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Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…

量子物理 · 物理学 2020-12-24 L. T. Hall , D. A. Broadway , A. Stacey , D. A. Simpson , J-P. Tetienne , L. C. L. Hollenberg

Dynamic nuclear polarization (DNP) of molecules in a solution at room temperature has potential to revolutionize nuclear magnetic resonance spectroscopy and imaging. The prevalent methods for achieving DNP in solutions are typically most…

化学物理 · 物理学 2016-03-02 Qiong Chen , Ilai Schwarz , Fedor Jelezko , Alex Retzker , Martin B Plenio

Dynamic Nuclear Polarization (DNP) presently stands as the preferred strategy to enhance the sensitivity of nuclear magnetic resonance measurements, but its application relies on the use of high-frequency microwave to manipulate electron…

介观与纳米尺度物理 · 物理学 2022-02-02 Carlos A. Meriles , Pablo R. Zangara

Dynamical nuclear polarisation (DNP) is an important technique that uses polarisation transfer from electron to nuclear spins to achieve nuclear hyperpolarisation. As the electron spin of the nitrogen vacancy (NV) centres in diamond can be…

Coupled electron-nuclear spins represent a promising quantum system, where the optically induced electron spin polarization can be dynamically transferred to nuclear spins via the hyperfine interaction. Most experiments on dynamic nuclear…

材料科学 · 物理学 2026-01-13 A. N. Anisimov , A. V. Poshakinskiy , G. V. Astakhov

Dynamic nuclear polarization experiments use microwave irradiation to transfer the larger electron polarization to nuclear spins of interest, and thus enhance the NMR transitions above thermal equilibrium. How the polarization transfer from…

化学物理 · 物理学 2026-01-12 Gian-Marco Camenisch , Nino Wili , Gunnar Jeschke , Matthias Ernst

NV-diamonds have attracted keen interest for nanoscale sensing and spin manipulation. In particular, the non-equilibrium electron spin polarization after optical excitation of single NV centers has successfully been transferred to nuclear…

介观与纳米尺度物理 · 物理学 2021-11-24 R. Rizzato , F. Bruckmaier , K. S. Liu , S. J. Glaser , D. B. Bucher

Dynamic nuclear polarization (DNP) has revolutionized the field of NMR spectroscopy, expanding its reach and capabilities to investigate diverse materials, biomolecules, and complex dynamic processes. Bringing high-efficiency DNP to the…

介观与纳米尺度物理 · 物理学 2024-02-27 Sahand Tabatabaei , Pritam Priyadarsi , Namanish Singh , Pardis Sahafi , Daniel Tay , Andrew Jordan , Raffi Budakian

We report bulk, room-temperature hyperpolarization of 13C nuclear spins observed via high-field nuclear magnetic resonance (NMR). The hyperpolarization is achieved by optical pumping (OP) of nitrogen vacancy defect centers in diamond…

Dynamic nuclear polarization (DNP) is a promising strategy for generating a significantly increased non-thermal spin polarization in nuclear magnetic resonance (NMR) applications thereby circumventing the need for strong magnetic fields.…

量子物理 · 物理学 2015-07-15 Alexander Karabanov , Daniel Wisniewski , Igor Lesanovsky , Walter Köckenberger

The hyperpolarisation of nuclear spins within target molecules is a critical and complex challenge in magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) spectroscopy. Hyperpolarisation offers enormous gains in signal and…

Precision measurements based on optically detected nuclear magnetic resonance offer exquisite sensitivity to absolute shifts in spin transition frequencies, with potential applications in fundamental physics experiments and inertial…

Polarization transfers are crucial building blocks in magnetic resonance experiments, i.e., they can be used to polarize insensitive nuclei and correlate nuclear spins in multidimensional NMR spectroscopy. The polarization can be…

化学物理 · 物理学 2022-08-24 Zhenfeng Pang , Sheetal Jain , Chen Yang , Xueqian Kong , Kong Ooi Tan

Nuclear spin hyperpolarization techniques, such as dynamic nuclear polarization (DNP) and parahydrogen-induced polarization (PHIP), have revolutionized nuclear magnetic resonance and magnetic resonance imaging. In these methods, a readily…

Hyper-polarization of nuclear spins is crucial for advancing nuclear magnetic resonance (NMR) and quantum information technologies, as nuclear spins typically exhibit extremely low polarization at room temperature due to their small…

量子物理 · 物理学 2025-05-20 Haiyang Li , Hao Liao , Ping Wang

Rapid injection of spin polarization into an ensemble of nuclear spins is a problem of broad interest, spanning dynamic nuclear polarization (DNP) to quantum information science. We report on a strategy to boost the spin injection rate by…

We report polarization of a dense nuclear-spin ensemble in diamond and its dependence on magnetic field and temperature. The polarization method is based on the transfer of electron spin polarization of negatively charged nitrogen vacancy…

量子物理 · 物理学 2013-04-01 Ran Fischer , Andrey Jarmola , Pauli Kehayias , Dmitry Budker

Dynamic Nuclear Polarization (DNP) is to date the most effective technique to increase the nuclear polarization up to a factor $100,000$ opening disruptive perspectives for medical applications. In DNP, the nuclear spins are driven to an -…

强关联电子 · 物理学 2015-08-26 Andrea De Luca , Alberto Rosso

Dynamic Nuclear Polarization (DNP) is a powerful suite of techniques that deliver multifold signal enhancements in NMR and MRI. The generated athermal spin states can also be exploited for quantum sensing and as probes for many-body…

Dynamic nuclear spin polarization (DNP) mediated by paramagnetic point defects in semiconductors is a key resource for both initializing nuclear quantum memories and producing nuclear hyperpolarization. DNP is therefore an important process…

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