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44325 measured and assigned transitions of H$_2^{32}$S, the parent isotopologue of the hydrogen sulfide molecule, are collated from 33 publications into a single database and reviewed critically. Based on this information,…

Rovibronic energy levels are determined for four low-lying electronic states (\X, \A, \Sa, and \Sc) of the imidogen free radical ($^{14}$NH) using the \Marvel\ (Measured Active Rotational-Vibrational Energy Levels) technique. Compilation of…

Accurate, experimental rovibronic energy levels, with associated labels and uncertainties, are reported for 11 low-lying electronic states of the diatomic \TiO\ molecule, determined using the \Marvel\ (Measured Active Rotational-Vibrational…

The cyano radical (CN) is a key molecule across many different factions of astronomy and chemistry. Accurate, empirical rovibronic energy levels with uncertainties are determined for 8 doublet states of CN using the \Marvel{} (Measured…

太阳与恒星天体物理 · 物理学 2020-10-13 Anna-Maree Syme , Laura K. McKemmish

The carbon dimer, the $^{12}$C$_2$ molecule, is ubiquitous in astronomical environments. Experimental-quality rovibronic energy levels are reported for $^{12}$C$_2$, based on rovibronic transitions measured for and among its singlet,…

Published high-resolution rotation-vibration transitions of \spec{h212c16o}, the principal isotopologue of methanal, are analyzed using the MARVEL (Measured Active Rotation-Vibration Energy Levels) procedure. The literature results are…

An analysis of the measured rovibrational transitions is carried out for the 12C32S2 isotopologue of carbon disulfide. Data from 21 sources is extracted and validated using a consistent set of standard linear molecule quantum numbers. A…

原子物理 · 物理学 2025-02-28 Tanvi Sattiraju , Jonathan Tennyson

The spectrum of dicarbon (C2) is important in astrophysics and for spectroscopic studies of plasmas and flames. The C2 spectrum is characterized by many band systems with new ones still being actively identified; astronomical observations…

Carbon monoxide is thought to be the second most abundant molecule in the Universe. This makes observation of both its parent isotopologue ($^{12}$C$^{16}$O) and its stable isotopologues, $^{13}$C$^{16}$O, $^{12}$C$^{18}$O,…

星系天体物理 · 物理学 2026-01-21 Timur Grigorev , Yuhang Dai , Max Potter , Xiaoyu Xiang , Keyu Zhang , Jonathan Tennyson

The calcium monohydroxide radical (CaOH) is an important astrophysical molecule relevant to cool stars and rocky exoplanets, amongst other astronomical environments. Here, we present a consistent set of highly accurate rovibronic…

化学物理 · 物理学 2020-06-01 Y. Wang , A. Owens , J. Tennyson , S. N. Yurchenko

Zirconium oxide(ZrO) is an important astrophysical molecule that defines the S-star classification class for cool giant stars. Accurate, empirical rovibronic energy levels, with associated labels and uncertainties, are reported for 9…

We use optical frequency comb Fourier transform spectroscopy to record high-resolution, low-pressure, room-temperature spectra of formaldehyde (H$_2$$^{12}$C$^{16}$O) in the range of 1250 to 1390 cm$^{-1}$. Through line-by-line fitting, we…

Results are presented for highly accurate ab initio variational calculation of the rotation - vibration energy levels of H2O2 in its electronic ground state. These results use a recently computed potential energy surface and the variational…

The rovibronic structure of A$^2\Sigma^+$, B$^2\Pi$ and C$^2\Pi$ states of nitric oxide (NO)is studied with the aim of producing comprehensive line lists for its near ultraviolet spectrum. Empirical energy levels for the three electronic…

化学物理 · 物理学 2021-08-24 Qianwei Qu , Bridgette Cooper , Sergei N. Yurchenko , Jonathan Tennyson

Using the effective rotational Hamiltonian method, we have conducted an analysis of the D218O ground and the first excited vibration state rotational energy levels. The analysis was based on the effective Hamiltonians represented in several…

化学物理 · 物理学 2021-01-18 I. A. Vasilenko , O. V. Naumenko , E. R. Polovtseva , A. D. Bykov

Optimal set of 1050 rovibronic energy levels for 35 triplet electronic states of $D_2$ has been obtained by means of a statistical analysis of all available wavenumbers of triplet-triplet rovibronic transitions studied in emission,…

光学 · 物理学 2009-11-13 B. P. Lavrov , I. S. Umrikhin

An optimal set of 1050 rovibronic energy levels for 35 triplet electronic states of $D_2$ has been obtained by means of a statistical analysis of all available wavenumbers of triplet-triplet rovibronic transitions studied in emission,…

光学 · 物理学 2008-02-08 B. P. Lavrov , I. S. Umrikhin

The calculation of the hindered roton-phonon energy levels of a hydrogen molecule in a confining potential with different symmetries is systematized for the case when the rotational angular momentum $J$ is a good quantum number. One goal of…

凝聚态物理 · 物理学 2009-11-07 T. Yildirim , A. B. Harris

Current situation in studies of lifetimes of excited rovibronic levels for the H2, D2, T2, HD, HT, and DT molecules is analyzed. All measured values of the lifetimes (792 data for 618 different vibro-rotational levels of 33 electronic…

化学物理 · 物理学 2014-12-11 S. A. Astashkevich , B. P. Lavrov

A new ro-vibrational line list for the ground electronic state of the main isotopologue of acetylene, $^{12}$C$_2$H$_2$, is computed as part of the ExoMol project. The aCeTY line list covers the transition wavenumbers up to 10,000 cm$^{-1}$…

太阳与恒星天体物理 · 物理学 2020-02-05 Katy L. Chubb , Jonathan Tennyson , Sergey N. Yurchenko
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