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We theoretically revealed that a weak photoexcitation achieves the electric polarization-inversion with approximately $18\%$ of all the charges, which was interpreted as a superimposition of multi-exciton states, from the charge-ordered…

强关联电子 · 物理学 2019-06-12 T. Yamaguchi , K. Asada , H. Yamakawa , T. Miyamoto , K. Iwano , T. Nakamura , N. Kida , H. Okamoto

Short period ferroelectric/ferroelectric BaTiO3 (BTO)/PbTiO3 (PTO) superlattices are studied using density functional theory. Contrary to the trends in paraelectric/ferroelectric superlattices the polarization remains nearly constant for…

材料科学 · 物理学 2012-03-12 Valentino R. Cooper , Karin M. Rabe

We discovered a near room temperature lead-free relaxor-ferroelectric (Ba0.6Bi0.2Li0.2)TiO3 (BBLT) having A-site compositional disordered ABO3 perovskite structure. Microstructure-property relations revealed that the chemical…

Solid-state cooling presents an energy-efficient and environmentally friendly alternative to traditional refrigeration technologies that rely on thermodynamic cycles involving greenhouse gases. However, conventional caloric effects face…

A reduction of polarization in ultra-thin ferroelectric films appears to be fundamental to ferroelectricity at the nanoscale. For the model system PbTiO3 on SrTiO3, we report observation of the polarization vs. thickness relation. Distinct…

材料科学 · 物理学 2007-05-23 Rene Meyer , Arturas Vailionis , Paul. C. McIntyre

We explore the photodissociation of polar dimers in static electric fields in the cold regime using the example of the LiCs molecule. A giant enhancement of the differential cross section is found for laboratory electric field strengths,…

原子物理 · 物理学 2017-09-13 R. González-Férez , P. Schmelcher

Since polycrystals of alkali halides are highly useful as components in optical devices, a number of mixed crystals of NaBr and KBr have been prepared from melt by other workers. Among these crystals, it was reported that the polycrystal…

材料科学 · 物理学 2017-05-03 V. Katsika-Tsigourakou , P. Bekris

We have proposed the phenomenological description of polarization switching peculiarities in ferroelectric semiconductors with charged defects and prevailing extrinsic conductivity. Exactly we have modified Landau-Ginsburg approach shown…

材料科学 · 物理学 2009-11-10 Anna N. Morozovska , Eugeny A. Eliseev

Full pattern Le-Bail refinement using x-ray powder diffraction profiles of Sr1-xCaxTiO3 for x=0.02, 0.04 in the temperature range 12 to 300 K reveals anomalies in the unit cell parameters at 170, 225 K due to an antiferrodistortive (cubic…

材料科学 · 物理学 2015-05-13 Sanjay Kumar Mishra , Dhananjai Pandey

We have studied ferroelectricity and photovoltaic effects in atomic layer deposited (ALD) 40-nm thick SnTiO$_{x}$ films deposited directly onto p-type (001)Si substrate. These films showed well-saturated, square and repeatable hysteresis…

The effects of 2% Zr introduction in Ba0.8Ca0.2TiO3 (BCT) system on its electrical and the electrocaloric properties was investigated.

Lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT) ceramic exhibits excellent dielectric, ferroelectric and piezoelectric properties at the Morphotropic Phase Boundary (MPB). Previously, we demonstrated that the use of the anionic surfactant…

The large electrocaloric coupling in PbZrO3 allows using high-speed infrared imaging to visualize antiferroelectric switching dynamics via the associated temperature change. We find that in ceramic samples of homogeneous temperature and…

The dispersal of high dielectric constant ferroelectric ceramic material Ba(0.7)Sr(0.3)TiO(3) (Tc~30 C) and Ba(0.88)Sr(0.12)TiO(3) (Tc~90 C) in an ion conducting polymer electrolyte (PEO:NH4I) is reported to result in an increase in the…

化学物理 · 物理学 2009-11-10 Pramod Kumar Singh , Amreesh Chandra

Lead-free Ba0.85Ca0.15Ti0.9Zr0.1O3 (BCZT) ceramics had attracted much attention for the fabrication of microelectronic devices by virtue of their excellent dielectric, ferroelectric and piezoelectric properties. To understand the effects of…

Self-poled ultra-thin ferroelectric PbZr0.52Ti0.48O3 (PZT) (5 and 7 nm) films have been grown by pulsed laser deposition technique on ferromagnetic La0.67Sr0.33MnO3 (LSMO) (30 nm) to check the effect of polar capping on magnetization for…

Structural, impedance, ferroelectric and magnetic properties were examined in multiferroic Bi_{2}Fe_{4(1-x)}Co_{4x}O_{9} (0$\leq$x$\leq$0.02) ceramics synthesized via solid-state reaction method. X-ray diffraction analysis and Rietveld…

材料科学 · 物理学 2016-05-06 S. R. Mohapatra , B. Sahu , M. Chandrasekhar , P. Kumar , S. D. Kaushik , S. Rath , A. K. Singh

Recent findings of a large electrocaloric (EC) effect in polymeric and inorganic ferroelectric materials open a potential possibility of development of solid-state cooling or heating devices of new generation with better energy efficiency…

The cubic perovskite-related ceramic CaCu3Ti4O12 has a very high static dielectric constant ~10000 at room temperature (RT), which drops to about 100 below about 100 K. Substituting Cd for Ca reduces the RT value of the dielectric constant…

强关联电子 · 物理学 2007-05-23 C. C. Homes , T. Vogt , S. M. Shapiro , W. Si , S. Wakimoto , M. A. Subramanian

We investigated the physical properties of low concentration ferroelectric nematic colloids, using calorimetry, optical methods, infra-red spectroscopy and capacitance studies. The resulting colloids normally remain homogeneous, but the…