相关论文: Accurate frequency determination of vibration-rota…
The rovibrational spectrum of the molecular ion H$_2$CCCH$^+$ was investigated in a 4~K cryogenic ion trap instrument employing the leak-out spectroscopy method. Transitions within the fundamental $\nu_1$ (C-H stretch) and the combination…
The rotational spectrum of the molecular ion HCNH+ is revisited using double-resonance spectroscopy in an ion trap apparatus, with six transitions measured between 74 and 445 GHz. Due to the cryogenic temperature of the trap, the hyperfine…
The long-searched C-H stretches of the fundamental ions CH$^+$ and $^{13}$CH$^+$ have been observed for the first time in the laboratory. For this, the state-dependent attachment of He atoms to these ions at cryogenic temperatures has been…
The pure rotational transitions of the protonated hydrogen cyanide ion, HCNH+, and its isotopic species, HCND+ and DCND+, were measured in the 107 - 482 GHz region with a source modulated microwave spectrometer. The ions were generated in…
The protonated Argon ion, $^{36}$ArH$^{+}$, has been identified recently in the Crab Nebula (Barlow et al. 2013) from Herschel spectra. Given the atmospheric opacity at the frequency of its $J$=1-0 and $J$=2-1 rotational transitions (617.5…
The OH$^+$ ($X ^3\Sigma^-$) radical cation has been investigated by combining a 4 K 22-pole ion trap apparatus with high-resolution IR and THz radiation sources. Applying different types of action spectroscopic methods, the fundamental…
Spectra of vibrational overtone and combination bands from vibrational ground state of HCNH+ were measured using an action spectroscopy technique with active background suppression in a cryogenic 22 pole radio frequency ion trap apparatus.…
The high resolution spectrum of the v4 band of NH3D+ has been measured by difference frequency IR laser spectroscopy in a multipass hollow cathode discharge cell. From the set of molecular constants obtained from the analysis of the…
We use quantum-logic spectroscopy (QLS) and interrogate rotational transitions of a single CaH+ ion with a highly coherent frequency comb, achieving a fractional statistical uncertainty for a transition line center of 4 x 10^-13. We also…
The rotational spectrum of silyl isocyanide (SiH$_3$NC), an isomer of the well studied silyl cyanide (SiH$_3$CN), has been detected in the laboratory in a supersonic molecular beam, and the identification was confirmed by observations of…
In this work, we report on the high-resolution infrared spectrum of CCH$^+$ ($^3\Pi$) recorded in the range $3066-3184$~cm$^{-1}$ by means of leak-out spectroscopy. This spectral range covers the fundamental of the CH stretching mode and a…
The frequencies and line strengths of the 2Pi3/2 J=5/2-3/2 rotational transition of 17OH have been calculated from an analysis of its far-infrared laser magnetic resonance spectrum. These results have been used to make the first detection…
Rotational-vibrational transitions of the fundamental vibrational modes of the $^{12}$C$^{14}$N$^+$ and $^{12}$C$^{15}$N$^+$ cations have been observed for the first time using a cryogenic ion trap apparatus with an action spectroscopy…
We improve by a factor of 4-20 the energy accuracy of the strongest soft X-ray transitions of Fe XVII ions by resonantly exciting them in an electron beam ion trap with a monochromatic beam at the P04 beamline of the PETRA III synchrotron…
Transition frequencies between low-lying energy levels in a single trapped $^{138}$Ba$^{+}$ ion have been measured with laser spectroscopy referenced to an optical frequency comb. By extracting the frequencies of one-photon and two-photon…
Recently we reported a high precision optical frequency measurement of the (v,L):(0,2)->(8,3) vibrational overtone transition in trapped deuterated molecular hydrogen (HD+) ions at 10 mK temperature. Achieving a resolution of 0.85…
We report frequency measurement of the clock transition in an 115In+ ion sympathetically-cooled with Ca+ ions in a linear rf trap. The Ca+ ions are used as a probe of the external electromagnetic field and as the coolant for preparing the…
We demonstrate rotational excitation of molecular ions that are sympathetically cooled by laser-cooled atomic ions to a temperature as low as ca. 10 mK. The molecular hydrogen ions HD+ and the fundamental rotational transition $(v=0,\,…
This work provides the first full set of vibrational and rotational spectral data needed to aid in the detection of AlH$_3$OH$_2$, SiH$_3$OH, and SiH$_3$NH$_2$ in astrophysical or simulated laboratory environments through the use of quantum…
We present high-resolution rovibronic spectroscopy of calcium monohydride molecular ions (CaH$^+$) co-trapped in a Coulomb crystal with calcium ions ($^{40}$Ca$^+$), focusing on rotational transitions in the $|X^1\Sigma^+, \nu" = 0>…