相关论文: Hamiltonian transformation to compute Thermo-osmot…

This extended article presents a thermomechanical approach for calculating the stress tensor from the thermodynamic potential of inhomogeneous fluids and some applications to ionic fluids. The technique, based on the invariance of the…

Thermo-osmotic slip -- the flow induced by a thermal gradient along a surface -- is a well-known phenomenon, but curiously there is a lack of robust molecular-simulation techniques to predict its magnitude. Here, we compare three different…

Thermo-osmotic flows, generated by applying a thermal gradient along a liquid-solid interface, could be harnessed to convert waste heat into electricity. While this phenomenon has been known for almost a century, there is a crucial need to…

Thermal forces drive several nonequilibrium phenomena able to set a fluid in motion without pressure gradients. Although the most celebrated effect is thermophoresis, also known as Ludwig-Soret effect, probably the simplest example where…

The nonequilibrium thermodynamics of an open (classical or quantum) system in strong contact with a single heat bath can be conveniently described in terms of the Hamiltonian of mean force. However, the conventional formulation is limited…

We present numerical simulations of diffusio-osmotic flow, i.e. the fluid flow generated by a concentration gradient along a solid-fluid interface. In our study, we compare a number of distinct approaches that have been proposed for…

The application of a temperature gradient along a fluid-solid interface generates stresses in the fluid causing "thermo-osmotic" flow. Much of the understanding of this phenomenon is based on Derjaguin's work relating thermo-osmotic flows…

Thermal gradients lead to macroscopic fluid motion if a confining surface is present along the gradient. This fundamental nonequilibrium effect, known as thermo-osmosis, is held responsible for particle thermophoresis in colloidal…

The motion of a fluid induced by thermal gradients in the absence of driving forces is known as thermo-osmosis. The physical explanation of this phenomenon stems from the emergence of gradients in the tangential pressure due to the presence…

We present a complete reciprocal description of particle motion inside multi-component fluids that extends the conventional Onsager formulation of non-equilibrium transport to systems where the thermodynamic forces are non-uniform on the…

Thermo-elasticity couples the deformation of an elastic (solid) body to its temperature and vice-versa. It is a solid-like property. Highlighting such property in liquids is a paradigm shift: it requires long-range collective interactions…

In a recent paper [P. Strasberg and M. Esposito, Phys. Rev. E {\bf 101}, 050101(R) (2020)] an attempt is presented to formulate the nonequilibrium thermodynamics of an open system in terms of the Hamiltonian of mean force. The purpose of…

We study the effective forces acting between colloidal particles trapped at a fluid interface which itself is exposed to a pressure field. To this end we apply what we call the ``force approach'', which relies solely on the condition of…

We report a numerical study of thermo-osmotic slip, i.e. the particle flux induced by a thermal gradient along a solid-fluid interface. To facilitate comparison with theory, we consider a model of an ideal but viscous gas. We compare three…

Using the integral transformation, the field-theoretical Hamiltonian of the statistical field theory of fluids is obtained, along with the microscopic expressions for the coefficients of the Hamiltonian. Applying this approach to the…

A simple analytical microscopic expression for the surface tension of liquids $\gamma$ is obtained which is in a good agreement with available data of numerical experiments. We apply the integral transformation that maps the fluid…

Thermo-osmotic and related thermo-phoretic phenomena can be found in many situations from biology to colloid science, but the underlying molecular mechanisms remain largely unexplored. Using molecular dynamics simulations, we measured the…

Regarding a recent dispute about the symmetry of the stress tensor of fluids, more considerations are presented. The usual proofs of this symmetry are reviewed, and contradictions between this symmetry and the mechanism of gas viscosity are…

Torques on interfaces can be described by a divergence-free tensor which is fully encoded in the geometry. This tensor consists of two terms, one originating in the couple of the stress, the other capturing an intrinsic contribution due to…

Stress tensors are derived for the multiparticle collision dynamics algorithm, a particle-based mesoscale simulation method for fluctuating fluids, resembling those of atomistic or molecular systems. Systems with periodic boundary…