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We present novel, analytical, equilibrium-chemistry formulae for the abundances of molecules in hot exoplanetary atmospheres that include the carbon, oxygen and nitrogen networks. Our hydrogen-dominated solutions involve acetylene…

地球与行星天体物理 · 物理学 2016-10-05 Kevin Heng , Shang-Min Tsai

Motivated by recent spectroscopic evidence for carbon-rich atmospheres on some transiting exoplanets, we investigate the influence of the C/O ratio on the chemistry, composition, and spectra of extrasolar giant planets both from a…

地球与行星天体物理 · 物理学 2015-06-12 J. I. Moses , N. Madhusudhan , C. Visscher , R. S. Freedman

The gas mass of protoplanetary disks, and the gas-to-dust ratio, are two key elements driving the evolution of these disks and the formation of planetary system. We explore here to what extent CO (or its isotopologues) can be used as a…

太阳与恒星天体物理 · 物理学 2015-07-15 L. Reboussin , V. Wakelam , S. Guilloteau , F. Hersant , A. Dutrey

Chemical equilibrium considerations suggest that, assuming solar elemental abundances, carbon on HD 209458b is sequestered primarily as carbon monoxide (CO) and methane (CH4). The relative mole fractions of CO(g) and CH4(g) in chemical…

天体物理学 · 物理学 2008-11-26 Curtis S. Cooper , Adam P. Showman

We present results from one-dimensional atmospheric simulations investigating the effect of varying the carbon-to-oxygen (C/O) ratio on the thermal structure, chemical composition and transmission and emission spectra, for irradiated…

地球与行星天体物理 · 物理学 2019-04-10 Benjamin Drummond , Aarynn L. Carter , Eric Hébrard , Nathan J. Mayne , David K. Sing , Thomas M. Evans , Jayesh Goyal

During the accretion of Titan, impact heating may have been sufficient to allow the global melting of water ice and the release of volatile compounds, mainly constituted of CO2, CH4 and NH3. The duration and efficiency of exchange between…

地球与行星天体物理 · 物理学 2018-06-06 Nadejda Marounina , Olivier Grasset , Gabriel Tobie , Sabrina Carpy

The TRAPPIST-1 planets have become prime targets for studying the atmospheric and geophysical properties of planets around M-dwarf stars. To effectively identify their atmospheric composition, we first must understand their geological…

地球与行星天体物理 · 物理学 2025-11-17 Junellie Perez , Laura K. Schaefer , Edward Schwieterman , Kevin B. Stevenson , Howard Chen , Jacob Lustig-Yaeger

We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…

星系天体物理 · 物理学 2024-08-14 Germán Molpeceres , Kenji Furuya , Yuri Aikawa

Vertical mixing disrupts the thermochemical equilibrium and introduces additional heat flux that alters exoplanetary atmospheric temperatures. We investigate how this mixing-induced heat flux affects atmospheric chemistry. Temperature…

地球与行星天体物理 · 物理学 2025-10-27 Zhen-Tai Zhang , Wei Zhong , Wei Wang , Jianheng Guo , Xianyu Tan , Bo Ma , Ruyi Wei , Cong Yu

Molecular oxygen (O2) will be an important molecule in the search for biosignatures in terrestrial planetary atmospheres in the coming decades. In particular, O2 combined with a reducing gas is thought to be strong evidence for…

地球与行星天体物理 · 物理学 2025-07-23 Thea Kozakis , João M. Mendonça , Lars A. Buchhave , Luisa M. Lara

Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in…

Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…

We study the abundances of complex carbon-bearing molecules in the oxygen-rich dust- forming atmospheres of Brown Dwarfs and giant gas planets. The inner atmospheric re- gions that form the inner boundary for thermochemical gas-phase models…

太阳与恒星天体物理 · 物理学 2015-06-16 Camille Bilger , Paul Rimmer , Christiane Helling

The C/O ratio is predicted to regulate the atmospheric chemistry in hot Jupiters. Recent observations suggest that some exo-planets, e.g. Wasp 12- b, have atmospheric C/O ratios substantially different from the solar value of 0.54. In this…

星系天体物理 · 物理学 2015-05-30 Karin I. Oberg , Ruth Murray-Clay , Edwin A. Bergin

We address disequilibrum abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based 1D atmospheric chemistry model. Our approach is to use the…

地球与行星天体物理 · 物理学 2015-06-22 Kevin J. Zahnle , Mark S. Marley

Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths…

地球与行星天体物理 · 物理学 2015-06-18 Renyu Hu , Sara Seager

To understand the role that planet formation history has on the observable atmospheric carbon-to-oxygen ratio (C/O) we have produced a population of astrochemically evolving protoplanetary disks. Based on the parameters used in a…

地球与行星天体物理 · 物理学 2019-12-04 Alex J. Cridland , Ewine F. van Dishoeck , Matthew Alessi , Ralph E. Pudritz

We have conducted laboratory experiments to study the chemistry in hot Jupiter atmospheres with C/O ratio of 0.35. We have compared our results with the ones obtained previously for atmospheres with a C/O ratio of 1 to investigate the…

地球与行星天体物理 · 物理学 2022-04-15 Benjamin Fleury , Murthy S. Gudipati , Bryana L. Henderson , Mark Swain

[Abridged] Combining a time-dependent astrochemical model with a model of planet formation and migration, we compute the carbon-to-oxygen ratio (C/O) of a range of planetary embryos starting their formation in the inner solar system (1-3…

地球与行星天体物理 · 物理学 2019-07-17 Alex J. Cridland , Christian Eistrup , Ewine F. van Dishoeck

Cycling of carbon dioxide between the atmosphere and interior of rocky planets can stabilize global climate and enable planetary surface temperatures above freezing over geologic time. However, variations in global carbon budget and…

地球与行星天体物理 · 物理学 2022-10-25 R. J. Graham , Tim Lichtenberg , Ray Pierrehumbert