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The crystal and magnetic structure of multiferroic LiFe(WO$_4$)$_2$ were investigated by temperature and magnetic-field dependent specific heat, susceptibility and neutron diffraction experiments on single crystals. Considering only the two…

The magnetic properties of the spin-5/2 double molybdate LiFe(MoO$_4$)$_2$ have been characterized by heat capacity, magnetic susceptibility, and neutron powder diffraction techniques. Unlike the multiferroic system LiFe(MoO$_4$)$_2$ which…

Rhenium oxides belonging to the family $A$ReO$_4$ where $A$ is a metal cation, exhibit interesting electronic and magnetic properties. In this study we have utilized the muon spin rotation/relaxation ($\mu^+$SR) technique to study the…

We report the multiferroic behaviour of MnWO$_4$, a magnetic oxide with monoclinic crystal structure and spiral long-range magnetic order. Based upon recent theoretical predictions MnWO$_4$ should exhibit ferroelectric polarization…

强关联电子 · 物理学 2007-05-23 O. Heyer , N. Hollmann , I. Klassen , S. Jodlauk , L. Bohaty , P. Becker , J. A. Mydosh , T. Lorenz , D. Khomskii

The ordered magnetic states of MnWO4 at low temperatures were examined by evaluating the spin exchange interactions between the Mn2+ ions of MnWO4 on the basis of first principles density functional calculations and by performing classical…

Ferrimagnetic spinel materials of formula AB2X4, where A and B are transition metals and X is oxygen or sulphur, hold promise for the realization of multiferroic characteristics. In this work, we report synthesis of spinel CoMn2O4 and…

材料科学 · 物理学 2026-04-07 P. Kumar , P. Das , B. K. Kuanr , S. Patnaik

BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…

We report the remarkably robust ferroelectric state in the multiferroic compound Mn$_{1-x}$Zn$_x$WO$_4$. The substitution of the magnetic Mn$^{2+}$ with nonmagnetic Zn$^{2+}$ reduces the magnetic exchange and provides control of the various…

强关联电子 · 物理学 2011-01-12 R. P. Chaudhury , F. Ye , J. A. Fernandez-Baca , B. Lorenz , Y. Q. Wang , Y. Y. Sun , H. A. Mook , C. W. Chu

Trirutile-type LiFe$_2$F$_6$ is a charge-ordered material with Fe$^{2+}$/Fe$^{3+}$ configuration. Here its physical properties, including magnetism, electronic structure, phase transition, and charge ordering, are studied theoretically. On…

材料科学 · 物理学 2017-12-11 Ling-Fang Lin , Qiao-Ru Xu , Yang Zhang , Jun-Jie Zhang , Yan-Ping Liang , Shuai Dong

We report the magnetic, dielectric and ferroelectric properties of polycrystalline iron vanadate(FeVO4), which has been recently found to exhibit multiferroicity in low temperature with noncollinear magnetic orderings. The influence of…

材料科学 · 物理学 2011-02-21 L. Zhao , M. P. Y. Wu , K. W. Yeh , M. K. Wu

Cubic perovskite-structure ABO$_3$ and A$_{1-x}$A$^{\prime}$$_x$BO$_3$-type oxides have been investigated extensively while their hexagonal-structure versions have received minimal attention, even though they are multiferroic and can form…

材料科学 · 物理学 2024-01-29 M. J. Swamynadhan , Andrew O'Hara , Saurabh Ghosh , Sokrates T. Pantelides

We report multiferroic behavior in double perovskite Y2CoMnO6 with ferroelectric transition temperature Tc = 80K. The origin of ferroelectricity is associated with magnetic ordering of Co2+ and Mn4+ moments in a up-up-down-down arrangement.…

材料科学 · 物理学 2015-06-15 G. Sharma , J. Saha , S. Patnaik

Iron tungstate (FeWO$_4$) and manganese tungstate (MnWO$_4$) belong to a family of wolframite-type materials that has applications in various areas, including supercapacitors, batteries, and multiferroics. A detailed understanding of bulk…

材料科学 · 物理学 2017-10-30 Khang Hoang

The olivine compound Mn2GeO4 is shown to feature both a ferroelectric polarization and a ferromagnetic magnetization that are directly coupled and point along the same direction. We show that a spin spiral generates ferroelectricity (FE),…

材料科学 · 物理学 2012-08-07 J. S. White , T. Honda , K. Kimura , T. Kimura , Ch. Niedermayer , O. Zaharko , A. Poole , B. Roessli , M. Kenzelmann

Despite remarkable progress in developing multifunctional materials, spin-driven ferroelectrics featuring both spontaneous magnetization and electric polarization are still rare. Among such ferromagnetic ferroelectrics are conical spin…

In this contribution to the special issue on multiferroics we focus on multiferroicity driven by different forms of charge ordering. We will present the generic mechanisms by which charge ordering can induce ferroelectricity in magnetic…

材料科学 · 物理学 2011-07-22 Jeroen van den Brink , Daniel I. Khomskii

Density functional calculations are used to study magnetic and electronic properties of the spinel ferrites, ZnFe$_2$O$_4$ and MnFe$_2$O$_4$. Correct magnetic orderings are obtained. ZnFe$_2$O$_4$ is predicted to be a small gap insulator in…

凝聚态物理 · 物理学 2009-11-07 D. J. Singh , M. Gupta , R. Gupta

The coexistence of multiple ferroic orders, i.e. multiferroicity, is a scarce property to be found in materials. Historically, this state has been found mainly in 3-dimensional complex oxides, but so far this state has still been elusive…

The magnetic, thermodynamic and dielectric properties of the $\gamma$ - Fe${_2}$WO${_6}$ system is reported. Crystallizing in the centrosymmetric $Pbcn$ space group, this particular polymorph exhibits a number of different magnetic…

强关联电子 · 物理学 2017-08-29 Soumendra Nath Panja , Jitender Kumar , Luminita Harnagea , A. K. Nigam , Sunil Nair

First principles calculations based on the density functional theory within the local spin density approximation plus U(LSDA+U)scheme, show rhombohedral Bi$_2$FeTiO$_6$ is a potential multiferroic in which the magnetism and ferroelectricity…

材料科学 · 物理学 2012-12-20 Hong-Jian Feng , Fa-Min Liu
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