

The bulk photovoltaic effect (BPVE) is a second-order optical process in noncentrosymmetric materials that converts the light into DC currents. BPVE is classified into shift current and injection current according to the generation…

材料科学 · 物理学 2023-02-21 Hanqi Pi , Shuai Zhang , Hongming Weng

Bulk photovoltaic (BPVE) effect in crystals lacking inversion symmetry offers great potential for optoelectronic applications due to its unique properties such as above bandgap photovoltage and switchable photocurrent. Because of their…

材料科学 · 物理学 2021-10-27 Amr Abdelsamie , Lu You , Le Wang , Shuzhou Li , Mingqiang Gu , Junling Wang

The bulk photovoltaic effect (BPVE) refers to the phenomenon of generating photocurrent or photovoltage in homogeneous noncentrosymmetric materials under illumination, and the intrinsic contribution to the BPVE is known as the shift current…

材料科学 · 物理学 2023-02-01 Gan Jin , Lixin He

The two-dimensional (2D) bulk photovoltaic effect (BPVE) is a cornerstone for future highly efficient 2D solar cells and optoelectronics. The ferromagnetic semiconductor 2H-FeCl2 is shown to realize a new type of BPVE in which spatial…

材料科学 · 物理学 2023-06-16 Liang Liu , Xiaolin Li , Luping Du , Xi Zhang

The bulk photovoltaic effect (BPVE) -- generation of electric currents by light in noncentrosymmetric materials in the absence of electric fields and gradients -- has been intensively investigated in the end of the last century. The…

介观与纳米尺度物理 · 物理学 2019-11-28 Boris Sturman

The bulk photovoltaic (BPV) effect that converts light into electric current is highly sensitive to the system symmetry and its electronic Bloch wavefunction. To create a sizable net electric current, it is necessary to break the…

材料科学 · 物理学 2024-07-08 Chunmei Zhang , Jian Zhou

The bulk photovoltaic effect (BPVE), a manifestation of broken centrosymmetry, has attracted interest as a probe of the symmetry and quantum geometry of materials, and for use in novel optoelectronic devices. Despite its bulk nature, the…

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